Cage effects control the mechanism of methane hydroxylation in zeolites

Catalytic conversion of methane to methanol remains an economically tantalizing but fundamentally challenging goal. Current technologies based on zeolites deactivate too rapidly for practical application. We found that similar active sites hosted in different zeolite lattices can exhibit markedly di...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Science (American Association for the Advancement of Science) 2021-07, Vol.373 (6552), p.327-331
Hauptverfasser:	Snyder, Benjamin E R, Bols, Max L, Rhoda, Hannah M, Plessers, Dieter, Schoonheydt, Robert A, Sels, Bert F, Solomon, Edward I
Format:	Artikel
Sprache:	eng
Schlagworte:	Apertures Catalysis Catalysts Catalytic converters Deactivation Density functional theory Hydroxylation Intermediates Iron Lattices MATERIALS SCIENCE Methane Methanol Methyl radicals Radicals Raman spectroscopy Recombination Zeolites
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!