Zn-Salphen Acrylic Films Powered by Aggregation-Induced Enhanced Emission for Sensing Applications
Zn(II) complexes possess attractive characteristics for supramolecular chemistry, catalysis, and optoelectronic applications, while Zn-Salphen counterparts are also suitable as chemical sensors, although limited by solution-based to date. In this study, we report the synthesis of new polymers from m...
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| Veröffentlicht in: | Journal of fluorescence 2024-07, Vol.34 (4), p.1903-1912 |
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| container_end_page | 1912 |
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| container_issue | 4 |
| container_start_page | 1903 |
| container_title | Journal of fluorescence |
| container_volume | 34 |
| creator | Enríquez-Palacios, Ernesto Robledo-Patiño, Ana Victoria Zelada-Guillén, Gustavo A. |
| description | Zn(II) complexes possess attractive characteristics for supramolecular chemistry, catalysis, and optoelectronic applications, while Zn-Salphen counterparts are also suitable as chemical sensors, although limited by solution-based to date. In this study, we report the synthesis of new polymers from methyl methacrylate,
n
-butyl acrylate, and a non-symmetrical Zn-Salphen complex. We show that this low-fluorescent complex exhibits aggregation-induced emission enhancement (AIEE) properties and that, the incorporation of AIEE complexes into a polymeric matrix make it possible to achieve fluorescent films with enhanced fluorescence suitable for sensing applications. As a proof of concept, these films could detect acetic acid, showing a decrease of up to 73% in the original fluorescence. Host/guest studies showed a subtle disruption of the emission in aggregates upon treatment with anion guests. These results indicate that an interaction between the guest and Zn-Salphen complex may occur, stabilizing or destabilizing the complex and causing a concomitant increase or decrease in emission. |
| doi_str_mv | 10.1007/s10895-023-03399-6 |
| format | Article |
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n
-butyl acrylate, and a non-symmetrical Zn-Salphen complex. We show that this low-fluorescent complex exhibits aggregation-induced emission enhancement (AIEE) properties and that, the incorporation of AIEE complexes into a polymeric matrix make it possible to achieve fluorescent films with enhanced fluorescence suitable for sensing applications. As a proof of concept, these films could detect acetic acid, showing a decrease of up to 73% in the original fluorescence. Host/guest studies showed a subtle disruption of the emission in aggregates upon treatment with anion guests. These results indicate that an interaction between the guest and Zn-Salphen complex may occur, stabilizing or destabilizing the complex and causing a concomitant increase or decrease in emission.</description><identifier>ISSN: 1053-0509</identifier><identifier>ISSN: 1573-4994</identifier><identifier>EISSN: 1573-4994</identifier><identifier>DOI: 10.1007/s10895-023-03399-6</identifier><identifier>PMID: 37665511</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Acetic acid ; Analytical Chemistry ; Biochemistry ; Biological and Medical Physics ; Biomedical and Life Sciences ; Biomedicine ; Biophysics ; Biotechnology ; Chemical sensors ; Chemical synthesis ; Emission ; Fluorescence ; Optoelectronic devices ; Polymethyl methacrylate ; Supramolecular compounds</subject><ispartof>Journal of fluorescence, 2024-07, Vol.34 (4), p.1903-1912</ispartof><rights>The Author(s) 2023</rights><rights>2023. The Author(s).</rights><rights>The Author(s) 2023. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c426t-57f8e6f4cc932a236e5d9e217563eaaee789aa11a8e5932519fd6fdfd51a763a3</cites><orcidid>0000-0001-5113-1535 ; 0000-0001-7270-2544</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10895-023-03399-6$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10895-023-03399-6$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>230,315,781,785,886,27929,27930,41493,42562,51324</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37665511$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Enríquez-Palacios, Ernesto</creatorcontrib><creatorcontrib>Robledo-Patiño, Ana Victoria</creatorcontrib><creatorcontrib>Zelada-Guillén, Gustavo A.</creatorcontrib><title>Zn-Salphen Acrylic Films Powered by Aggregation-Induced Enhanced Emission for Sensing Applications</title><title>Journal of fluorescence</title><addtitle>J Fluoresc</addtitle><addtitle>J Fluoresc</addtitle><description>Zn(II) complexes possess attractive characteristics for supramolecular chemistry, catalysis, and optoelectronic applications, while Zn-Salphen counterparts are also suitable as chemical sensors, although limited by solution-based to date. In this study, we report the synthesis of new polymers from methyl methacrylate,
n
-butyl acrylate, and a non-symmetrical Zn-Salphen complex. We show that this low-fluorescent complex exhibits aggregation-induced emission enhancement (AIEE) properties and that, the incorporation of AIEE complexes into a polymeric matrix make it possible to achieve fluorescent films with enhanced fluorescence suitable for sensing applications. As a proof of concept, these films could detect acetic acid, showing a decrease of up to 73% in the original fluorescence. Host/guest studies showed a subtle disruption of the emission in aggregates upon treatment with anion guests. These results indicate that an interaction between the guest and Zn-Salphen complex may occur, stabilizing or destabilizing the complex and causing a concomitant increase or decrease in emission.</description><subject>Acetic acid</subject><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Biological and Medical Physics</subject><subject>Biomedical and Life Sciences</subject><subject>Biomedicine</subject><subject>Biophysics</subject><subject>Biotechnology</subject><subject>Chemical sensors</subject><subject>Chemical synthesis</subject><subject>Emission</subject><subject>Fluorescence</subject><subject>Optoelectronic devices</subject><subject>Polymethyl methacrylate</subject><subject>Supramolecular compounds</subject><issn>1053-0509</issn><issn>1573-4994</issn><issn>1573-4994</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><recordid>eNp9kU1v3CAQhlHVqEm2_QM9VJZ6yYWUMQbMKVpF-ZIitVLaSy-IxWOvIy-4sG61_z5kNx9NDjkx4n3mHYaXkM_AjoEx9S0Bq7WgrOSUca41le_IAQjFaaV19T7XTGRJML1PDlO6ZYzpuqo_kH2upBQC4IAsfnt6Y4dxib6Yu7gZelec98MqFT_CP4zYFItNMe-6iJ1d98HTK99MLl-f-aX122LVp5SVog2xuEGfet8V83HMTtuO9JHstXZI-OnhnJFf52c_Ty_p9feLq9P5NXVVKddUqLZG2VbOaV7akksUjcYSlJAcrUVUtbYWwNYoMiFAt41sm7YRYJXkls_Iyc53nBYrbBz6dbSDGWO_snFjgu3NS8X3S9OFvwagrHSVv3FGjh4cYvgzYVqbvJvDYbAew5RMWUsmQXFVZfTrK_Q2TNHn_QxnNYDWXKtMlTvKxZBSxPbpNcDMfYZml6HJw802QyNz05f_93hqeQwtA3wHpCz5DuPz7Dds7wBOqaiU</recordid><startdate>20240701</startdate><enddate>20240701</enddate><creator>Enríquez-Palacios, Ernesto</creator><creator>Robledo-Patiño, Ana Victoria</creator><creator>Zelada-Guillén, Gustavo A.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-5113-1535</orcidid><orcidid>https://orcid.org/0000-0001-7270-2544</orcidid></search><sort><creationdate>20240701</creationdate><title>Zn-Salphen Acrylic Films Powered by Aggregation-Induced Enhanced Emission for Sensing Applications</title><author>Enríquez-Palacios, Ernesto ; Robledo-Patiño, Ana Victoria ; Zelada-Guillén, Gustavo A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-57f8e6f4cc932a236e5d9e217563eaaee789aa11a8e5932519fd6fdfd51a763a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Acetic acid</topic><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Biological and Medical Physics</topic><topic>Biomedical and Life Sciences</topic><topic>Biomedicine</topic><topic>Biophysics</topic><topic>Biotechnology</topic><topic>Chemical sensors</topic><topic>Chemical synthesis</topic><topic>Emission</topic><topic>Fluorescence</topic><topic>Optoelectronic devices</topic><topic>Polymethyl methacrylate</topic><topic>Supramolecular compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Enríquez-Palacios, Ernesto</creatorcontrib><creatorcontrib>Robledo-Patiño, Ana Victoria</creatorcontrib><creatorcontrib>Zelada-Guillén, Gustavo A.</creatorcontrib><collection>Springer Nature OA/Free Journals</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Journal of fluorescence</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Enríquez-Palacios, Ernesto</au><au>Robledo-Patiño, Ana Victoria</au><au>Zelada-Guillén, Gustavo A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zn-Salphen Acrylic Films Powered by Aggregation-Induced Enhanced Emission for Sensing Applications</atitle><jtitle>Journal of fluorescence</jtitle><stitle>J Fluoresc</stitle><addtitle>J Fluoresc</addtitle><date>2024-07-01</date><risdate>2024</risdate><volume>34</volume><issue>4</issue><spage>1903</spage><epage>1912</epage><pages>1903-1912</pages><issn>1053-0509</issn><issn>1573-4994</issn><eissn>1573-4994</eissn><abstract>Zn(II) complexes possess attractive characteristics for supramolecular chemistry, catalysis, and optoelectronic applications, while Zn-Salphen counterparts are also suitable as chemical sensors, although limited by solution-based to date. In this study, we report the synthesis of new polymers from methyl methacrylate,
n
-butyl acrylate, and a non-symmetrical Zn-Salphen complex. We show that this low-fluorescent complex exhibits aggregation-induced emission enhancement (AIEE) properties and that, the incorporation of AIEE complexes into a polymeric matrix make it possible to achieve fluorescent films with enhanced fluorescence suitable for sensing applications. As a proof of concept, these films could detect acetic acid, showing a decrease of up to 73% in the original fluorescence. Host/guest studies showed a subtle disruption of the emission in aggregates upon treatment with anion guests. These results indicate that an interaction between the guest and Zn-Salphen complex may occur, stabilizing or destabilizing the complex and causing a concomitant increase or decrease in emission.</abstract><cop>New York</cop><pub>Springer US</pub><pmid>37665511</pmid><doi>10.1007/s10895-023-03399-6</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-5113-1535</orcidid><orcidid>https://orcid.org/0000-0001-7270-2544</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Acetic acid Analytical Chemistry Biochemistry Biological and Medical Physics Biomedical and Life Sciences Biomedicine Biophysics Biotechnology Chemical sensors Chemical synthesis Emission Fluorescence Optoelectronic devices Polymethyl methacrylate Supramolecular compounds |
| title | Zn-Salphen Acrylic Films Powered by Aggregation-Induced Enhanced Emission for Sensing Applications |
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