Influence of Cross-Linkers on the Wash Resistance of Chitosan-Functionalized Polyester Fabrics
This study investigates the wash resistance of polyester fabrics functionalized with chitosan, a biopolymer known for its biocompatibility, non-toxicity, biodegradability and environmentally friendly properties. The interaction of chitosan with synthetic polymers, such as polyester, often requires s...
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| Veröffentlicht in: | Polymers 2024-08, Vol.16 (16), p.2365 |
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| creator | Pušić, Tanja Bušac, Tea Volmajer Valh, Julija |
| description | This study investigates the wash resistance of polyester fabrics functionalized with chitosan, a biopolymer known for its biocompatibility, non-toxicity, biodegradability and environmentally friendly properties. The interaction of chitosan with synthetic polymers, such as polyester, often requires surface treatment due to the weak natural affinity between the two materials. To improve the interaction and stability of chitosan on polyester, alkaline hydrolysis of the polyester fabric was used as a surface treatment method. The effectiveness of using cross-linking agents 1,2,3,4-butane tetracarboxylic acid (BTCA) and hydroxyethyl methacrylate (HEMA) in combination with ammonium persulphate (APS) to improve the stability of chitosan on polyester during washing was investigated. The wash resistance of polyester fabrics functionalized with chitosan was tested after 1, 5 and 10 washes with a standard ECE detergent. Staining tests were carried out to evaluate the retention of chitosan on the fabric. The results showed that polyester fabrics functionalized with chitosan without cross-linkers exhibited better wash resistance than the fabrics treated with crosslinkers. |
| doi_str_mv | 10.3390/polym16162365 |
| format | Article |
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The interaction of chitosan with synthetic polymers, such as polyester, often requires surface treatment due to the weak natural affinity between the two materials. To improve the interaction and stability of chitosan on polyester, alkaline hydrolysis of the polyester fabric was used as a surface treatment method. The effectiveness of using cross-linking agents 1,2,3,4-butane tetracarboxylic acid (BTCA) and hydroxyethyl methacrylate (HEMA) in combination with ammonium persulphate (APS) to improve the stability of chitosan on polyester during washing was investigated. The wash resistance of polyester fabrics functionalized with chitosan was tested after 1, 5 and 10 washes with a standard ECE detergent. Staining tests were carried out to evaluate the retention of chitosan on the fabric. The results showed that polyester fabrics functionalized with chitosan without cross-linkers exhibited better wash resistance than the fabrics treated with crosslinkers.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym16162365</identifier><identifier>PMID: 39204584</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Biocompatibility ; Biopolymers ; Caustic soda ; Chitosan ; Crosslinking ; Detergents ; Fabrics ; Hydrochloric acid ; Molecular weight ; Polyesters ; Polyhydroxyethyl methacrylate ; Polymers ; Sodium ; Surface stability ; Surface treatment ; Textile composites ; Textile fibers</subject><ispartof>Polymers, 2024-08, Vol.16 (16), p.2365</ispartof><rights>2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2024 by the authors. 2024</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0001-9533-5986 ; 0000-0001-7048-1311 ; 0000-0002-6727-8344</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC11360505/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC11360505/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,315,728,781,785,886,27929,27930,53796,53798</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39204584$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Pušić, Tanja</creatorcontrib><creatorcontrib>Bušac, Tea</creatorcontrib><creatorcontrib>Volmajer Valh, Julija</creatorcontrib><title>Influence of Cross-Linkers on the Wash Resistance of Chitosan-Functionalized Polyester Fabrics</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>This study investigates the wash resistance of polyester fabrics functionalized with chitosan, a biopolymer known for its biocompatibility, non-toxicity, biodegradability and environmentally friendly properties. The interaction of chitosan with synthetic polymers, such as polyester, often requires surface treatment due to the weak natural affinity between the two materials. To improve the interaction and stability of chitosan on polyester, alkaline hydrolysis of the polyester fabric was used as a surface treatment method. The effectiveness of using cross-linking agents 1,2,3,4-butane tetracarboxylic acid (BTCA) and hydroxyethyl methacrylate (HEMA) in combination with ammonium persulphate (APS) to improve the stability of chitosan on polyester during washing was investigated. The wash resistance of polyester fabrics functionalized with chitosan was tested after 1, 5 and 10 washes with a standard ECE detergent. Staining tests were carried out to evaluate the retention of chitosan on the fabric. 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Bušac, Tea ; Volmajer Valh, Julija</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p264t-740620dbca5c9160b7f3a584faa1ee7bc3f8928eacc95b3e8e567e304c5970a43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Biocompatibility</topic><topic>Biopolymers</topic><topic>Caustic soda</topic><topic>Chitosan</topic><topic>Crosslinking</topic><topic>Detergents</topic><topic>Fabrics</topic><topic>Hydrochloric acid</topic><topic>Molecular weight</topic><topic>Polyesters</topic><topic>Polyhydroxyethyl methacrylate</topic><topic>Polymers</topic><topic>Sodium</topic><topic>Surface stability</topic><topic>Surface treatment</topic><topic>Textile composites</topic><topic>Textile fibers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pušić, Tanja</creatorcontrib><creatorcontrib>Bušac, Tea</creatorcontrib><creatorcontrib>Volmajer Valh, Julija</creatorcontrib><collection>PubMed</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Access via ProQuest (Open Access)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pušić, Tanja</au><au>Bušac, Tea</au><au>Volmajer Valh, Julija</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of Cross-Linkers on the Wash Resistance of Chitosan-Functionalized Polyester Fabrics</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2024-08-21</date><risdate>2024</risdate><volume>16</volume><issue>16</issue><spage>2365</spage><pages>2365-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>This study investigates the wash resistance of polyester fabrics functionalized with chitosan, a biopolymer known for its biocompatibility, non-toxicity, biodegradability and environmentally friendly properties. The interaction of chitosan with synthetic polymers, such as polyester, often requires surface treatment due to the weak natural affinity between the two materials. To improve the interaction and stability of chitosan on polyester, alkaline hydrolysis of the polyester fabric was used as a surface treatment method. The effectiveness of using cross-linking agents 1,2,3,4-butane tetracarboxylic acid (BTCA) and hydroxyethyl methacrylate (HEMA) in combination with ammonium persulphate (APS) to improve the stability of chitosan on polyester during washing was investigated. The wash resistance of polyester fabrics functionalized with chitosan was tested after 1, 5 and 10 washes with a standard ECE detergent. Staining tests were carried out to evaluate the retention of chitosan on the fabric. 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| source | MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central; PubMed Central Open Access |
| subjects | Biocompatibility Biopolymers Caustic soda Chitosan Crosslinking Detergents Fabrics Hydrochloric acid Molecular weight Polyesters Polyhydroxyethyl methacrylate Polymers Sodium Surface stability Surface treatment Textile composites Textile fibers |
| title | Influence of Cross-Linkers on the Wash Resistance of Chitosan-Functionalized Polyester Fabrics |
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