Peculiar Structural Phase of a Single-Atom-Thick Layer of Antimony

Peculiar Structural Phase of a Single-Atom-Thick Layer of Antimony

Using molecular beam epitaxy, a new structural phase of a single atom thick antimony layer has been synthesized on the W(110) surface. Scanning tunneling microscopy measurements reveal an atomically resolved structure with a perfectly flat surface and unusually large unit cell. The structure forms a...

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Veröffentlicht in:Nano letters 2023-11, Vol.23 (21), p.9894-9899
Hauptverfasser: Stȩpniak-Dybala, Agnieszka, Jaroch, Tomasz, Krawiec, Mariusz, Dróżdż, Piotr, Gołȩbiowski, Mariusz, Zdyb, Ryszard
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container_end_page 9899
container_issue 21
container_start_page 9894
container_title Nano letters
container_volume 23
creator Stȩpniak-Dybala, Agnieszka
Jaroch, Tomasz
Krawiec, Mariusz
Dróżdż, Piotr
Gołȩbiowski, Mariusz
Zdyb, Ryszard
description Using molecular beam epitaxy, a new structural phase of a single atom thick antimony layer has been synthesized on the W(110) surface. Scanning tunneling microscopy measurements reveal an atomically resolved structure with a perfectly flat surface and unusually large unit cell. The structure forms a well-ordered continuous film with a lateral size in the range of several millimeters, as revealed by low energy electron microscopy and diffraction experiments. The results of density functional theory calculations confirm the formation of a new phase of single-atom-thick antimony film without the buckling characteristic for the known phases of antimonene. The presented results demonstrate a substrate-tuned approach in the preparation of new structural phases of 2D materials.
doi_str_mv 10.1021/acs.nanolett.3c02847
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title Peculiar Structural Phase of a Single-Atom-Thick Layer of Antimony
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