Uncovering a CF3 Effect on X-ray Absorption Energies of [Cu(CF3)4]− and Related Cu Compounds Using Resonant Diffraction Anomalous Fine Structure (DAFS) Measurements

Understanding the electronic structures of high-valent metal complexes aids the advancement of metal-catalyzed cross coupling methodologies. A prototypical complex with formally high valency is [Cu(CF 3 ) 4 ] − ( 1 ), which has a formal Cu(III) oxidation state but whose physical analysis has led som...

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Veröffentlicht in:	Angewandte Chemie International Edition 2023-11, Vol.62 (51), p.e202313744-e202313744
Hauptverfasser:	Alayoglu, Pinar, Chang, Tieyan, Yan, Connly, Chen, Yu-Sheng, Mankad, Neal P.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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