Preparation of Lyocell Fibers from Solutions of Miscanthus Cellulose
Both annual (cotton, flax, hemp, etc.) and perennial (trees and grasses) plants can serve as a source of cellulose for fiber production. In recent years, the perennial herbaceous plant miscanthus has attracted particular interest as a popular industrial plant with enormous potential. This industrial...
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| Veröffentlicht in: | Polymers 2024-10, Vol.16 (20), p.2915 |
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| creator | Makarov, Igor S Budaeva, Vera V Gismatulina, Yulia A Kashcheyeva, Ekaterina I Zolotukhin, Vladimir N Gorbatova, Polina A Sakovich, Gennady V Vinogradov, Markel I Palchikova, Ekaterina E Levin, Ivan S Azanov, Mikhail V |
| description | Both annual (cotton, flax, hemp, etc.) and perennial (trees and grasses) plants can serve as a source of cellulose for fiber production. In recent years, the perennial herbaceous plant miscanthus has attracted particular interest as a popular industrial plant with enormous potential. This industrial crop, which contains up to 57% cellulose, serves as a raw material in the chemical and biotechnology sectors. This study proposes for the first time the utilization of miscanthus, namely Miscanthus Giganteus "KAMIS", to generate spinning solutions in N-methylmorpholine-N-oxide. Miscanthus cellulose's properties were identified using standard methods for determining the constituent composition, including also IR and atomic emission spectroscopy. The dry-jet wet method was used to make fibers from cellulose solutions with an appropriate viscosity/elasticity ratio. The structural characteristics of the fibers were studied using IR and scanning electron microscopy, as well as via X-ray structural analysis. The mechanical and thermal properties of the novel type of hydrated cellulose fibers demonstrated the possibility of producing high-quality fibers from miscanthus. |
| doi_str_mv | 10.3390/polym16202915 |
| format | Article |
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In recent years, the perennial herbaceous plant miscanthus has attracted particular interest as a popular industrial plant with enormous potential. This industrial crop, which contains up to 57% cellulose, serves as a raw material in the chemical and biotechnology sectors. This study proposes for the first time the utilization of miscanthus, namely Miscanthus Giganteus "KAMIS", to generate spinning solutions in N-methylmorpholine-N-oxide. Miscanthus cellulose's properties were identified using standard methods for determining the constituent composition, including also IR and atomic emission spectroscopy. The dry-jet wet method was used to make fibers from cellulose solutions with an appropriate viscosity/elasticity ratio. The structural characteristics of the fibers were studied using IR and scanning electron microscopy, as well as via X-ray structural analysis. The mechanical and thermal properties of the novel type of hydrated cellulose fibers demonstrated the possibility of producing high-quality fibers from miscanthus.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym16202915</identifier><identifier>PMID: 39458743</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Atmospheric pressure ; Caustic soda ; Cellulose ; Cellulose fibers ; Cotton ; Flax ; Hemp ; Industrial plants ; Infrared spectroscopy ; Lignin ; Methods ; Polymerization ; Raw materials ; Solvents ; Spectrum analysis ; Structural analysis ; Thermodynamic properties</subject><ispartof>Polymers, 2024-10, Vol.16 (20), p.2915</ispartof><rights>COPYRIGHT 2024 MDPI AG</rights><rights>2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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| source | MDPI - Multidisciplinary Digital Publishing Institute; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; PubMed Central Open Access |
| subjects | Atmospheric pressure Caustic soda Cellulose Cellulose fibers Cotton Flax Hemp Industrial plants Infrared spectroscopy Lignin Methods Polymerization Raw materials Solvents Spectrum analysis Structural analysis Thermodynamic properties |
| title | Preparation of Lyocell Fibers from Solutions of Miscanthus Cellulose |
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