Synthesis of Quinoline-Based Pt–Sb Complexes with L- or Z‑Type Interaction: Ligand-Controlled Redox via Anion Transfer

A series of Pt–Sb complexes with two or three L-type quinoline side arms were prepared and studied. Two ligands, tri­(8-quinolinyl)­stibane (SbQ3, Q = 8-quinolinyl, 1) and 8,8′-(phenylstibanediyl)­diquinoline (SbQ2Ph, 2), were used to synthesize the PtII–SbIII complexes (SbQ3)­PtCl2 (3) and (SbQ2Ph)...

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Veröffentlicht in:Organometallics 2024-09, Vol.43 (17), p.1789-1802
Hauptverfasser: Webber, Christopher K., Kong, Fanji, Kumawat, Jugal, Joy, Jyothish, Richardson, Erica K., Siano, Paolo, Dickie, Diane A., Ess, Daniel H., Gunnoe, T. Brent
Format: Artikel
Sprache:eng
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