Lewis-acid-catalyzed phosphorylation of alcohols
An efficient method has been developed for reacting dialkyl H-phosphonates or diarylphosphine oxides with alcohols for constructing C-P bonds. This reaction was catalyzed by Lewis acid and involved nucleophilic substitution. A series of diphenylphosphonates and diphenylphosphine oxides were obtained...
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| Veröffentlicht in: | RSC advances 2024-01, Vol.14 (6), p.3757-376 |
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| container_end_page | 376 |
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| container_issue | 6 |
| container_start_page | 3757 |
| container_title | RSC advances |
| container_volume | 14 |
| creator | Wang, Xiao-Hong Liu, Xuan Xue, Ya-Wen Wang, Yan-Bin Wei, Xiao-Hong Su, Qiong |
| description | An efficient method has been developed for reacting dialkyl H-phosphonates or diarylphosphine oxides with alcohols for constructing C-P bonds. This reaction was catalyzed by Lewis acid and involved nucleophilic substitution. A series of diphenylphosphonates and diphenylphosphine oxides were obtained, from the phosphorylation of alcohols, with good-to-excellent yields.
An efficient method has been developed for reacting dialkyl H-phosphonates or diarylphosphine oxides with alcohols for constructing C-P bonds. |
| doi_str_mv | 10.1039/d3ra08214h |
| format | Article |
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An efficient method has been developed for reacting dialkyl H-phosphonates or diarylphosphine oxides with alcohols for constructing C-P bonds.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d3ra08214h</identifier><identifier>PMID: 38268541</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Alcohols ; Chemistry ; Lewis acid ; Phosphonates ; Phosphorylation ; Substitution reactions</subject><ispartof>RSC advances, 2024-01, Vol.14 (6), p.3757-376</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2024</rights><rights>This journal is © The Royal Society of Chemistry 2024 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c429t-9e3a376b9b6a885f620937cf80d77327c2700839ff76628a4c404b7e1cfc1a393</citedby><cites>FETCH-LOGICAL-c429t-9e3a376b9b6a885f620937cf80d77327c2700839ff76628a4c404b7e1cfc1a393</cites><orcidid>0000-0002-5680-9509</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10807371/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10807371/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38268541$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Xiao-Hong</creatorcontrib><creatorcontrib>Liu, Xuan</creatorcontrib><creatorcontrib>Xue, Ya-Wen</creatorcontrib><creatorcontrib>Wang, Yan-Bin</creatorcontrib><creatorcontrib>Wei, Xiao-Hong</creatorcontrib><creatorcontrib>Su, Qiong</creatorcontrib><title>Lewis-acid-catalyzed phosphorylation of alcohols</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>An efficient method has been developed for reacting dialkyl H-phosphonates or diarylphosphine oxides with alcohols for constructing C-P bonds. This reaction was catalyzed by Lewis acid and involved nucleophilic substitution. A series of diphenylphosphonates and diphenylphosphine oxides were obtained, from the phosphorylation of alcohols, with good-to-excellent yields.
An efficient method has been developed for reacting dialkyl H-phosphonates or diarylphosphine oxides with alcohols for constructing C-P bonds.</description><subject>Alcohols</subject><subject>Chemistry</subject><subject>Lewis acid</subject><subject>Phosphonates</subject><subject>Phosphorylation</subject><subject>Substitution reactions</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpdkd1LwzAUxYMobsy9-K4MfBGhepO0-XiSMT8mDATR55Cmqevompm0yvzr7dyc08Algfvj3JN7EDrGcImByquMeg2C4Hi6h7oEYhYRYHJ_591B_RBm0B6WYMLwIepQQZhIYtxFMLEfRYi0KbLI6FqXy0-bDRZTF9ryy1LXhasGLh_o0ripK8MROsh1GWx_c_fQy93t82gcTR7vH0bDSWRiIutIWqopZ6lMmRYiyRkBSbnJBWScU8IN4QCCyjznjBGhYxNDnHKLTW6wppL20PVad9Gkc5sZW9Vel2rhi7n2S-V0of52qmKqXt27wiCAU45bhfONgndvjQ21mhfB2LLUlXVNUERikWDgZDXs7B86c42v2v-1FAEscMJZS12sKeNdCN7mWzcY1CoMdUOfht9hjFv4dNf_Fv1ZfQucrAEfzLb7myb9AvHfjQ4</recordid><startdate>20240123</startdate><enddate>20240123</enddate><creator>Wang, Xiao-Hong</creator><creator>Liu, Xuan</creator><creator>Xue, Ya-Wen</creator><creator>Wang, Yan-Bin</creator><creator>Wei, Xiao-Hong</creator><creator>Su, Qiong</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-5680-9509</orcidid></search><sort><creationdate>20240123</creationdate><title>Lewis-acid-catalyzed phosphorylation of alcohols</title><author>Wang, Xiao-Hong ; Liu, Xuan ; Xue, Ya-Wen ; Wang, Yan-Bin ; Wei, Xiao-Hong ; Su, Qiong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c429t-9e3a376b9b6a885f620937cf80d77327c2700839ff76628a4c404b7e1cfc1a393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Alcohols</topic><topic>Chemistry</topic><topic>Lewis acid</topic><topic>Phosphonates</topic><topic>Phosphorylation</topic><topic>Substitution reactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Xiao-Hong</creatorcontrib><creatorcontrib>Liu, Xuan</creatorcontrib><creatorcontrib>Xue, Ya-Wen</creatorcontrib><creatorcontrib>Wang, Yan-Bin</creatorcontrib><creatorcontrib>Wei, Xiao-Hong</creatorcontrib><creatorcontrib>Su, Qiong</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Xiao-Hong</au><au>Liu, Xuan</au><au>Xue, Ya-Wen</au><au>Wang, Yan-Bin</au><au>Wei, Xiao-Hong</au><au>Su, Qiong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lewis-acid-catalyzed phosphorylation of alcohols</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2024-01-23</date><risdate>2024</risdate><volume>14</volume><issue>6</issue><spage>3757</spage><epage>376</epage><pages>3757-376</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>An efficient method has been developed for reacting dialkyl H-phosphonates or diarylphosphine oxides with alcohols for constructing C-P bonds. This reaction was catalyzed by Lewis acid and involved nucleophilic substitution. A series of diphenylphosphonates and diphenylphosphine oxides were obtained, from the phosphorylation of alcohols, with good-to-excellent yields.
An efficient method has been developed for reacting dialkyl H-phosphonates or diarylphosphine oxides with alcohols for constructing C-P bonds.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38268541</pmid><doi>10.1039/d3ra08214h</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-5680-9509</orcidid><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 2046-2069 |
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| language | eng |
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| source | DOAJ Directory of Open Access Journals; EZB-FREE-00999 freely available EZB journals; PubMed Central; PubMed Central Open Access |
| subjects | Alcohols Chemistry Lewis acid Phosphonates Phosphorylation Substitution reactions |
| title | Lewis-acid-catalyzed phosphorylation of alcohols |
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