Nutshell Materials as a Potential Eco-Friendly Biosorbent for the Effective Extraction of UV Filters and Parabens from Water Samples
UV filters and parabens, as ingredients of cosmetics, are commonly occurring water pollutants. In our work, nutshells were used as biosorbents in the developed analytical procedure for the determination of UV filters and parabens in water samples. The shells obtained from walnuts, hazelnuts, peanuts...
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| creator | Narloch, Izabela Wejnerowska, Grażyna Kosobucki, Przemysław |
| description | UV filters and parabens, as ingredients of cosmetics, are commonly occurring water pollutants. In our work, nutshells were used as biosorbents in the developed analytical procedure for the determination of UV filters and parabens in water samples. The shells obtained from walnuts, hazelnuts, peanuts and pistachios were applied as biosorbents. The proposed analytical method can be used as a powerful alternative to other methods for the analysis of UV filters and parabens in water samples. A method of carrying out the sorption step and its parameters, i.e., the effect of time, pH, and salt addition, was developed. A method for the desorption of analytes was also developed, in which the type and volume of solvent, and the desorption time, were established. The recoveries were in the range of 59-117% for benzophenones and lower recoveries from 14 to 75% for parabens. The results showed that nutshells can be used as low-cost, efficient and eco-friendly biosorbents for the determination of parabens and UV filters in water samples. These materials can be used as a 'greener' replacement for the commercially available adsorbents for the extraction of cosmetic ingredients from the environment. |
| doi_str_mv | 10.3390/ma17205128 |
| format | Article |
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These materials can be used as a 'greener' replacement for the commercially available adsorbents for the extraction of cosmetic ingredients from the environment.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma17205128</identifier><identifier>PMID: 39459833</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Analytical chemistry ; Cellulose ; Cosmetics ; Desorption ; Fourier transforms ; Germany ; Ingredients ; Lignin ; Lignocellulose ; Microscopy ; Nutshells ; Personal grooming ; Pistachio nuts ; Poland ; Shells ; Sorbents ; Ultraviolet filters ; Water ; Water pollution ; Water purification ; Water sampling</subject><ispartof>Materials, 2024-10, Vol.17 (20), p.5128</ispartof><rights>COPYRIGHT 2024 MDPI AG</rights><rights>2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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In our work, nutshells were used as biosorbents in the developed analytical procedure for the determination of UV filters and parabens in water samples. The shells obtained from walnuts, hazelnuts, peanuts and pistachios were applied as biosorbents. The proposed analytical method can be used as a powerful alternative to other methods for the analysis of UV filters and parabens in water samples. A method of carrying out the sorption step and its parameters, i.e., the effect of time, pH, and salt addition, was developed. A method for the desorption of analytes was also developed, in which the type and volume of solvent, and the desorption time, were established. The recoveries were in the range of 59-117% for benzophenones and lower recoveries from 14 to 75% for parabens. The results showed that nutshells can be used as low-cost, efficient and eco-friendly biosorbents for the determination of parabens and UV filters in water samples. These materials can be used as a 'greener' replacement for the commercially available adsorbents for the extraction of cosmetic ingredients from the environment.</description><subject>Analytical chemistry</subject><subject>Cellulose</subject><subject>Cosmetics</subject><subject>Desorption</subject><subject>Fourier transforms</subject><subject>Germany</subject><subject>Ingredients</subject><subject>Lignin</subject><subject>Lignocellulose</subject><subject>Microscopy</subject><subject>Nutshells</subject><subject>Personal grooming</subject><subject>Pistachio nuts</subject><subject>Poland</subject><subject>Shells</subject><subject>Sorbents</subject><subject>Ultraviolet filters</subject><subject>Water</subject><subject>Water pollution</subject><subject>Water purification</subject><subject>Water sampling</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdUt1vFCEQJ0Zjm7Mv_gGGxBdjspWPhV2eTG3u1KS1TWr1kbAs9Gh2lyuwjX33D3cuV2srkMzA_OY3zAdCryk55FyRD6OhDSOCsvYZ2qdKyYqqun7-SN9DBzlfE1ic05apl2iPq1qolvN99PvbXPLaDQM-NcWlYIaMDRx8HoubCtzx0sZqlYKb-uEOfwoxx9SBCfuYcFk7vPTe2RJuQftVkgE1Tjh6fPkDr8IApEA39fjcJAN-GfsUR_xzGw1fmHEzuPwKvfAQ2B3cywW6XC2_H3-pTs4-fz0-OqksU6pUTS87IRQjXkoqhDCKCeF7Ybiz1nElOMBqJrjsPKWs441oBPPEKNo4RixfoI873s3cja63kEUyg96kMJp0p6MJ-qllCmt9FW81pYIoKiUwvLtnSPFmdrnoMWQL5TOTi3PWnDJKZE1oA9C3_0Gv45wmyG-LIg1pW-jIAh3uUFdmcDpMPm5LCLt3Y7Bxcj7A-1FL65oQJmtweL9zsCnmnJx_-D4lejsR-t9EAPjN44QfoH_7z_8ARs6wMw</recordid><startdate>20241021</startdate><enddate>20241021</enddate><creator>Narloch, Izabela</creator><creator>Wejnerowska, Grażyna</creator><creator>Kosobucki, Przemysław</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-9509-2267</orcidid><orcidid>https://orcid.org/0000-0003-4223-0480</orcidid></search><sort><creationdate>20241021</creationdate><title>Nutshell Materials as a Potential Eco-Friendly Biosorbent for the Effective Extraction of UV Filters and Parabens from Water Samples</title><author>Narloch, Izabela ; 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| source | MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Analytical chemistry Cellulose Cosmetics Desorption Fourier transforms Germany Ingredients Lignin Lignocellulose Microscopy Nutshells Personal grooming Pistachio nuts Poland Shells Sorbents Ultraviolet filters Water Water pollution Water purification Water sampling |
| title | Nutshell Materials as a Potential Eco-Friendly Biosorbent for the Effective Extraction of UV Filters and Parabens from Water Samples |
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