Bioactive Ion‐Based Switchable Supercapacitors
Switchable supercapacitors (SCs) enable a reversible electrically‐driven uptake/release of bioactive ions by polarizing porous carbon electrodes. Herein we demonstrate the first example of a bioactive ion‐based switchable supercapacitor. Based on choline chloride and porous carbons we unravel the me...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie International Edition 2022-12, Vol.61 (50), p.e202212250-n/a |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 50 |
| container_start_page | e202212250 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 61 |
| creator | Li, Panlong Bräuniger, Yannik Kunigkeit, Jonas Zhou, Hanfeng Ortega Vega, Maria Rita Zhang, En Grothe, Julia Brunner, Eike Kaskel, Stefan |
| description | Switchable supercapacitors (SCs) enable a reversible electrically‐driven uptake/release of bioactive ions by polarizing porous carbon electrodes. Herein we demonstrate the first example of a bioactive ion‐based switchable supercapacitor. Based on choline chloride and porous carbons we unravel the mechanism of physisorption vs. electrosorption by nuclear magnetic resonance, Raman, and impedance spectroscopy. Weak physisorption facilitates electrically‐driven electrolyte depletion enabling the controllable uptake/release of electrolyte ions. A new 4‐terminal device is proposed, with a main capacitor and a detective capacitor for monitoring bioactive ion adsorption in situ. Ion‐concentration control in printed choline‐based switchable SCs realizes switching down to 8.3 % residual capacitance. The exploration of adsorption mechanisms in printable microdevices will open an avenue of manipulating bioactive ions for the application of drug delivery, neuromodulation, or neuromorphic devices.
Inspired by the highly efficient information transmission of biologically active compounds in nerve systems, a well‐controllable capture/release of biologically active ions is achieved by a switchable supercapacitor. |
| doi_str_mv | 10.1002/anie.202212250 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10100445</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2746821624</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4690-5c9b1e54562a756a26f1a978fdf3c46c51980c595c2f73ed5ea985200e92cc533</originalsourceid><addsrcrecordid>eNqFkbtOAzEQRS0E4t1Sokg0NBvs8dq7rhBBPCIhKIDacpxZMNqsg70LouMT-Ea-BEMgPBoqj-QzRzNzCdlitM8ohT3TOOwDBWAAgi6QVSaAZbwo-GKqc86zohRshazFeJf4sqRymaxwCZJKLlYJHThvbOsesDf0zevzy8BEHPcuH11rb82oxt5lN8VgzdRY1_oQN8hSZeqIm5_vOrk-Pro6PM3OLk6Ghwdnmc2lopmwasRQ5EKCKYQ0ICtmVFFW44onwgqmSmqFEhaqguNYoFGlAEpRgbWC83WyP_NOu9EExxabNphaT4ObmPCkvXH690_jbvWNf9CMpsPkuUiG3U9D8PcdxlZPXLRY16ZB30UNBcicquID3fmD3vkuNGm_ROWyBCYhT1R_RtngYwxYzadhVL-nod_T0PM0UsP2zx3m-Nf5E6BmwKOr8ekfnT44Hx59y98AeG6WJw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2746821624</pqid></control><display><type>article</type><title>Bioactive Ion‐Based Switchable Supercapacitors</title><source>MEDLINE</source><source>Wiley Online Library Journals Frontfile Complete</source><creator>Li, Panlong ; Bräuniger, Yannik ; Kunigkeit, Jonas ; Zhou, Hanfeng ; Ortega Vega, Maria Rita ; Zhang, En ; Grothe, Julia ; Brunner, Eike ; Kaskel, Stefan</creator><creatorcontrib>Li, Panlong ; Bräuniger, Yannik ; Kunigkeit, Jonas ; Zhou, Hanfeng ; Ortega Vega, Maria Rita ; Zhang, En ; Grothe, Julia ; Brunner, Eike ; Kaskel, Stefan</creatorcontrib><description>Switchable supercapacitors (SCs) enable a reversible electrically‐driven uptake/release of bioactive ions by polarizing porous carbon electrodes. Herein we demonstrate the first example of a bioactive ion‐based switchable supercapacitor. Based on choline chloride and porous carbons we unravel the mechanism of physisorption vs. electrosorption by nuclear magnetic resonance, Raman, and impedance spectroscopy. Weak physisorption facilitates electrically‐driven electrolyte depletion enabling the controllable uptake/release of electrolyte ions. A new 4‐terminal device is proposed, with a main capacitor and a detective capacitor for monitoring bioactive ion adsorption in situ. Ion‐concentration control in printed choline‐based switchable SCs realizes switching down to 8.3 % residual capacitance. The exploration of adsorption mechanisms in printable microdevices will open an avenue of manipulating bioactive ions for the application of drug delivery, neuromodulation, or neuromorphic devices.
Inspired by the highly efficient information transmission of biologically active compounds in nerve systems, a well‐controllable capture/release of biologically active ions is achieved by a switchable supercapacitor.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>ISSN: 1521-3773</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202212250</identifier><identifier>PMID: 36260635</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Adsorption ; Biological activity ; Capacitance ; Capacitors ; Carbon - chemistry ; Choline ; Controllability ; Depletion ; Drug delivery ; Electric Capacitance ; Electrodes ; Electrolytes ; Electrosorption ; Ion adsorption ; Ions ; Iontronic Architecture ; Neuromodulation ; NMR ; Nuclear magnetic resonance ; Porous Carbon ; Spectroscopy ; Supercapacitors ; Switchable Supercapacitor</subject><ispartof>Angewandte Chemie International Edition, 2022-12, Vol.61 (50), p.e202212250-n/a</ispartof><rights>2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH</rights><rights>2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.</rights><rights>2022. This article is published under http://creativecommons.org/licenses/by-nc/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4690-5c9b1e54562a756a26f1a978fdf3c46c51980c595c2f73ed5ea985200e92cc533</citedby><cites>FETCH-LOGICAL-c4690-5c9b1e54562a756a26f1a978fdf3c46c51980c595c2f73ed5ea985200e92cc533</cites><orcidid>0000-0002-6049-2831 ; 0000-0003-4572-0303 ; 0000-0001-8871-4849</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202212250$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202212250$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>230,314,778,782,883,1414,27907,27908,45557,45558</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36260635$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Panlong</creatorcontrib><creatorcontrib>Bräuniger, Yannik</creatorcontrib><creatorcontrib>Kunigkeit, Jonas</creatorcontrib><creatorcontrib>Zhou, Hanfeng</creatorcontrib><creatorcontrib>Ortega Vega, Maria Rita</creatorcontrib><creatorcontrib>Zhang, En</creatorcontrib><creatorcontrib>Grothe, Julia</creatorcontrib><creatorcontrib>Brunner, Eike</creatorcontrib><creatorcontrib>Kaskel, Stefan</creatorcontrib><title>Bioactive Ion‐Based Switchable Supercapacitors</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>Switchable supercapacitors (SCs) enable a reversible electrically‐driven uptake/release of bioactive ions by polarizing porous carbon electrodes. Herein we demonstrate the first example of a bioactive ion‐based switchable supercapacitor. Based on choline chloride and porous carbons we unravel the mechanism of physisorption vs. electrosorption by nuclear magnetic resonance, Raman, and impedance spectroscopy. Weak physisorption facilitates electrically‐driven electrolyte depletion enabling the controllable uptake/release of electrolyte ions. A new 4‐terminal device is proposed, with a main capacitor and a detective capacitor for monitoring bioactive ion adsorption in situ. Ion‐concentration control in printed choline‐based switchable SCs realizes switching down to 8.3 % residual capacitance. The exploration of adsorption mechanisms in printable microdevices will open an avenue of manipulating bioactive ions for the application of drug delivery, neuromodulation, or neuromorphic devices.
Inspired by the highly efficient information transmission of biologically active compounds in nerve systems, a well‐controllable capture/release of biologically active ions is achieved by a switchable supercapacitor.</description><subject>Adsorption</subject><subject>Biological activity</subject><subject>Capacitance</subject><subject>Capacitors</subject><subject>Carbon - chemistry</subject><subject>Choline</subject><subject>Controllability</subject><subject>Depletion</subject><subject>Drug delivery</subject><subject>Electric Capacitance</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Electrosorption</subject><subject>Ion adsorption</subject><subject>Ions</subject><subject>Iontronic Architecture</subject><subject>Neuromodulation</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Porous Carbon</subject><subject>Spectroscopy</subject><subject>Supercapacitors</subject><subject>Switchable Supercapacitor</subject><issn>1433-7851</issn><issn>1521-3773</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><sourceid>EIF</sourceid><recordid>eNqFkbtOAzEQRS0E4t1Sokg0NBvs8dq7rhBBPCIhKIDacpxZMNqsg70LouMT-Ea-BEMgPBoqj-QzRzNzCdlitM8ohT3TOOwDBWAAgi6QVSaAZbwo-GKqc86zohRshazFeJf4sqRymaxwCZJKLlYJHThvbOsesDf0zevzy8BEHPcuH11rb82oxt5lN8VgzdRY1_oQN8hSZeqIm5_vOrk-Pro6PM3OLk6Ghwdnmc2lopmwasRQ5EKCKYQ0ICtmVFFW44onwgqmSmqFEhaqguNYoFGlAEpRgbWC83WyP_NOu9EExxabNphaT4ObmPCkvXH690_jbvWNf9CMpsPkuUiG3U9D8PcdxlZPXLRY16ZB30UNBcicquID3fmD3vkuNGm_ROWyBCYhT1R_RtngYwxYzadhVL-nod_T0PM0UsP2zx3m-Nf5E6BmwKOr8ekfnT44Hx59y98AeG6WJw</recordid><startdate>20221212</startdate><enddate>20221212</enddate><creator>Li, Panlong</creator><creator>Bräuniger, Yannik</creator><creator>Kunigkeit, Jonas</creator><creator>Zhou, Hanfeng</creator><creator>Ortega Vega, Maria Rita</creator><creator>Zhang, En</creator><creator>Grothe, Julia</creator><creator>Brunner, Eike</creator><creator>Kaskel, Stefan</creator><general>Wiley Subscription Services, Inc</general><general>John Wiley and Sons Inc</general><scope>24P</scope><scope>WIN</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-6049-2831</orcidid><orcidid>https://orcid.org/0000-0003-4572-0303</orcidid><orcidid>https://orcid.org/0000-0001-8871-4849</orcidid></search><sort><creationdate>20221212</creationdate><title>Bioactive Ion‐Based Switchable Supercapacitors</title><author>Li, Panlong ; Bräuniger, Yannik ; Kunigkeit, Jonas ; Zhou, Hanfeng ; Ortega Vega, Maria Rita ; Zhang, En ; Grothe, Julia ; Brunner, Eike ; Kaskel, Stefan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4690-5c9b1e54562a756a26f1a978fdf3c46c51980c595c2f73ed5ea985200e92cc533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Adsorption</topic><topic>Biological activity</topic><topic>Capacitance</topic><topic>Capacitors</topic><topic>Carbon - chemistry</topic><topic>Choline</topic><topic>Controllability</topic><topic>Depletion</topic><topic>Drug delivery</topic><topic>Electric Capacitance</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Electrosorption</topic><topic>Ion adsorption</topic><topic>Ions</topic><topic>Iontronic Architecture</topic><topic>Neuromodulation</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Porous Carbon</topic><topic>Spectroscopy</topic><topic>Supercapacitors</topic><topic>Switchable Supercapacitor</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Panlong</creatorcontrib><creatorcontrib>Bräuniger, Yannik</creatorcontrib><creatorcontrib>Kunigkeit, Jonas</creatorcontrib><creatorcontrib>Zhou, Hanfeng</creatorcontrib><creatorcontrib>Ortega Vega, Maria Rita</creatorcontrib><creatorcontrib>Zhang, En</creatorcontrib><creatorcontrib>Grothe, Julia</creatorcontrib><creatorcontrib>Brunner, Eike</creatorcontrib><creatorcontrib>Kaskel, Stefan</creatorcontrib><collection>Wiley Online Library Open Access</collection><collection>Wiley Online Library Free Content</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Panlong</au><au>Bräuniger, Yannik</au><au>Kunigkeit, Jonas</au><au>Zhou, Hanfeng</au><au>Ortega Vega, Maria Rita</au><au>Zhang, En</au><au>Grothe, Julia</au><au>Brunner, Eike</au><au>Kaskel, Stefan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bioactive Ion‐Based Switchable Supercapacitors</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2022-12-12</date><risdate>2022</risdate><volume>61</volume><issue>50</issue><spage>e202212250</spage><epage>n/a</epage><pages>e202212250-n/a</pages><issn>1433-7851</issn><issn>1521-3773</issn><eissn>1521-3773</eissn><abstract>Switchable supercapacitors (SCs) enable a reversible electrically‐driven uptake/release of bioactive ions by polarizing porous carbon electrodes. Herein we demonstrate the first example of a bioactive ion‐based switchable supercapacitor. Based on choline chloride and porous carbons we unravel the mechanism of physisorption vs. electrosorption by nuclear magnetic resonance, Raman, and impedance spectroscopy. Weak physisorption facilitates electrically‐driven electrolyte depletion enabling the controllable uptake/release of electrolyte ions. A new 4‐terminal device is proposed, with a main capacitor and a detective capacitor for monitoring bioactive ion adsorption in situ. Ion‐concentration control in printed choline‐based switchable SCs realizes switching down to 8.3 % residual capacitance. The exploration of adsorption mechanisms in printable microdevices will open an avenue of manipulating bioactive ions for the application of drug delivery, neuromodulation, or neuromorphic devices.
Inspired by the highly efficient information transmission of biologically active compounds in nerve systems, a well‐controllable capture/release of biologically active ions is achieved by a switchable supercapacitor.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>36260635</pmid><doi>10.1002/anie.202212250</doi><tpages>8</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-6049-2831</orcidid><orcidid>https://orcid.org/0000-0003-4572-0303</orcidid><orcidid>https://orcid.org/0000-0001-8871-4849</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2022-12, Vol.61 (50), p.e202212250-n/a |
| issn | 1433-7851 1521-3773 1521-3773 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10100445 |
| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Adsorption Biological activity Capacitance Capacitors Carbon - chemistry Choline Controllability Depletion Drug delivery Electric Capacitance Electrodes Electrolytes Electrosorption Ion adsorption Ions Iontronic Architecture Neuromodulation NMR Nuclear magnetic resonance Porous Carbon Spectroscopy Supercapacitors Switchable Supercapacitor |
| title | Bioactive Ion‐Based Switchable Supercapacitors |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-17T06%3A56%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Bioactive%20Ion%E2%80%90Based%20Switchable%20Supercapacitors&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Li,%20Panlong&rft.date=2022-12-12&rft.volume=61&rft.issue=50&rft.spage=e202212250&rft.epage=n/a&rft.pages=e202212250-n/a&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/anie.202212250&rft_dat=%3Cproquest_pubme%3E2746821624%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2746821624&rft_id=info:pmid/36260635&rfr_iscdi=true |