Leaching in Specific Facets of ZIF-67 and ZIF‑L Zeolitic Imidazolate Frameworks During the CO2 Cycloaddition with Epichlorohydrin

Zeolitic imidazolate frameworks (ZIFs) have been profusely used as catalysts for inserting CO2 into organic epoxides (i.e., epichlorohydrin) through cycloaddition. Here, we demonstrate that these materials suffer from irreversible degradation by leaching. To prove this, we performed the reactions an...

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Veröffentlicht in:Chemistry of materials 2023-01, Vol.35 (2), p.692-699
Hauptverfasser: Delgado-Marín, Jose J., Rendón-Patiño, Alejandra, Velisoju, Vijay Kumar, Kumar, Gadde Sathish, Zambrano, Naydu, Rueping, Magnus, Gascón, Jorge, Castaño, Pedro, Narciso, Javier, Ramos-Fernandez, Enrique V.
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Sprache:eng
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