Ligand Rigidity Steers the Selectivity and Efficiency of the Photosubstitution Reaction of Strained Ruthenium Polypyridyl Complexes

While photosubstitution reactions in metal complexes are usually thought of as dissociative processes poorly dependent on the environment, they are, in fact, very sensitive to solvent effects. Therefore, it is crucial to explicitly consider solvent molecules in theoretical models of these reactions....

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2023-06, Vol.145 (24), p.13420-13434
Hauptverfasser:	Hakkennes, Matthijs L. A., Meijer, Michael S., Menzel, Jan Paul, Goetz, Anne-Charlotte, Van Duijn, Roy, Siegler, Maxime A., Buda, Francesco, Bonnet, Sylvestre
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!