Critical Cooling Rate of Fast-Crystallizing Polyesters: The Example of Poly(alkylene trans -1,4-cyclohexanedicarboxylate)
Controlling the cooling rate experienced by a material during a manufacturing process is a challenge and a major issue. Industrial processing techniques are very diverse and may involve a whole range of cooling rates, which are sometimes extremely high for small and/or thin manufactured parts. For p...
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| Veröffentlicht in: | Polymers 2024-10, Vol.16 (19), p.2792 |
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| creator | Hallavant, Kylian Soccio, Michelina Guidotti, Giulia Lotti, Nadia Esposito, Antonella Saiter-Fourcin, Allisson |
| description | Controlling the cooling rate experienced by a material during a manufacturing process is a challenge and a major issue. Industrial processing techniques are very diverse and may involve a whole range of cooling rates, which are sometimes extremely high for small and/or thin manufactured parts. For polymers, the cooling rate has consequences on both the microstructure and the time-dependent properties. The common cooling rates associated with conventional calorimetric measurements are generally limited to a few tens of degrees per minute. This work combines several calorimetric techniques (DSC, modulated-temperature DSC, stochastically-modulated DSC and Fast Scanning Calorimetry) to estimate the critical cooling rate required to melt-quench fast-crystallizing polyesters to their fully amorphous state, based on the example of a series of poly(alkylene
-1,4-cyclohexanedicarboxylate) (PCHs) with a number of methylene groups in the main structure of the repeating unit nCH2 varying from 3 to 6. The even-numbered ones require faster cooling rates (about 3000 K s
for nCH2 = 4, between 500 and 1000 K s
for nCH2 = 6) compared to the odd-numbered ones (between 50 K min
and 100 K s
for nCH2 = 3, between 10 and 30 K min
for nCH2 = 5). |
| doi_str_mv | 10.3390/polym16192792 |
| format | Article |
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-1,4-cyclohexanedicarboxylate) (PCHs) with a number of methylene groups in the main structure of the repeating unit nCH2 varying from 3 to 6. The even-numbered ones require faster cooling rates (about 3000 K s
for nCH2 = 4, between 500 and 1000 K s
for nCH2 = 6) compared to the odd-numbered ones (between 50 K min
and 100 K s
for nCH2 = 3, between 10 and 30 K min
for nCH2 = 5).</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym16192792</identifier><identifier>PMID: 39408502</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Analysis ; Calorimetry ; Carboxylic acids ; Cooling ; Cooling rate ; Cyclohexane ; Differential scanning calorimetry ; Engineering Sciences ; Heat treating ; Identification and classification ; Materials ; Mechanical properties ; Methods ; Molecular weight ; Polyester resins ; Polyesters ; Polymers ; Properties ; Reagents ; Temperature</subject><ispartof>Polymers, 2024-10, Vol.16 (19), p.2792</ispartof><rights>COPYRIGHT 2024 MDPI AG</rights><rights>2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><rights>2024 by the authors. 2024</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c375t-6e3ae5d0854af85c04574cf19264fa1e0eb464823cc73a7c8df6d258fc17d99e3</cites><orcidid>0009-0001-0440-8770 ; 0000-0001-6879-2989 ; 0000-0003-0507-1417 ; 0000-0001-9275-6865 ; 0000-0003-3646-9612 ; 0000-0002-7976-2934</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC11478611/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC11478611/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27903,27904,53769,53771</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39408502$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-04716992$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Hallavant, Kylian</creatorcontrib><creatorcontrib>Soccio, Michelina</creatorcontrib><creatorcontrib>Guidotti, Giulia</creatorcontrib><creatorcontrib>Lotti, Nadia</creatorcontrib><creatorcontrib>Esposito, Antonella</creatorcontrib><creatorcontrib>Saiter-Fourcin, Allisson</creatorcontrib><title>Critical Cooling Rate of Fast-Crystallizing Polyesters: The Example of Poly(alkylene trans -1,4-cyclohexanedicarboxylate)</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>Controlling the cooling rate experienced by a material during a manufacturing process is a challenge and a major issue. Industrial processing techniques are very diverse and may involve a whole range of cooling rates, which are sometimes extremely high for small and/or thin manufactured parts. For polymers, the cooling rate has consequences on both the microstructure and the time-dependent properties. The common cooling rates associated with conventional calorimetric measurements are generally limited to a few tens of degrees per minute. This work combines several calorimetric techniques (DSC, modulated-temperature DSC, stochastically-modulated DSC and Fast Scanning Calorimetry) to estimate the critical cooling rate required to melt-quench fast-crystallizing polyesters to their fully amorphous state, based on the example of a series of poly(alkylene
-1,4-cyclohexanedicarboxylate) (PCHs) with a number of methylene groups in the main structure of the repeating unit nCH2 varying from 3 to 6. The even-numbered ones require faster cooling rates (about 3000 K s
for nCH2 = 4, between 500 and 1000 K s
for nCH2 = 6) compared to the odd-numbered ones (between 50 K min
and 100 K s
for nCH2 = 3, between 10 and 30 K min
for nCH2 = 5).</description><subject>Analysis</subject><subject>Calorimetry</subject><subject>Carboxylic acids</subject><subject>Cooling</subject><subject>Cooling rate</subject><subject>Cyclohexane</subject><subject>Differential scanning calorimetry</subject><subject>Engineering Sciences</subject><subject>Heat treating</subject><subject>Identification and classification</subject><subject>Materials</subject><subject>Mechanical properties</subject><subject>Methods</subject><subject>Molecular weight</subject><subject>Polyester resins</subject><subject>Polyesters</subject><subject>Polymers</subject><subject>Properties</subject><subject>Reagents</subject><subject>Temperature</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdklFv1DAMxysEYtPYI6-oEi-bREfSpEnLCzpVG0M6CYTGc5RLnbuMtDmS3nTl0-NyY9qWPCSyf7b_tpxlbym5YKwhH7fBTz0VtCllU77IjksiWcGZIC8f_Y-y05RuCR5eCUHl6-yINZzUFSmPs6mNbnRG-7wNwbthnf_QI-TB5lc6jUUbpzRq792f2fUdy0EaIaZP-c0G8su97rf-Hz27zrT_NXkYIB-jHlJe0A-8MJPxYQN7PUCHdeIq7CePJc7fZK-s9glO79-T7OfV5U17XSy_ffnaLpaFYbIaCwFMQ9WhXK5tXRlsQnJjsWXBraZAYMUFr0tmjGRamrqzoiur2hoqu6YBdpJ9PuTd7lY9dAYGVOfVNrpex0kF7dRTz-A2ah3uFKVc1oJSzHB-yLB5Fne9WKrZRrikomnKu5k9u68Ww-8dDkv1LhnwHvsPu6QYpZLIqqINou-fobdhFwecxUwJgX2WNVIXB2qtPSg32IAiDd4OemfCANahfVFTzoms5aygOASYGFKKYB8kU6LmrVFPtgb5d4_n80D_3xH2FzSvvjY</recordid><startdate>20241001</startdate><enddate>20241001</enddate><creator>Hallavant, Kylian</creator><creator>Soccio, Michelina</creator><creator>Guidotti, Giulia</creator><creator>Lotti, Nadia</creator><creator>Esposito, Antonella</creator><creator>Saiter-Fourcin, Allisson</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>1XC</scope><scope>VOOES</scope><scope>5PM</scope><orcidid>https://orcid.org/0009-0001-0440-8770</orcidid><orcidid>https://orcid.org/0000-0001-6879-2989</orcidid><orcidid>https://orcid.org/0000-0003-0507-1417</orcidid><orcidid>https://orcid.org/0000-0001-9275-6865</orcidid><orcidid>https://orcid.org/0000-0003-3646-9612</orcidid><orcidid>https://orcid.org/0000-0002-7976-2934</orcidid></search><sort><creationdate>20241001</creationdate><title>Critical Cooling Rate of Fast-Crystallizing Polyesters: The Example of Poly(alkylene trans -1,4-cyclohexanedicarboxylate)</title><author>Hallavant, Kylian ; Soccio, Michelina ; Guidotti, Giulia ; Lotti, Nadia ; Esposito, Antonella ; Saiter-Fourcin, Allisson</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c375t-6e3ae5d0854af85c04574cf19264fa1e0eb464823cc73a7c8df6d258fc17d99e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Analysis</topic><topic>Calorimetry</topic><topic>Carboxylic acids</topic><topic>Cooling</topic><topic>Cooling rate</topic><topic>Cyclohexane</topic><topic>Differential scanning calorimetry</topic><topic>Engineering Sciences</topic><topic>Heat treating</topic><topic>Identification and classification</topic><topic>Materials</topic><topic>Mechanical properties</topic><topic>Methods</topic><topic>Molecular weight</topic><topic>Polyester resins</topic><topic>Polyesters</topic><topic>Polymers</topic><topic>Properties</topic><topic>Reagents</topic><topic>Temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hallavant, Kylian</creatorcontrib><creatorcontrib>Soccio, Michelina</creatorcontrib><creatorcontrib>Guidotti, Giulia</creatorcontrib><creatorcontrib>Lotti, Nadia</creatorcontrib><creatorcontrib>Esposito, Antonella</creatorcontrib><creatorcontrib>Saiter-Fourcin, Allisson</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hallavant, Kylian</au><au>Soccio, Michelina</au><au>Guidotti, Giulia</au><au>Lotti, Nadia</au><au>Esposito, Antonella</au><au>Saiter-Fourcin, Allisson</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Critical Cooling Rate of Fast-Crystallizing Polyesters: The Example of Poly(alkylene trans -1,4-cyclohexanedicarboxylate)</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2024-10-01</date><risdate>2024</risdate><volume>16</volume><issue>19</issue><spage>2792</spage><pages>2792-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>Controlling the cooling rate experienced by a material during a manufacturing process is a challenge and a major issue. Industrial processing techniques are very diverse and may involve a whole range of cooling rates, which are sometimes extremely high for small and/or thin manufactured parts. For polymers, the cooling rate has consequences on both the microstructure and the time-dependent properties. The common cooling rates associated with conventional calorimetric measurements are generally limited to a few tens of degrees per minute. This work combines several calorimetric techniques (DSC, modulated-temperature DSC, stochastically-modulated DSC and Fast Scanning Calorimetry) to estimate the critical cooling rate required to melt-quench fast-crystallizing polyesters to their fully amorphous state, based on the example of a series of poly(alkylene
-1,4-cyclohexanedicarboxylate) (PCHs) with a number of methylene groups in the main structure of the repeating unit nCH2 varying from 3 to 6. The even-numbered ones require faster cooling rates (about 3000 K s
for nCH2 = 4, between 500 and 1000 K s
for nCH2 = 6) compared to the odd-numbered ones (between 50 K min
and 100 K s
for nCH2 = 3, between 10 and 30 K min
for nCH2 = 5).</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>39408502</pmid><doi>10.3390/polym16192792</doi><orcidid>https://orcid.org/0009-0001-0440-8770</orcidid><orcidid>https://orcid.org/0000-0001-6879-2989</orcidid><orcidid>https://orcid.org/0000-0003-0507-1417</orcidid><orcidid>https://orcid.org/0000-0001-9275-6865</orcidid><orcidid>https://orcid.org/0000-0003-3646-9612</orcidid><orcidid>https://orcid.org/0000-0002-7976-2934</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Analysis Calorimetry Carboxylic acids Cooling Cooling rate Cyclohexane Differential scanning calorimetry Engineering Sciences Heat treating Identification and classification Materials Mechanical properties Methods Molecular weight Polyester resins Polyesters Polymers Properties Reagents Temperature |
| title | Critical Cooling Rate of Fast-Crystallizing Polyesters: The Example of Poly(alkylene trans -1,4-cyclohexanedicarboxylate) |
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