Structure and photochemistry of di- tert -butyldiphosphatetrahedrane

Di- -butyldiphosphatetrahedrane ( BuCP) (1) is a mixed carbon- and phosphorus-based tetrahedral molecule, isolobal to white phosphorus (P ). However, despite the fundamental significance and well-explored reactivity of the latter molecule, the precise structure of the free ( BuCP) molecule (1) and a...

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Veröffentlicht in:	Chemical science (Cambridge) 2024-04, Vol.15 (15), p.5596-5603
Hauptverfasser:	Hierlmeier, Gabriele, Kutta, Roger Jan, Coburger, Peter, Stammler, Hans-Georg, Schwabedissen, Jan, Mitzel, Norbert W, Dimitrova, Maria, Berger, Raphael J F, Nuernberger, Patrick, Wolf, Robert
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromaticity Chemistry Cycloaddition Diamagnetism Dimerization Isomerization Low temperature Molecular structure Phosphaalkynes Phosphorus Photochemistry Quantum chemistry Single crystals Ultraviolet radiation
Online-Zugang:	Volltext
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