Aminodealkenylation: Ozonolysis and copper catalysis convert C(sp 3 )-C(sp 2 ) bonds to C(sp 3 )-N bonds

Great efforts have been directed toward alkene π bond amination. In contrast, analogous functionalization of the adjacent C(sp )-C(sp ) σ bonds is much rarer. Here we report how ozonolysis and copper catalysis under mild reaction conditions enable alkene C(sp )-C(sp ) σ bond-rupturing cross-coupling...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2023-08, Vol.381 (6660), p.877-886
Hauptverfasser:	He, Zhiqi, Moreno, Jose Antonio, Swain, Manisha, Wu, Jason, Kwon, Ohyun
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Carbon Carbon compounds Catalysis Copper Copper converters Nitrogen Terpenes
Online-Zugang:	Volltext
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