Nickel(II) and Palladium(II) Complexes with η5:κ1(N)-Coordinated Dicarbollide Ligands Containing Pendant Pyridine Group
A series of C- and B-substituted nido-carborane derivatives with a pendant pyridyl group was prepared. The synthesized compounds were used as ligands in the complexation reactions with bis(triphenylphosphine)nickel(II) and palladium(II) chlorides to give six new metallacomplexes with unusual η5:κ1(N...
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| Veröffentlicht in: | International journal of molecular sciences 2023-10, Vol.24 (20), p.15069 |
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| creator | Semyonov, Dmitriy K. Stogniy, Marina Yu Anufriev, Sergey A. Timofeev, Sergey V. Suponitsky, Kyrill Yu Sivaev, Igor B. |
| description | A series of C- and B-substituted nido-carborane derivatives with a pendant pyridyl group was prepared. The synthesized compounds were used as ligands in the complexation reactions with bis(triphenylphosphine)nickel(II) and palladium(II) chlorides to give six new metallacomplexes with unusual η5:κ1(N)-coordination of the metal center. The single crystal structures of 1-(NC5H4-2′-S)-1,2-C2B10H11, 1-(NC5H4-2′-CH2S)-1,2-C2B10H11, Cs [7-(NC5H4-2′-CH2S)-7,8-C2B9H11] closo- and nido-carboranes and 3-Ph3P-3-(4(7)-NC5H4-2′-S)-closo-3,1,2-NiC2B9H10 and 3-Ph3P-3-(4(7)-NC5H4-2′-CH2S)-closo-3,1,2-NiC2B9H10 metallacarboranes were determined using single crystal X-ray diffraction. |
| doi_str_mv | 10.3390/ijms242015069 |
| format | Article |
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The synthesized compounds were used as ligands in the complexation reactions with bis(triphenylphosphine)nickel(II) and palladium(II) chlorides to give six new metallacomplexes with unusual η5:κ1(N)-coordination of the metal center. The single crystal structures of 1-(NC5H4-2′-S)-1,2-C2B10H11, 1-(NC5H4-2′-CH2S)-1,2-C2B10H11, Cs [7-(NC5H4-2′-CH2S)-7,8-C2B9H11] closo- and nido-carboranes and 3-Ph3P-3-(4(7)-NC5H4-2′-S)-closo-3,1,2-NiC2B9H10 and 3-Ph3P-3-(4(7)-NC5H4-2′-CH2S)-closo-3,1,2-NiC2B9H10 metallacarboranes were determined using single crystal X-ray diffraction.</description><identifier>ISSN: 1422-0067</identifier><identifier>ISSN: 1661-6596</identifier><identifier>EISSN: 1422-0067</identifier><identifier>DOI: 10.3390/ijms242015069</identifier><identifier>PMID: 37894752</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Boron ; Carbon ; Ligands ; Mass spectrometry ; Nickel ; Scientific imaging ; Single crystals</subject><ispartof>International journal of molecular sciences, 2023-10, Vol.24 (20), p.15069</ispartof><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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The single crystal structures of 1-(NC5H4-2′-S)-1,2-C2B10H11, 1-(NC5H4-2′-CH2S)-1,2-C2B10H11, Cs [7-(NC5H4-2′-CH2S)-7,8-C2B9H11] closo- and nido-carboranes and 3-Ph3P-3-(4(7)-NC5H4-2′-S)-closo-3,1,2-NiC2B9H10 and 3-Ph3P-3-(4(7)-NC5H4-2′-CH2S)-closo-3,1,2-NiC2B9H10 metallacarboranes were determined using single crystal X-ray diffraction.</description><subject>Boron</subject><subject>Carbon</subject><subject>Ligands</subject><subject>Mass spectrometry</subject><subject>Nickel</subject><subject>Scientific imaging</subject><subject>Single crystals</subject><issn>1422-0067</issn><issn>1661-6596</issn><issn>1422-0067</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>BENPR</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNpdkctuEzEUhq2qiJaWZfeW2KSLAV_GY5tNVQUokaI2C1hbHtuTOszYwZ4B8mSV-hB9JhxaIcrqHJ3z_b_OBYAzjN5SKtE7vxkyqQnCDDXyABzjmpAKoYYf_pMfgVc5bxAilDD5EhxRLmTNGTkGu2tvvrl-tlicQx0sXOm-19ZPw5_KPA7b3v1yGf704y18uGPvH-7x7Pq8mseYrA96dBZ-8EanNva9tw4u_br45CINo_bBhzVcuWB1GOFql3zROHiV4rQ9BS863Wf3-imegK-fPn6Zf66WN1eL-eWyMoTLsSKWt4iYpradQZgTYmqjhWk7I2uCtcCWNE5KLihinErpmNO87WQRi65rBD0BF4--26kdnDUujEn3apv8oNNORe3V807wt2odfyiMGtTUiBaH2ZNDit8nl0c1-GxcOVRwccqKCEGZqBnbo2_-QzdxSqHst6fK8QvVFKp6pEyKOSfX_Z0GI7X_qnr2VfobmRqVOg</recordid><startdate>20231011</startdate><enddate>20231011</enddate><creator>Semyonov, Dmitriy K.</creator><creator>Stogniy, Marina Yu</creator><creator>Anufriev, Sergey A.</creator><creator>Timofeev, Sergey V.</creator><creator>Suponitsky, Kyrill Yu</creator><creator>Sivaev, Igor B.</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8G5</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>M2O</scope><scope>MBDVC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-0617-0118</orcidid><orcidid>https://orcid.org/0000-0002-5442-367X</orcidid><orcidid>https://orcid.org/0000-0002-6699-7910</orcidid><orcidid>https://orcid.org/0000-0002-6386-7301</orcidid></search><sort><creationdate>20231011</creationdate><title>Nickel(II) and Palladium(II) Complexes with η5:κ1(N)-Coordinated Dicarbollide Ligands Containing Pendant Pyridine Group</title><author>Semyonov, Dmitriy K. ; Stogniy, Marina Yu ; Anufriev, Sergey A. ; Timofeev, Sergey V. ; Suponitsky, Kyrill Yu ; Sivaev, Igor B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c279t-2d7b02c64dfc01722c4ca8cbfc9421a81d26e99783057399e5ea7bf92798ff683</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Boron</topic><topic>Carbon</topic><topic>Ligands</topic><topic>Mass spectrometry</topic><topic>Nickel</topic><topic>Scientific imaging</topic><topic>Single crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Semyonov, Dmitriy K.</creatorcontrib><creatorcontrib>Stogniy, Marina Yu</creatorcontrib><creatorcontrib>Anufriev, Sergey A.</creatorcontrib><creatorcontrib>Timofeev, Sergey V.</creatorcontrib><creatorcontrib>Suponitsky, Kyrill Yu</creatorcontrib><creatorcontrib>Sivaev, Igor B.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Research Library</collection><collection>Research Library (Corporate)</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>International journal of molecular sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Semyonov, Dmitriy K.</au><au>Stogniy, Marina Yu</au><au>Anufriev, Sergey A.</au><au>Timofeev, Sergey V.</au><au>Suponitsky, Kyrill Yu</au><au>Sivaev, Igor B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nickel(II) and Palladium(II) Complexes with η5:κ1(N)-Coordinated Dicarbollide Ligands Containing Pendant Pyridine Group</atitle><jtitle>International journal of molecular sciences</jtitle><date>2023-10-11</date><risdate>2023</risdate><volume>24</volume><issue>20</issue><spage>15069</spage><pages>15069-</pages><issn>1422-0067</issn><issn>1661-6596</issn><eissn>1422-0067</eissn><abstract>A series of C- and B-substituted nido-carborane derivatives with a pendant pyridyl group was prepared. 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| subjects | Boron Carbon Ligands Mass spectrometry Nickel Scientific imaging Single crystals |
| title | Nickel(II) and Palladium(II) Complexes with η5:κ1(N)-Coordinated Dicarbollide Ligands Containing Pendant Pyridine Group |
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