Host Spin‐Crossover Thermodynamics Indicate Guest Fit

Spin‐crossover (SCO) metal‐organic cages capable of switching between high‐spin and low‐spin states have the potential to be used as magnetic sensors and switches. Variation of the donor strength of heterocyclic aldehyde subcomponents in imine‐based ligands can tune the ligand field for a FeII cente...

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Veröffentlicht in:	Angewandte Chemie International Edition 2022-12, Vol.61 (50), p.e202212634-n/a
Hauptverfasser:	Zheng, Jieyu, Krbek, Larissa K. S., Ronson, Tanya K., Nitschke, Jonathan R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Cages Crossovers Host–Guest Chemistry Imidazole Ligands Metal-Organic Cages Spin Crossover Supramolecular compounds Switches Tetrahedra Thermodynamics
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