Acetate exchange mechanism on a Zr12 oxo hydroxo cluster: relevance for reshaping Zr–carboxylate coordination adaptable networks

The kinetics and mechanism of the acetate ligand exchange with free acetic acid in [Zr6O4(OH)4(O2CCH3)12]2, used as a molecular model of crosslink migration in [Zr6O4(OH)4(carboxylate)12−n(OH)n]-based coordination adaptable networks with vitrimer-like properties, has been thoroughly investigated by...

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