One-Pot Oxidative Amidation of Aldehydes via the Generation of Nitrile Imine Intermediates

A one-pot procedure for the oxidative amidation of aldehydes via the in situ generation of reactive nitrile imine (NI) intermediates has been developed. Distinct from our progenitor processes, mechanistic and control experiments revealed that the NI undergoes rapid oxidation to an acyl diazene speci...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of organic chemistry 2024-06, Vol.89 (11), p.7913-7926
Hauptverfasser:	Henry, Martyn C., Minty, Laura, Kwok, Alexander C. W., Elwood, Jessica M. L., Foulis, Adam J., Pettinger, Jonathan, Jamieson, Craig
Format:	Artikel
Sprache:	eng
Schlagworte:	imines organic chemistry oxidation species
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!