Thermal Jahn–Teller Distortion Changes and Slow Relaxation of Magnetization in Mn(III) Schiff Base Complexes

The impact that the anion and alkyl group has on the electronic structures and magnetic properties of four mononuclear Mn­(III) complexes is explored in [Mn­(salEen-Br)2]Y (salEen-Br = 2-{[2-(ethylamino)­ethylimino]­methyl}-4-Br-phenol; Y = ClO4 – 1 and BF4 –·1/3CH2Cl2 2) and [Mn­(salBzen-Br)2]Y (sa...

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Veröffentlicht in:	Inorganic chemistry 2024-07, Vol.63 (28), p.12858-12869
Hauptverfasser:	Chantarangkul, Chantalaksana, Patigo, Apinya, McMurtrie, John C., Clérac, Rodolphe, Rouzières, Mathieu, Gómez-Coca, Silvia, Ruiz, Eliseo, Harding, Phimphaka, Harding, David J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Coordination chemistry
Online-Zugang:	Volltext
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