The Effect of Boron (B) and Copper (Cu) on the Microstructure and Graphite Morphology of Spheroidal Graphite Cast Iron
This study examines the impacts of copper and boron in parts per million (ppm) on the microstructure and mechanical properties of spheroidal graphite cast iron (SCI). Boron's inclusion increases the ferrite content whereas copper augments the stability of pearlite. The interaction between the t...
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creator | Ha, Jin-Su Hong, Ji-Woo Kim, Ji-Wook Han, Soo-Bin Choi, Chang-Young Song, Hye-Jin Jang, Jin-Seok Kim, Dong-Yul Ko, Dae-Cheol Yi, Seong-Hoon Cho, Yong-Jae |
description | This study examines the impacts of copper and boron in parts per million (ppm) on the microstructure and mechanical properties of spheroidal graphite cast iron (SCI). Boron's inclusion increases the ferrite content whereas copper augments the stability of pearlite. The interaction between the two significantly influences the ferrite content. Differential scanning calorimetry (DSC) analysis indicates that boron alters the enthalpy change of the α + Fe3C → γ conversion and the α → γ conversion. Scanning electron microscope (SEM) analysis confirms the locations of copper and boron. Mechanical property assessments using a universal testing machine show that the inclusion of boron and copper decreases the tensile strength and yield strength of SCI, but simultaneously enhances elongation. Additionally, in SCI production, the utilization of copper-bearing scrap and trace amounts of boron-containing scrap metal, especially in the casting of ferritic nodular cast iron, offers potential for resource recycling. This highlights the importance of resource conservation and recycling in advancing sustainable manufacturing practices. These findings provide critical insights into the effects of boron and copper on SCI's behavior, contributing to the design and development of high-performance SCI materials. |
doi_str_mv | 10.3390/ma16124225 |
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Boron's inclusion increases the ferrite content whereas copper augments the stability of pearlite. The interaction between the two significantly influences the ferrite content. Differential scanning calorimetry (DSC) analysis indicates that boron alters the enthalpy change of the α + Fe3C → γ conversion and the α → γ conversion. Scanning electron microscope (SEM) analysis confirms the locations of copper and boron. Mechanical property assessments using a universal testing machine show that the inclusion of boron and copper decreases the tensile strength and yield strength of SCI, but simultaneously enhances elongation. Additionally, in SCI production, the utilization of copper-bearing scrap and trace amounts of boron-containing scrap metal, especially in the casting of ferritic nodular cast iron, offers potential for resource recycling. This highlights the importance of resource conservation and recycling in advancing sustainable manufacturing practices. These findings provide critical insights into the effects of boron and copper on SCI's behavior, contributing to the design and development of high-performance SCI materials.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma16124225</identifier><identifier>PMID: 37374410</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Alloys ; Automobiles ; Boron ; Carbon ; Cast iron ; Cementite ; Conversion ; Copper ; Copper converters ; Ductility ; Elongation ; Enthalpy ; Ferrite ; Graphite ; Heat resistance ; High strength steel ; Impact tests ; Iron carbides ; Mechanical properties ; Metal scrap ; Metals ; Microscopy ; Microstructure ; Morphology ; Nodular cast iron ; Nodular graphitic structure ; Pearlite ; Recycling ; Resource conservation ; Scrap iron ; Solidification ; Stability augmentation ; Stress concentration ; Temperature ; Tensile strength ; Tension tests</subject><ispartof>Materials, 2023-06, Vol.16 (12), p.4225</ispartof><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2023 by the authors. 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c366t-c7974c3d12defb1393dd2eca8c3f363fe9667c9a923ef43282e816ecb0d99cd53</cites><orcidid>0000-0002-6801-9109 ; 0000-0002-4064-739X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10301530/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10301530/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37374410$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ha, Jin-Su</creatorcontrib><creatorcontrib>Hong, Ji-Woo</creatorcontrib><creatorcontrib>Kim, Ji-Wook</creatorcontrib><creatorcontrib>Han, Soo-Bin</creatorcontrib><creatorcontrib>Choi, Chang-Young</creatorcontrib><creatorcontrib>Song, Hye-Jin</creatorcontrib><creatorcontrib>Jang, Jin-Seok</creatorcontrib><creatorcontrib>Kim, Dong-Yul</creatorcontrib><creatorcontrib>Ko, Dae-Cheol</creatorcontrib><creatorcontrib>Yi, Seong-Hoon</creatorcontrib><creatorcontrib>Cho, Yong-Jae</creatorcontrib><title>The Effect of Boron (B) and Copper (Cu) on the Microstructure and Graphite Morphology of Spheroidal Graphite Cast Iron</title><title>Materials</title><addtitle>Materials (Basel)</addtitle><description>This study examines the impacts of copper and boron in parts per million (ppm) on the microstructure and mechanical properties of spheroidal graphite cast iron (SCI). Boron's inclusion increases the ferrite content whereas copper augments the stability of pearlite. The interaction between the two significantly influences the ferrite content. Differential scanning calorimetry (DSC) analysis indicates that boron alters the enthalpy change of the α + Fe3C → γ conversion and the α → γ conversion. Scanning electron microscope (SEM) analysis confirms the locations of copper and boron. Mechanical property assessments using a universal testing machine show that the inclusion of boron and copper decreases the tensile strength and yield strength of SCI, but simultaneously enhances elongation. Additionally, in SCI production, the utilization of copper-bearing scrap and trace amounts of boron-containing scrap metal, especially in the casting of ferritic nodular cast iron, offers potential for resource recycling. This highlights the importance of resource conservation and recycling in advancing sustainable manufacturing practices. These findings provide critical insights into the effects of boron and copper on SCI's behavior, contributing to the design and development of high-performance SCI materials.</description><subject>Alloys</subject><subject>Automobiles</subject><subject>Boron</subject><subject>Carbon</subject><subject>Cast iron</subject><subject>Cementite</subject><subject>Conversion</subject><subject>Copper</subject><subject>Copper converters</subject><subject>Ductility</subject><subject>Elongation</subject><subject>Enthalpy</subject><subject>Ferrite</subject><subject>Graphite</subject><subject>Heat resistance</subject><subject>High strength steel</subject><subject>Impact tests</subject><subject>Iron carbides</subject><subject>Mechanical properties</subject><subject>Metal scrap</subject><subject>Metals</subject><subject>Microscopy</subject><subject>Microstructure</subject><subject>Morphology</subject><subject>Nodular cast iron</subject><subject>Nodular graphitic structure</subject><subject>Pearlite</subject><subject>Recycling</subject><subject>Resource conservation</subject><subject>Scrap iron</subject><subject>Solidification</subject><subject>Stability augmentation</subject><subject>Stress concentration</subject><subject>Temperature</subject><subject>Tensile strength</subject><subject>Tension tests</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdkU9P3DAQxa2qVUGUSz9AZamXpdK2tsfrxKcKIgpIoB6As-W1xyQoG6eOg8S3r7f8Lb6M5fnpzfM8Qj5z9h1Asx8byxUXUojVO7LLtVZLrqV8_-q-Q_an6ZaVA8BroT-SHaigkpKzXXJ31SI9DgFdpjHQo5jiQBdHB9QOnjZxHDHRRTMf0PKcC3rRuRSnnGaX54T_qJNkx7bLpRfT2MY-3txvpS7HFlPsvO1fiMZOmZ6VEZ_Ih2D7Cfcf6x65_nV81Zwuz3-fnDWH50sHSuWlq3QlHXguPIY1Bw3eC3S2dhBAQUCtVOW01QIwSBC1wJordGvmtXZ-BXvk54PuOK836B0OOdnejKnb2HRvou3M_52ha81NvDOcAeMrYEVh8aiQ4p8Zp2w23eSw7-2AcZ6MqIEptZIKCvr1DXob5zSU_xVK6FpCpepCfXugtoucEoZnN5yZbaTmJdICf3nt_xl9ChD-AtYcm3w</recordid><startdate>20230607</startdate><enddate>20230607</enddate><creator>Ha, Jin-Su</creator><creator>Hong, Ji-Woo</creator><creator>Kim, Ji-Wook</creator><creator>Han, Soo-Bin</creator><creator>Choi, Chang-Young</creator><creator>Song, Hye-Jin</creator><creator>Jang, Jin-Seok</creator><creator>Kim, Dong-Yul</creator><creator>Ko, Dae-Cheol</creator><creator>Yi, Seong-Hoon</creator><creator>Cho, Yong-Jae</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-6801-9109</orcidid><orcidid>https://orcid.org/0000-0002-4064-739X</orcidid></search><sort><creationdate>20230607</creationdate><title>The Effect of Boron (B) and Copper (Cu) on the Microstructure and Graphite Morphology of Spheroidal Graphite Cast Iron</title><author>Ha, Jin-Su ; Hong, Ji-Woo ; Kim, Ji-Wook ; Han, Soo-Bin ; Choi, Chang-Young ; Song, Hye-Jin ; Jang, Jin-Seok ; Kim, Dong-Yul ; Ko, Dae-Cheol ; Yi, Seong-Hoon ; Cho, Yong-Jae</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c366t-c7974c3d12defb1393dd2eca8c3f363fe9667c9a923ef43282e816ecb0d99cd53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Alloys</topic><topic>Automobiles</topic><topic>Boron</topic><topic>Carbon</topic><topic>Cast iron</topic><topic>Cementite</topic><topic>Conversion</topic><topic>Copper</topic><topic>Copper converters</topic><topic>Ductility</topic><topic>Elongation</topic><topic>Enthalpy</topic><topic>Ferrite</topic><topic>Graphite</topic><topic>Heat resistance</topic><topic>High strength steel</topic><topic>Impact tests</topic><topic>Iron carbides</topic><topic>Mechanical properties</topic><topic>Metal scrap</topic><topic>Metals</topic><topic>Microscopy</topic><topic>Microstructure</topic><topic>Morphology</topic><topic>Nodular cast iron</topic><topic>Nodular graphitic structure</topic><topic>Pearlite</topic><topic>Recycling</topic><topic>Resource conservation</topic><topic>Scrap iron</topic><topic>Solidification</topic><topic>Stability augmentation</topic><topic>Stress concentration</topic><topic>Temperature</topic><topic>Tensile strength</topic><topic>Tension tests</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ha, Jin-Su</creatorcontrib><creatorcontrib>Hong, Ji-Woo</creatorcontrib><creatorcontrib>Kim, Ji-Wook</creatorcontrib><creatorcontrib>Han, Soo-Bin</creatorcontrib><creatorcontrib>Choi, Chang-Young</creatorcontrib><creatorcontrib>Song, Hye-Jin</creatorcontrib><creatorcontrib>Jang, Jin-Seok</creatorcontrib><creatorcontrib>Kim, Dong-Yul</creatorcontrib><creatorcontrib>Ko, Dae-Cheol</creatorcontrib><creatorcontrib>Yi, Seong-Hoon</creatorcontrib><creatorcontrib>Cho, Yong-Jae</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ha, Jin-Su</au><au>Hong, Ji-Woo</au><au>Kim, Ji-Wook</au><au>Han, Soo-Bin</au><au>Choi, Chang-Young</au><au>Song, Hye-Jin</au><au>Jang, Jin-Seok</au><au>Kim, Dong-Yul</au><au>Ko, Dae-Cheol</au><au>Yi, Seong-Hoon</au><au>Cho, Yong-Jae</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Effect of Boron (B) and Copper (Cu) on the Microstructure and Graphite Morphology of Spheroidal Graphite Cast Iron</atitle><jtitle>Materials</jtitle><addtitle>Materials (Basel)</addtitle><date>2023-06-07</date><risdate>2023</risdate><volume>16</volume><issue>12</issue><spage>4225</spage><pages>4225-</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>This study examines the impacts of copper and boron in parts per million (ppm) on the microstructure and mechanical properties of spheroidal graphite cast iron (SCI). Boron's inclusion increases the ferrite content whereas copper augments the stability of pearlite. The interaction between the two significantly influences the ferrite content. Differential scanning calorimetry (DSC) analysis indicates that boron alters the enthalpy change of the α + Fe3C → γ conversion and the α → γ conversion. Scanning electron microscope (SEM) analysis confirms the locations of copper and boron. Mechanical property assessments using a universal testing machine show that the inclusion of boron and copper decreases the tensile strength and yield strength of SCI, but simultaneously enhances elongation. Additionally, in SCI production, the utilization of copper-bearing scrap and trace amounts of boron-containing scrap metal, especially in the casting of ferritic nodular cast iron, offers potential for resource recycling. This highlights the importance of resource conservation and recycling in advancing sustainable manufacturing practices. These findings provide critical insights into the effects of boron and copper on SCI's behavior, contributing to the design and development of high-performance SCI materials.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>37374410</pmid><doi>10.3390/ma16124225</doi><orcidid>https://orcid.org/0000-0002-6801-9109</orcidid><orcidid>https://orcid.org/0000-0002-4064-739X</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Alloys Automobiles Boron Carbon Cast iron Cementite Conversion Copper Copper converters Ductility Elongation Enthalpy Ferrite Graphite Heat resistance High strength steel Impact tests Iron carbides Mechanical properties Metal scrap Metals Microscopy Microstructure Morphology Nodular cast iron Nodular graphitic structure Pearlite Recycling Resource conservation Scrap iron Solidification Stability augmentation Stress concentration Temperature Tensile strength Tension tests |
title | The Effect of Boron (B) and Copper (Cu) on the Microstructure and Graphite Morphology of Spheroidal Graphite Cast Iron |
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