Pd-Catalyzed Ring-Opening Polymerization of Cyclobutanols through C(sp3)–C(sp3) Bond Cleavage

A new approach to ring-opening polymerization (ROP) based on C­(sp3)–C­(sp3) bond cleavage is reported. This process is based on the ability of Pd to promote both the β-carbon elimination of a bifunctional cyclobutanol precursor and the C–C coupling process with the resulting Pd-alkyl intermediate....

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Veröffentlicht in:	Macromolecules 2024-07, Vol.57 (14), p.6577-6582
Hauptverfasser:	Parra-García, Sergio, Saura-Llamas, Isabel, Bautista, Delia, Gil-Rubio, Juan, García-López, José-Antonio
Format:	Artikel
Sprache:	eng
Schlagworte:	cleavage (chemistry) polymerization polymers
Online-Zugang:	Volltext
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