Iron(II)-Catalyzed Activation of Si–N and Si–O Bonds Using Hydroboranes

We report the activation and functionalization of Si–N bonds with pinacol borane catalyzed by a three-coordinate iron­(II) β-diketiminate complex. The reactions proceed via the mild activation of silazanes to yield useful hydrosilanes and aminoboranes. The reaction is studied by kinetic analysis, al...

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Veröffentlicht in:	Organometallics 2023-10, Vol.42 (20), p.3013-3024
Hauptverfasser:	Farcaş-Johnson, Mirela A., Gasperini, Danila, King, Andrew K., Mohan, Sakshi, Barrett, Adam N., Lau, Samantha, Mahon, Mary F., Sarazin, Yann, Kyne, Sara H., Webster, Ruth L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Organic chemistry
Online-Zugang:	Volltext
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