Synthesis and Properties of the Ba2PrWO6 Double Perovskite
We report details on the synthesis and properties of barium praseodymium tungstate, Ba2PrWO6, a double perovskite that has not been synthesized before. Room-temperature (RT) powder X-ray diffraction identified the most probable space group (SG) as monoclinic I2/m, but it was only slightly distorted...
Gespeichert in:
| Veröffentlicht in: | Inorganic chemistry 2024-06, Vol.63 (22), p.10194-10206 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 10206 |
|---|---|
| container_issue | 22 |
| container_start_page | 10194 |
| container_title | Inorganic chemistry |
| container_volume | 63 |
| creator | Wlodarczyk, Damian Amilusik, Mikolaj Kosyl, Katarzyna M. Chrunik, Maciej Lawniczak-Jablonska, Krystyna Przybylinska, Hanka Kosmela, Paulina Strankowski, Michal Bulyk, Lev-Ivan Tsiumra, Volodymyr Islam, Rajibul Autieri, Carmine Xue, Fei Zajac, Marcin Lysak, Anastasiia Minikayev, Roman Bockowski, Michal Suchocki, Andrzej |
| description | We report details on the synthesis and properties of barium praseodymium tungstate, Ba2PrWO6, a double perovskite that has not been synthesized before. Room-temperature (RT) powder X-ray diffraction identified the most probable space group (SG) as monoclinic I2/m, but it was only slightly distorted from the cubic structure. X-ray photoelectron spectroscopy confirmed that the initial (postsynthesis) material contained praseodymium in both 3+ and 4+ charge states. The former (Pr3+) disappeared after exposure to UV light at RT. Photoluminescence studies of Pr3+ revealed that Ba2PrWO6 is an insulator with a band gap exceeding 4.93 eV. Pressure-dependent Raman spectroscopy excluded the possibility of a phase transition up to 20 GPa; however, measurements between 8 and 873 K signified that there might be a change toward the lower symmetry SG below 200 K. Electron paramagnetic resonance spectra revealed the presence of interstitial oxygen which acts as a deep electron trap. |
| doi_str_mv | 10.1021/acs.inorgchem.4c00567 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_11151198</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3057072574</sourcerecordid><originalsourceid>FETCH-LOGICAL-a333t-fd1815f12e52e60efaebe7e494aed85eba3d40c9b479986c7543623c72747d113</originalsourceid><addsrcrecordid>eNpVkE1Lw0AQhhdRbK3-BCFHL6k72a_Ei2j9hEILKnpbNsmkTU2ydTcp9N-b0iJ4mmHelwfmIeQS6BhoBNcm8-OysW6RLbEe84xSIdURGYKIaCiAfh2TIaX9DlImA3Lm_YpSmjAuT8mAxUoqAXJIbt62TbtEX_rANHkwd3aNri3RB7YI-iC4N9Hcfc5k8GC7tMJgjs5u_HfZ4jk5KUzl8eIwR-Tj6fF98hJOZ8-vk7tpaBhjbVjkEIMoIEIRoaRYGExRIU-4wTwWmBqWc5olKVdJEstMCc5kxDIVKa5yADYit3vuuktrzDNsWmcqvXZlbdxWW1Pq_0lTLvXCbjQACIAk7glXB4KzPx36Vtelz7CqTIO285pRoaiKhOJ9FfbV3q9e2c41_WsaqN5J17vjn3R9kM5-AXKVd7A</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3057072574</pqid></control><display><type>article</type><title>Synthesis and Properties of the Ba2PrWO6 Double Perovskite</title><source>ACS Publications</source><creator>Wlodarczyk, Damian ; Amilusik, Mikolaj ; Kosyl, Katarzyna M. ; Chrunik, Maciej ; Lawniczak-Jablonska, Krystyna ; Przybylinska, Hanka ; Kosmela, Paulina ; Strankowski, Michal ; Bulyk, Lev-Ivan ; Tsiumra, Volodymyr ; Islam, Rajibul ; Autieri, Carmine ; Xue, Fei ; Zajac, Marcin ; Lysak, Anastasiia ; Minikayev, Roman ; Bockowski, Michal ; Suchocki, Andrzej</creator><creatorcontrib>Wlodarczyk, Damian ; Amilusik, Mikolaj ; Kosyl, Katarzyna M. ; Chrunik, Maciej ; Lawniczak-Jablonska, Krystyna ; Przybylinska, Hanka ; Kosmela, Paulina ; Strankowski, Michal ; Bulyk, Lev-Ivan ; Tsiumra, Volodymyr ; Islam, Rajibul ; Autieri, Carmine ; Xue, Fei ; Zajac, Marcin ; Lysak, Anastasiia ; Minikayev, Roman ; Bockowski, Michal ; Suchocki, Andrzej</creatorcontrib><description>We report details on the synthesis and properties of barium praseodymium tungstate, Ba2PrWO6, a double perovskite that has not been synthesized before. Room-temperature (RT) powder X-ray diffraction identified the most probable space group (SG) as monoclinic I2/m, but it was only slightly distorted from the cubic structure. X-ray photoelectron spectroscopy confirmed that the initial (postsynthesis) material contained praseodymium in both 3+ and 4+ charge states. The former (Pr3+) disappeared after exposure to UV light at RT. Photoluminescence studies of Pr3+ revealed that Ba2PrWO6 is an insulator with a band gap exceeding 4.93 eV. Pressure-dependent Raman spectroscopy excluded the possibility of a phase transition up to 20 GPa; however, measurements between 8 and 873 K signified that there might be a change toward the lower symmetry SG below 200 K. Electron paramagnetic resonance spectra revealed the presence of interstitial oxygen which acts as a deep electron trap.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/acs.inorgchem.4c00567</identifier><identifier>PMID: 38767516</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Inorganic chemistry, 2024-06, Vol.63 (22), p.10194-10206</ispartof><rights>2024 The Authors. Published by American Chemical Society</rights><rights>2024 The Authors. Published by American Chemical Society 2024 The Authors</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-5923-7569 ; 0000-0002-5008-8165 ; 0000-0001-7126-1951 ; 0000-0002-3114-6526</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.4c00567$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.inorgchem.4c00567$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,315,781,785,886,27081,27929,27930,56743,56793</link.rule.ids></links><search><creatorcontrib>Wlodarczyk, Damian</creatorcontrib><creatorcontrib>Amilusik, Mikolaj</creatorcontrib><creatorcontrib>Kosyl, Katarzyna M.</creatorcontrib><creatorcontrib>Chrunik, Maciej</creatorcontrib><creatorcontrib>Lawniczak-Jablonska, Krystyna</creatorcontrib><creatorcontrib>Przybylinska, Hanka</creatorcontrib><creatorcontrib>Kosmela, Paulina</creatorcontrib><creatorcontrib>Strankowski, Michal</creatorcontrib><creatorcontrib>Bulyk, Lev-Ivan</creatorcontrib><creatorcontrib>Tsiumra, Volodymyr</creatorcontrib><creatorcontrib>Islam, Rajibul</creatorcontrib><creatorcontrib>Autieri, Carmine</creatorcontrib><creatorcontrib>Xue, Fei</creatorcontrib><creatorcontrib>Zajac, Marcin</creatorcontrib><creatorcontrib>Lysak, Anastasiia</creatorcontrib><creatorcontrib>Minikayev, Roman</creatorcontrib><creatorcontrib>Bockowski, Michal</creatorcontrib><creatorcontrib>Suchocki, Andrzej</creatorcontrib><title>Synthesis and Properties of the Ba2PrWO6 Double Perovskite</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>We report details on the synthesis and properties of barium praseodymium tungstate, Ba2PrWO6, a double perovskite that has not been synthesized before. Room-temperature (RT) powder X-ray diffraction identified the most probable space group (SG) as monoclinic I2/m, but it was only slightly distorted from the cubic structure. X-ray photoelectron spectroscopy confirmed that the initial (postsynthesis) material contained praseodymium in both 3+ and 4+ charge states. The former (Pr3+) disappeared after exposure to UV light at RT. Photoluminescence studies of Pr3+ revealed that Ba2PrWO6 is an insulator with a band gap exceeding 4.93 eV. Pressure-dependent Raman spectroscopy excluded the possibility of a phase transition up to 20 GPa; however, measurements between 8 and 873 K signified that there might be a change toward the lower symmetry SG below 200 K. Electron paramagnetic resonance spectra revealed the presence of interstitial oxygen which acts as a deep electron trap.</description><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpVkE1Lw0AQhhdRbK3-BCFHL6k72a_Ei2j9hEILKnpbNsmkTU2ydTcp9N-b0iJ4mmHelwfmIeQS6BhoBNcm8-OysW6RLbEe84xSIdURGYKIaCiAfh2TIaX9DlImA3Lm_YpSmjAuT8mAxUoqAXJIbt62TbtEX_rANHkwd3aNri3RB7YI-iC4N9Hcfc5k8GC7tMJgjs5u_HfZ4jk5KUzl8eIwR-Tj6fF98hJOZ8-vk7tpaBhjbVjkEIMoIEIRoaRYGExRIU-4wTwWmBqWc5olKVdJEstMCc5kxDIVKa5yADYit3vuuktrzDNsWmcqvXZlbdxWW1Pq_0lTLvXCbjQACIAk7glXB4KzPx36Vtelz7CqTIO285pRoaiKhOJ9FfbV3q9e2c41_WsaqN5J17vjn3R9kM5-AXKVd7A</recordid><startdate>20240603</startdate><enddate>20240603</enddate><creator>Wlodarczyk, Damian</creator><creator>Amilusik, Mikolaj</creator><creator>Kosyl, Katarzyna M.</creator><creator>Chrunik, Maciej</creator><creator>Lawniczak-Jablonska, Krystyna</creator><creator>Przybylinska, Hanka</creator><creator>Kosmela, Paulina</creator><creator>Strankowski, Michal</creator><creator>Bulyk, Lev-Ivan</creator><creator>Tsiumra, Volodymyr</creator><creator>Islam, Rajibul</creator><creator>Autieri, Carmine</creator><creator>Xue, Fei</creator><creator>Zajac, Marcin</creator><creator>Lysak, Anastasiia</creator><creator>Minikayev, Roman</creator><creator>Bockowski, Michal</creator><creator>Suchocki, Andrzej</creator><general>American Chemical Society</general><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-5923-7569</orcidid><orcidid>https://orcid.org/0000-0002-5008-8165</orcidid><orcidid>https://orcid.org/0000-0001-7126-1951</orcidid><orcidid>https://orcid.org/0000-0002-3114-6526</orcidid></search><sort><creationdate>20240603</creationdate><title>Synthesis and Properties of the Ba2PrWO6 Double Perovskite</title><author>Wlodarczyk, Damian ; Amilusik, Mikolaj ; Kosyl, Katarzyna M. ; Chrunik, Maciej ; Lawniczak-Jablonska, Krystyna ; Przybylinska, Hanka ; Kosmela, Paulina ; Strankowski, Michal ; Bulyk, Lev-Ivan ; Tsiumra, Volodymyr ; Islam, Rajibul ; Autieri, Carmine ; Xue, Fei ; Zajac, Marcin ; Lysak, Anastasiia ; Minikayev, Roman ; Bockowski, Michal ; Suchocki, Andrzej</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a333t-fd1815f12e52e60efaebe7e494aed85eba3d40c9b479986c7543623c72747d113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wlodarczyk, Damian</creatorcontrib><creatorcontrib>Amilusik, Mikolaj</creatorcontrib><creatorcontrib>Kosyl, Katarzyna M.</creatorcontrib><creatorcontrib>Chrunik, Maciej</creatorcontrib><creatorcontrib>Lawniczak-Jablonska, Krystyna</creatorcontrib><creatorcontrib>Przybylinska, Hanka</creatorcontrib><creatorcontrib>Kosmela, Paulina</creatorcontrib><creatorcontrib>Strankowski, Michal</creatorcontrib><creatorcontrib>Bulyk, Lev-Ivan</creatorcontrib><creatorcontrib>Tsiumra, Volodymyr</creatorcontrib><creatorcontrib>Islam, Rajibul</creatorcontrib><creatorcontrib>Autieri, Carmine</creatorcontrib><creatorcontrib>Xue, Fei</creatorcontrib><creatorcontrib>Zajac, Marcin</creatorcontrib><creatorcontrib>Lysak, Anastasiia</creatorcontrib><creatorcontrib>Minikayev, Roman</creatorcontrib><creatorcontrib>Bockowski, Michal</creatorcontrib><creatorcontrib>Suchocki, Andrzej</creatorcontrib><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wlodarczyk, Damian</au><au>Amilusik, Mikolaj</au><au>Kosyl, Katarzyna M.</au><au>Chrunik, Maciej</au><au>Lawniczak-Jablonska, Krystyna</au><au>Przybylinska, Hanka</au><au>Kosmela, Paulina</au><au>Strankowski, Michal</au><au>Bulyk, Lev-Ivan</au><au>Tsiumra, Volodymyr</au><au>Islam, Rajibul</au><au>Autieri, Carmine</au><au>Xue, Fei</au><au>Zajac, Marcin</au><au>Lysak, Anastasiia</au><au>Minikayev, Roman</au><au>Bockowski, Michal</au><au>Suchocki, Andrzej</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Properties of the Ba2PrWO6 Double Perovskite</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2024-06-03</date><risdate>2024</risdate><volume>63</volume><issue>22</issue><spage>10194</spage><epage>10206</epage><pages>10194-10206</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>We report details on the synthesis and properties of barium praseodymium tungstate, Ba2PrWO6, a double perovskite that has not been synthesized before. Room-temperature (RT) powder X-ray diffraction identified the most probable space group (SG) as monoclinic I2/m, but it was only slightly distorted from the cubic structure. X-ray photoelectron spectroscopy confirmed that the initial (postsynthesis) material contained praseodymium in both 3+ and 4+ charge states. The former (Pr3+) disappeared after exposure to UV light at RT. Photoluminescence studies of Pr3+ revealed that Ba2PrWO6 is an insulator with a band gap exceeding 4.93 eV. Pressure-dependent Raman spectroscopy excluded the possibility of a phase transition up to 20 GPa; however, measurements between 8 and 873 K signified that there might be a change toward the lower symmetry SG below 200 K. Electron paramagnetic resonance spectra revealed the presence of interstitial oxygen which acts as a deep electron trap.</abstract><pub>American Chemical Society</pub><pmid>38767516</pmid><doi>10.1021/acs.inorgchem.4c00567</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0002-5923-7569</orcidid><orcidid>https://orcid.org/0000-0002-5008-8165</orcidid><orcidid>https://orcid.org/0000-0001-7126-1951</orcidid><orcidid>https://orcid.org/0000-0002-3114-6526</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0020-1669 |
| ispartof | Inorganic chemistry, 2024-06, Vol.63 (22), p.10194-10206 |
| issn | 0020-1669 1520-510X |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_11151198 |
| source | ACS Publications |
| title | Synthesis and Properties of the Ba2PrWO6 Double Perovskite |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-15T08%3A23%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20Properties%20of%20the%20Ba2PrWO6%20Double%20Perovskite&rft.jtitle=Inorganic%20chemistry&rft.au=Wlodarczyk,%20Damian&rft.date=2024-06-03&rft.volume=63&rft.issue=22&rft.spage=10194&rft.epage=10206&rft.pages=10194-10206&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/acs.inorgchem.4c00567&rft_dat=%3Cproquest_pubme%3E3057072574%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3057072574&rft_id=info:pmid/38767516&rfr_iscdi=true |