Molecular regulation of electrolytes for enhancing anode interfacial stability in lithium-sulfur batteries
We addressed the poor interfacial stability of the Li metal anode in Li-S batteries through molecular regulation of electrolytes using arylthiol additives with various numbers of anchoring sites. The dual functional tetrathiol additive markedly enhanced the Li anode interfacial stability, controlled...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2023-06, Vol.59 (53), p.8286-8289 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Zhou, Tianhong Zhao, Yan Fritz, Patrick W Ashirov, Timur Baster, Dominika El Kazzi, Mario Coskun, Ali |
| description | We addressed the poor interfacial stability of the Li metal anode in Li-S batteries through molecular regulation of electrolytes using arylthiol additives with various numbers of anchoring sites. The dual functional tetrathiol additive markedly enhanced the Li anode interfacial stability, controlled the sulfur redox kinetics and suppressed side reactions towards polysulfides, thus leading to an improved capacity retention of 70% after 500 cycles at 1 C.
We addressed the poor interfacial stability of the Li metal anode in Li-S batteries through molecular regulation of electrolytes using arylthiol additives with various numbers of anchoring sites. |
| doi_str_mv | 10.1039/d3cc01179h |
| format | Article |
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We addressed the poor interfacial stability of the Li metal anode in Li-S batteries through molecular regulation of electrolytes using arylthiol additives with various numbers of anchoring sites.</description><subject>Additives</subject><subject>Chemistry</subject><subject>Control stability</subject><subject>Electrolytes</subject><subject>Interface stability</subject><subject>Lithium sulfur batteries</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkt9rFDEQx0OxtLX2pe9KwBcpbM2vzW6eRE5rCy2-KPi2ZLOTuxy5pCZZ4f77pl49q3n5hpkP30xmBqFzSi4p4er9xI0hlHZqdYBOKJeiaUX_48XjvVVNx0V7jF7mvCb10LY_Qse847TnRJ2g9V30YGavE06wrFpcDDhaDDVcUvTbAhnbmDCElQ7GhSXWIU6AXSiQrDZOe5yLHp13ZVujuOrKzZsmz97OCY-6VNBBfoUOrfYZzp70FH2_-vxtcd3cfv1ys_h42xjBVGlUK0cmKCNGjVpq1bVgCDG9UNYIUBTkqEXXtWSivZXSWD1VVcwaKZieDD9FH3a-9_O4gclAKEn74T65jU7bIWo3_JsJbjUs46-hNpMowmh1ePfkkOLPGXIZNi4b8F4HiHMeWM8ko6onpKJv_0PXcU6h_q9SnMjKibZSFzvKpJhzAruvhpLHZ9XwiS8Wv2d4XeE3z-vfo3-GVoHXOyBls8_-XQL-AJ6Mo_c</recordid><startdate>20230629</startdate><enddate>20230629</enddate><creator>Zhou, Tianhong</creator><creator>Zhao, Yan</creator><creator>Fritz, Patrick W</creator><creator>Ashirov, Timur</creator><creator>Baster, Dominika</creator><creator>El Kazzi, Mario</creator><creator>Coskun, Ali</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-2975-0481</orcidid><orcidid>https://orcid.org/0000-0002-4760-1546</orcidid></search><sort><creationdate>20230629</creationdate><title>Molecular regulation of electrolytes for enhancing anode interfacial stability in lithium-sulfur batteries</title><author>Zhou, Tianhong ; Zhao, Yan ; Fritz, Patrick W ; Ashirov, Timur ; Baster, Dominika ; El Kazzi, Mario ; Coskun, Ali</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c429t-956b24120c9ba6a975ec00c849fc4e91e6ba47750d18f66cfad8f692fc642adc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Additives</topic><topic>Chemistry</topic><topic>Control stability</topic><topic>Electrolytes</topic><topic>Interface stability</topic><topic>Lithium sulfur batteries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Tianhong</creatorcontrib><creatorcontrib>Zhao, Yan</creatorcontrib><creatorcontrib>Fritz, Patrick W</creatorcontrib><creatorcontrib>Ashirov, Timur</creatorcontrib><creatorcontrib>Baster, Dominika</creatorcontrib><creatorcontrib>El Kazzi, Mario</creatorcontrib><creatorcontrib>Coskun, Ali</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Tianhong</au><au>Zhao, Yan</au><au>Fritz, Patrick W</au><au>Ashirov, Timur</au><au>Baster, Dominika</au><au>El Kazzi, Mario</au><au>Coskun, Ali</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Molecular regulation of electrolytes for enhancing anode interfacial stability in lithium-sulfur batteries</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2023-06-29</date><risdate>2023</risdate><volume>59</volume><issue>53</issue><spage>8286</spage><epage>8289</epage><pages>8286-8289</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>We addressed the poor interfacial stability of the Li metal anode in Li-S batteries through molecular regulation of electrolytes using arylthiol additives with various numbers of anchoring sites. The dual functional tetrathiol additive markedly enhanced the Li anode interfacial stability, controlled the sulfur redox kinetics and suppressed side reactions towards polysulfides, thus leading to an improved capacity retention of 70% after 500 cycles at 1 C.
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2023-06, Vol.59 (53), p.8286-8289 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10309021 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Additives Chemistry Control stability Electrolytes Interface stability Lithium sulfur batteries |
| title | Molecular regulation of electrolytes for enhancing anode interfacial stability in lithium-sulfur batteries |
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