Photochemical H2 activation by an Zn–Fe heterometallic: a mechanistic investigation

Addition of H2 to a Zn–Fe complex was observed to occur under photochemical conditions (390 or 428 nm LED) and leads to the formation of a heterometallic dihydride complex. The reaction does not occur under thermal conditions and DFT calculations suggest this is an endergonic, light driven process....

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Veröffentlicht in:	Chemical science (Cambridge) 2024-01, Vol.15 (4), p.1424-1430
Hauptverfasser:	Perez-Jimenez, Marina, Crimmin, Mark R
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Dihydrides Mathematical analysis Zinc
Online-Zugang:	Volltext
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