Dual-mode luminescence anti-counterfeiting and white light emission of NaGdF4:Ce,Eu,Tb/carbon dot hydrophilic nanocomposite ink

NaGdF4:Ce,Eu,Tb nanocrystals were successfully prepared by a one-step hydrothermal method with Ce3+ ions as sensitizers, Eu3+ and Tb3+ ions as activators, and polyethylenimine (PEI) as surfactants. Color-adjustable fluorescence emission was achieved by the energy transfer effect between rare earth i...

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Veröffentlicht in:RSC advances 2023-08, Vol.13 (37), p.25681-25690
Hauptverfasser: Liang, Jie, Fan, Ting, Jian-tao Lü, Guan, Tianjie, Ting-ting Deng, Xiong, Bangyun
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container_end_page 25690
container_issue 37
container_start_page 25681
container_title RSC advances
container_volume 13
creator Liang, Jie
Fan, Ting
Jian-tao Lü
Guan, Tianjie
Ting-ting Deng
Xiong, Bangyun
description NaGdF4:Ce,Eu,Tb nanocrystals were successfully prepared by a one-step hydrothermal method with Ce3+ ions as sensitizers, Eu3+ and Tb3+ ions as activators, and polyethylenimine (PEI) as surfactants. Color-adjustable fluorescence emission was achieved by the energy transfer effect between rare earth ions. Blue fluorescent carbon quantum dots (CDs) with a double UV response under 254 nm and 365 nm excitation were synthesized by a one-step hydrothermal method. A hydrophilic NaGdF4:Ce,Eu,Tb/CD composite ink was prepared by an easy physical mixing method. Because of the electrostatic self-assembly effect, the color adjustable luminescence was achieved in a few seconds, and the white light emission with color coordinates of (0.32, 0.32) was obtained. A dual-mode luminescence anti-counterfeiting pattern was designed and achieved by excitation with ultraviolet light at 254 nm and 365 nm.
doi_str_mv 10.1039/d3ra04368a
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subjects Carbon dots
Cerium
Chemistry
Color
Energy transfer
Excitation
Fluorescence
Hydrophilicity
Light emission
Luminescence
Nanocomposites
Nanocrystals
Polyethyleneimine
Quantum dots
Self-assembly
Terbium
Ultraviolet radiation
White light
title Dual-mode luminescence anti-counterfeiting and white light emission of NaGdF4:Ce,Eu,Tb/carbon dot hydrophilic nanocomposite ink
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