4f-Orbital mixing increases the magnetic susceptibility of Cp′3Eu

Traditional models of lanthanide electronic structure suggest that bonding is predominantly ionic, and that covalent orbital mixing is not an important factor in determining magnetic properties. Here, 4f orbital mixing and its impact on the magnetic susceptibility of Cp′3Eu (Cp′ = C5H4SiMe3) was ana...

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Veröffentlicht in:	Chemical science (Cambridge) 2024-08, Vol.15 (32), p.12667-12675
Hauptverfasser:	Gunther, S Olivia, Qiao, Yusen, Smith, Patrick W, Ciccone, Sierra R, Ditter, Alexander S, Huh, Daniel N, Moreau, Liane M, Shuh, David K, Sun, Taoxiang, Arnold, Polly L, Booth, Corwin H, de Jong, Wibe A, Evans, William J, Lukens, Wayne W, Minasian, Stefan G
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectroscopy Chemistry Electronic structure Magnetic measurement Magnetic permeability Magnetic properties Spectrum analysis X ray absorption
Online-Zugang:	Volltext
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