Zr6O8 core cluster with formula unit [Zr6O4(OH)4(OH2)8(CH3COO)4(SO4)4]·nH2O obtained under mild conditions

During attempts to synthesize zirconium-based MOFs, we have obtained a new crystal structure of the cluster with Zr6O8 core and formula unit [Zr6O4(OH)4(OH2)8(CH3COO)4(SO4)4]·nH2O. Unlike other systems, mild conditions were employed in this case; no strong acids or hydrothermal conditions were requi...

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Veröffentlicht in:	RSC advances 2024-09, Vol.14 (41), p.29910-29918
Hauptverfasser:	Garzón-Serrano, Andrea Y, Lozano, Johan D, Perez, Leon D, Sierra, César A, Macías, Mario A
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding strength Chemical bonds Chemistry Clusters Crystal structure Hydrogen bonds Long range order Zirconium
Online-Zugang:	Volltext
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