Improving the Corrosion Performance of Organically Coated Steel Using a Sol-Gel Overcoat
Organically coated steels are widely used in applications in which they are subjected to the natural environment and therefore require excellent corrosion resistance. Organic clearcoats are typically employed as a barrier that improves the overall corrosion resistance; however, they are typically de...
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Veröffentlicht in: | Materials 2024-02, Vol.17 (5), p.1075 |
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description | Organically coated steels are widely used in applications in which they are subjected to the natural environment and therefore require excellent corrosion resistance. Organic clearcoats are typically employed as a barrier that improves the overall corrosion resistance; however, they are typically derived from fossil fuel-based feedstock. A more sustainable alternative could be possible using sol-gel coatings. The application of a simple tetraethoxysilane (TEOS)-based sol-gel was applied to polyurethane-coated steels using a spray coater. The concentration of TEOS was altered to produce coatings containing either 2.5% or 10%. The 10% TEOS resulted in dense, homogeneous coatings that offered a significant improvement in corrosion resistance compared to an uncoated substrate. Whereas the 2.5% TEOS coatings were inhomogeneous and porous, which indicated a limitation of concentration required to produce a uniform coating. The successful demonstration of using a simple TEOS-based coating to improve the corrosion resistance of organically coated steel highlights the potential for further investigation into the use of sol-gels for these applications. |
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Organic clearcoats are typically employed as a barrier that improves the overall corrosion resistance; however, they are typically derived from fossil fuel-based feedstock. A more sustainable alternative could be possible using sol-gel coatings. The application of a simple tetraethoxysilane (TEOS)-based sol-gel was applied to polyurethane-coated steels using a spray coater. The concentration of TEOS was altered to produce coatings containing either 2.5% or 10%. The 10% TEOS resulted in dense, homogeneous coatings that offered a significant improvement in corrosion resistance compared to an uncoated substrate. Whereas the 2.5% TEOS coatings were inhomogeneous and porous, which indicated a limitation of concentration required to produce a uniform coating. The successful demonstration of using a simple TEOS-based coating to improve the corrosion resistance of organically coated steel highlights the potential for further investigation into the use of sol-gels for these applications.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma17051075</identifier><identifier>PMID: 38473547</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Aesthetics ; Carbon footprint ; Corrosion ; Corrosion inhibitors ; Corrosion resistance ; Corrosion resistant steels ; Gels ; Interferometry ; Ovens & stoves ; Polyurethane resins ; Polyurethanes ; Protective coatings ; Scanning electron microscopy ; Silica ; Silicon ; Sol-gel processes ; Steel ; Substrates ; Tetraethyl orthosilicate</subject><ispartof>Materials, 2024-02, Vol.17 (5), p.1075</ispartof><rights>COPYRIGHT 2024 MDPI AG</rights><rights>2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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Organic clearcoats are typically employed as a barrier that improves the overall corrosion resistance; however, they are typically derived from fossil fuel-based feedstock. A more sustainable alternative could be possible using sol-gel coatings. The application of a simple tetraethoxysilane (TEOS)-based sol-gel was applied to polyurethane-coated steels using a spray coater. The concentration of TEOS was altered to produce coatings containing either 2.5% or 10%. The 10% TEOS resulted in dense, homogeneous coatings that offered a significant improvement in corrosion resistance compared to an uncoated substrate. Whereas the 2.5% TEOS coatings were inhomogeneous and porous, which indicated a limitation of concentration required to produce a uniform coating. The successful demonstration of using a simple TEOS-based coating to improve the corrosion resistance of organically coated steel highlights the potential for further investigation into the use of sol-gels for these applications.</description><subject>Aesthetics</subject><subject>Carbon footprint</subject><subject>Corrosion</subject><subject>Corrosion inhibitors</subject><subject>Corrosion resistance</subject><subject>Corrosion resistant steels</subject><subject>Gels</subject><subject>Interferometry</subject><subject>Ovens & stoves</subject><subject>Polyurethane resins</subject><subject>Polyurethanes</subject><subject>Protective coatings</subject><subject>Scanning electron microscopy</subject><subject>Silica</subject><subject>Silicon</subject><subject>Sol-gel processes</subject><subject>Steel</subject><subject>Substrates</subject><subject>Tetraethyl orthosilicate</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkV1rHCEUhqU0NCHNTX9AGehNKUyqozPqVQlL8wGBDaSB3skZ58zG4OhWZxfy7-OyaZJWLzzq8756ziHkE6OnnGv6fQImacuobN-RI6Z1VzMtxPs38SE5yfmBlsE5U43-QA65EpK3Qh6R31fTOsWtC6tqvsdqEVOK2cVQ3WAaY5ogWKziWC3TCoKz4P1jgWDGobqdEX11l3daqG6jry_KfrnFZAvwkRyM4DOePK_H5O7856_FZX29vLhanF3XVtB2rpW0FFpBOSrLsWl60YBmVg-jldD0shv6QVo-MLvjqVWMjozSXg296IADPyY_9r7rTT_hYDHMCbxZJzdBejQRnPn3Jrh7s4pbw6jmQsimOHx9dkjxzwbzbCaXLXoPAeMmm0a3XVcKprqCfvkPfYibFEp-O6pVWjLFCnW6p1bg0bgwxvKwLXPAydkYcHTl_KwYCi5lK4rg215gS_FzwvHl-4yaXZfNa5cL_Pltwi_o357yJy8OoeA</recordid><startdate>20240226</startdate><enddate>20240226</enddate><creator>Watkins, Evan</creator><creator>Griffiths, Chris M</creator><creator>Richards, Calvin A J</creator><creator>Potts, Sarah-Jane</creator><creator>Batchelor, Chris</creator><creator>Barker, Peter</creator><creator>Searle, Justin</creator><creator>Jewell, Eifion</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0009-0000-5202-2357</orcidid><orcidid>https://orcid.org/0000-0003-0208-2364</orcidid><orcidid>https://orcid.org/0000-0002-6894-2251</orcidid><orcidid>https://orcid.org/0000-0002-2257-3913</orcidid><orcidid>https://orcid.org/0000-0003-1101-075X</orcidid></search><sort><creationdate>20240226</creationdate><title>Improving the Corrosion Performance of Organically Coated Steel Using a Sol-Gel Overcoat</title><author>Watkins, Evan ; 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subjects | Aesthetics Carbon footprint Corrosion Corrosion inhibitors Corrosion resistance Corrosion resistant steels Gels Interferometry Ovens & stoves Polyurethane resins Polyurethanes Protective coatings Scanning electron microscopy Silica Silicon Sol-gel processes Steel Substrates Tetraethyl orthosilicate |
title | Improving the Corrosion Performance of Organically Coated Steel Using a Sol-Gel Overcoat |
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