Synthesis of zirconium(IV) and hafnium(IV) isopropoxide, sec -butoxide and tert -butoxide

We revisited the synthesis of zirconium(IV) and hafnium(IV) alkoxides, namely the metal isopropoxide isopropanol complex (M(OiPr) ·iPrOH, M = Zr, Hf) and the metal - and -butoxide (M(O Bu) and M(O Bu) , M = Zr, Hf). We optimized the most convenient synthesis methods and compared the products with co...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2024-07, Vol.53 (28), p.11769-11777
Hauptverfasser:	Dhaene, Evert, Seno, Carlotta, De Roo, Jonathan
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkoxides Chemistry Hafnium Synthesis Zirconium
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	11777
container_issue	28
container_start_page	11769
container_title	Dalton transactions : an international journal of inorganic chemistry
container_volume	53
creator	Dhaene, Evert Seno, Carlotta De Roo, Jonathan
description	We revisited the synthesis of zirconium(IV) and hafnium(IV) alkoxides, namely the metal isopropoxide isopropanol complex (M(OiPr) ·iPrOH, M = Zr, Hf) and the metal - and -butoxide (M(O Bu) and M(O Bu) , M = Zr, Hf). We optimized the most convenient synthesis methods and compared the products with commercial sources. En route to the metal - and -butoxides, we synthesized the metal diethylamido complex (M(NEt ) , M = Zr, Hf).
doi_str_mv	10.1039/d4dt01280a
format	Article
fullrecord	<record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_11250499</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3081039677</sourcerecordid><originalsourceid>FETCH-LOGICAL-c296t-7e4f987efec6613fd17a48441c3d98173ff070a76ebbc7f3d49680eacf08f7b13</originalsourceid><addsrcrecordid>eNpdkVtLwzAUx4Mobk5f_ABS8GWK1aTJmuZJxuZlMPDBKfgU0jRxGW0zk1acn97u4rw8nduPP-ecPwDHCF4iiNlVRrIKoiiBYge0EaE0ZBEmu9s8ilvgwPsZhFEEe9E-aOGEYcZi2AYvj4uymipvfGB18GmctKWpi-7o-SwQZRZMhd7Wxtu5s3P7YTJ1EXglgzCtq1W5Yivlqp_WIdjTIvfqaBM74On2ZjK4D8cPd6NBfxzKiMVVSBXRLKFKKxnHCOsMUUESQpDEGUsQxVpDCgWNVZpKqnFGWJxAJaSGiaYpwh1wvdad12mhMqnKyomcz50phFtwKwz_OynNlL_ad45Q1IOEsUahu1Fw9q1WvuKF8VLluSiVrT3HkOLmobSHG_T0HzqztSub-xoqWboRU9pQ52tKOuu9U3q7DYJ8CfEhGU5WlvUb-OT3_lv02yP8Bf1Okbw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3081039677</pqid></control><display><type>article</type><title>Synthesis of zirconium(IV) and hafnium(IV) isopropoxide, sec -butoxide and tert -butoxide</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Dhaene, Evert ; Seno, Carlotta ; De Roo, Jonathan</creator><creatorcontrib>Dhaene, Evert ; Seno, Carlotta ; De Roo, Jonathan</creatorcontrib><description>We revisited the synthesis of zirconium(IV) and hafnium(IV) alkoxides, namely the metal isopropoxide isopropanol complex (M(OiPr) ·iPrOH, M = Zr, Hf) and the metal - and -butoxide (M(O Bu) and M(O Bu) , M = Zr, Hf). We optimized the most convenient synthesis methods and compared the products with commercial sources. En route to the metal - and -butoxides, we synthesized the metal diethylamido complex (M(NEt ) , M = Zr, Hf).</description><identifier>ISSN: 1477-9226</identifier><identifier>ISSN: 1477-9234</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d4dt01280a</identifier><identifier>PMID: 38939960</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Alkoxides ; Chemistry ; Hafnium ; Synthesis ; Zirconium</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2024-07, Vol.53 (28), p.11769-11777</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><rights>This journal is © The Royal Society of Chemistry 2024 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c296t-7e4f987efec6613fd17a48441c3d98173ff070a76ebbc7f3d49680eacf08f7b13</cites><orcidid>0000-0002-1604-0408 ; 0000-0002-1264-9312 ; 0000-0002-3565-8086</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,315,781,785,886,27926,27927</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38939960$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dhaene, Evert</creatorcontrib><creatorcontrib>Seno, Carlotta</creatorcontrib><creatorcontrib>De Roo, Jonathan</creatorcontrib><title>Synthesis of zirconium(IV) and hafnium(IV) isopropoxide, sec -butoxide and tert -butoxide</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>We revisited the synthesis of zirconium(IV) and hafnium(IV) alkoxides, namely the metal isopropoxide isopropanol complex (M(OiPr) ·iPrOH, M = Zr, Hf) and the metal - and -butoxide (M(O Bu) and M(O Bu) , M = Zr, Hf). We optimized the most convenient synthesis methods and compared the products with commercial sources. En route to the metal - and -butoxides, we synthesized the metal diethylamido complex (M(NEt ) , M = Zr, Hf).</description><subject>Alkoxides</subject><subject>Chemistry</subject><subject>Hafnium</subject><subject>Synthesis</subject><subject>Zirconium</subject><issn>1477-9226</issn><issn>1477-9234</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpdkVtLwzAUx4Mobk5f_ABS8GWK1aTJmuZJxuZlMPDBKfgU0jRxGW0zk1acn97u4rw8nduPP-ecPwDHCF4iiNlVRrIKoiiBYge0EaE0ZBEmu9s8ilvgwPsZhFEEe9E-aOGEYcZi2AYvj4uymipvfGB18GmctKWpi-7o-SwQZRZMhd7Wxtu5s3P7YTJ1EXglgzCtq1W5Yivlqp_WIdjTIvfqaBM74On2ZjK4D8cPd6NBfxzKiMVVSBXRLKFKKxnHCOsMUUESQpDEGUsQxVpDCgWNVZpKqnFGWJxAJaSGiaYpwh1wvdad12mhMqnKyomcz50phFtwKwz_OynNlL_ad45Q1IOEsUahu1Fw9q1WvuKF8VLluSiVrT3HkOLmobSHG_T0HzqztSub-xoqWboRU9pQ52tKOuu9U3q7DYJ8CfEhGU5WlvUb-OT3_lv02yP8Bf1Okbw</recordid><startdate>20240716</startdate><enddate>20240716</enddate><creator>Dhaene, Evert</creator><creator>Seno, Carlotta</creator><creator>De Roo, Jonathan</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-1604-0408</orcidid><orcidid>https://orcid.org/0000-0002-1264-9312</orcidid><orcidid>https://orcid.org/0000-0002-3565-8086</orcidid></search><sort><creationdate>20240716</creationdate><title>Synthesis of zirconium(IV) and hafnium(IV) isopropoxide, sec -butoxide and tert -butoxide</title><author>Dhaene, Evert ; Seno, Carlotta ; De Roo, Jonathan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c296t-7e4f987efec6613fd17a48441c3d98173ff070a76ebbc7f3d49680eacf08f7b13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Alkoxides</topic><topic>Chemistry</topic><topic>Hafnium</topic><topic>Synthesis</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dhaene, Evert</creatorcontrib><creatorcontrib>Seno, Carlotta</creatorcontrib><creatorcontrib>De Roo, Jonathan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dhaene, Evert</au><au>Seno, Carlotta</au><au>De Roo, Jonathan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of zirconium(IV) and hafnium(IV) isopropoxide, sec -butoxide and tert -butoxide</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2024-07-16</date><risdate>2024</risdate><volume>53</volume><issue>28</issue><spage>11769</spage><epage>11777</epage><pages>11769-11777</pages><issn>1477-9226</issn><issn>1477-9234</issn><eissn>1477-9234</eissn><abstract>We revisited the synthesis of zirconium(IV) and hafnium(IV) alkoxides, namely the metal isopropoxide isopropanol complex (M(OiPr) ·iPrOH, M = Zr, Hf) and the metal - and -butoxide (M(O Bu) and M(O Bu) , M = Zr, Hf). We optimized the most convenient synthesis methods and compared the products with commercial sources. En route to the metal - and -butoxides, we synthesized the metal diethylamido complex (M(NEt ) , M = Zr, Hf).</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38939960</pmid><doi>10.1039/d4dt01280a</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-1604-0408</orcidid><orcidid>https://orcid.org/0000-0002-1264-9312</orcidid><orcidid>https://orcid.org/0000-0002-3565-8086</orcidid><oa>free_for_read</oa></addata></record>
fulltext	fulltext
identifier	ISSN: 1477-9226
ispartof	Dalton transactions : an international journal of inorganic chemistry, 2024-07, Vol.53 (28), p.11769-11777
issn	1477-9226 1477-9234 1477-9234
language	eng
recordid	cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_11250499
source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Alkoxides Chemistry Hafnium Synthesis Zirconium
title	Synthesis of zirconium(IV) and hafnium(IV) isopropoxide, sec -butoxide and tert -butoxide
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-18T10%3A55%3A40IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20zirconium(IV)%20and%20hafnium(IV)%20isopropoxide,%20sec%20-butoxide%20and%20tert%20-butoxide&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Dhaene,%20Evert&rft.date=2024-07-16&rft.volume=53&rft.issue=28&rft.spage=11769&rft.epage=11777&rft.pages=11769-11777&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/d4dt01280a&rft_dat=%3Cproquest_pubme%3E3081039677%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3081039677&rft_id=info:pmid/38939960&rfr_iscdi=true