Chemical and engineering bases for green H2O2 production and related oxidation and ammoximation of olefins and analogues

Chemical and engineering bases for green H2O2 production and related oxidation and ammoximation of olefins and analogues

Plastics, fibers and rubber are three mainstream synthetic materials that are essential to our daily lives and contribute significantly to the quality of our lives. The production of the monomers of these synthetic polymers usually involves oxidation or ammoximation reactions of olefins and analogue...

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Veröffentlicht in:National science review 2024-08, Vol.11 (8), p.nwae243
Hauptverfasser: Qiao, Minghua, Zhou, Xinggui, Du, Zexue, Wu, Peng, Zong, Baoning
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container_title National science review
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creator Qiao, Minghua
Zhou, Xinggui
Du, Zexue
Wu, Peng
Zong, Baoning
description Plastics, fibers and rubber are three mainstream synthetic materials that are essential to our daily lives and contribute significantly to the quality of our lives. The production of the monomers of these synthetic polymers usually involves oxidation or ammoximation reactions of olefins and analogues. However, the utilization of C, O and N atoms in current industrial processes is
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The production of the monomers of these synthetic polymers usually involves oxidation or ammoximation reactions of olefins and analogues. However, the utilization of C, O and N atoms in current industrial processes is &lt;80%, which represents the most environmentally polluting processes for the production of basic chemicals. Through innovation and integration of catalytic materials, new reaction pathways, and reaction engineering, the Research Institute of Petroleum Processing, Sinopec Co., Ltd. (RIPP) and its collaborators have developed unique H2O2-centered oxidation/ammoximation technologies for olefins and analogues, which has resulted in a ¥500 billion emerging industry and driven trillions of ¥s' worth of downstream industries. The chemical and engineering bases of the production technologies mainly involve the integration of slurry-bed reactors and microsphere catalysts to enhance H2O2 production, H2O2 propylene/chloropropylene epoxidation for the production of propylene oxide/epichlorohydrin, and integration of H2O2 cyclohexanone ammoximation and membrane separation to innovate the caprolactam production process. This review briefly summarizes the whole process from the acquisition of scientific knowledge to the formation of an industrial production technology by RIPP. Moreover, the scientific frontiers of H2O2 production and related oxidation/ammoximation processes of olefins and analogues are reviewed, and new technological growth points are envisaged, with the aim of maintaining China's standing as a leader in the development of the science and technologies of H2O2 production and utilization.</description><identifier>ISSN: 2095-5138</identifier><identifier>ISSN: 2053-714X</identifier><identifier>EISSN: 2053-714X</identifier><identifier>DOI: 10.1093/nsr/nwae243</identifier><language>eng</language><publisher>Oxford University Press</publisher><subject>Review</subject><ispartof>National science review, 2024-08, Vol.11 (8), p.nwae243</ispartof><rights>The Author(s) 2024. Published by Oxford University Press on behalf of China Science Publishing &amp; Media Ltd.</rights><rights>The Author(s) 2024. 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title Chemical and engineering bases for green H2O2 production and related oxidation and ammoximation of olefins and analogues
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