Polymer Waste-Based Highly Efficient Maleated Interfacial Modifier in iPP/SCF Composites-Some Notes on the Role of Processing in Their Thermal and Dynamic Mechanical Properties
This work has a two-fold objective. First, it attempts to present the excellent efficiency of a maleated interfacial agent (obtained by the authors by using atactic polypropylene industrial waste) when used as interfacial additive in polypropylene/short carbon fiber composites (iPP/SCF). Second, in...
Gespeichert in:
Veröffentlicht in: | Polymers 2023-03, Vol.15 (6), p.1527 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | |
---|---|
container_issue | 6 |
container_start_page | 1527 |
container_title | Polymers |
container_volume | 15 |
creator | García-Martínez, Jesús-María P Collar, Emilia |
description | This work has a two-fold objective. First, it attempts to present the excellent efficiency of a maleated interfacial agent (obtained by the authors by using atactic polypropylene industrial waste) when used as interfacial additive in polypropylene/short carbon fiber composites (iPP/SCF). Second, in this paper, we pay attention to the role played by processing in the final properties of the composite. This work has been performed by considering the emerging crystalline morphologies generated by the different shear forces that the molten material suffers depending on the molding method employed. The interfacial agent analyzed here consists of an atactic polypropylene containing succinic anhydride grafts obtained through a chemical modification process performed in solution. It incorporates different types of succinic grafts, such as succinic bridges between aPP chains and backbone and terminal grafts (aPP-SASA) in its structure, and contains 5.6% (5.6 × 10
g/mol) of grafted polar groups in total. The adhesion of the polyamide SCF sizing and the succinic units is followed by Field Emission Scanning Electronic Microscopy (FESEM) and Synchrotron Infrared Microscopy (SIRM). However, the main objective of this work is the study of the thermal and the dynamic mechanical behavior of the materials of a series of both compression- and injection-molded samples to ascertain the enhanced interfacial interactions in the material and further comparison between the results obtained by both processing operations. Therefore, we detect improvements of 200% in stiffness and 400% in the viscous response of the same SCF content composites caused by aPP-SASA, depending on the processing method used. |
doi_str_mv | 10.3390/polym15061527 |
format | Article |
fullrecord | <record><control><sourceid>gale_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10053728</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A743935067</galeid><sourcerecordid>A743935067</sourcerecordid><originalsourceid>FETCH-LOGICAL-c411t-d42ead7281648ab633b1b42d2da721958441a968069cab3e99445b73ff7dd9d53</originalsourceid><addsrcrecordid>eNpdUsFu3CAQtapGTZTm2GuF1EsvTsBgs5yqdJs0kbLtqknVo4Vh2CWywQVvpf2rfmJntWmUBCQYzbz3hmGmKN4xesq5omdj7LcDq2nD6kq-Ko4qKnkpeENfP7EPi5Oc7ykuUTcNk2-KQ96omeRUHhV_lzsJSOSXzhOUn3UGS678at1vyYVz3ngIE1noHvSEkeswQXLaeN2TRbTeeaT6QPxyeXY7vyTzOIwx-wlyeRsHIN8imiQGMq2B_Ig9kOjIMkUDOfuw2lHv1uDT7kwDiupgyZdt0IM3ZAFmrYM36EbKCGnykN8WB073GU4e7uPi5-XF3fyqvPn-9Xp-flMawdhUWlGBtrKasUbMdNdw3rFOVLayWlZM1TMhmFbNjDbK6I6DUkLUneTOSWuVrflx8WmvO266AazBb0i6b8fkB522bdS-fR4Jft2u4p-WUVpzTIwKHx8UUvy9gTy1g88G-l4HiJvcVlJVQjVKMYR-eAG9j5sUsL4diklKsV2IOt2jVtiO1gcXMbHBbQG_KwZwHv3nUnDFcSYkEso9waSYcwL3-HxG290Atc8GCPHvn9b8iP4_LvwfW1_DUg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2791700873</pqid></control><display><type>article</type><title>Polymer Waste-Based Highly Efficient Maleated Interfacial Modifier in iPP/SCF Composites-Some Notes on the Role of Processing in Their Thermal and Dynamic Mechanical Properties</title><source>PubMed (Medline)</source><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central Open Access</source><creator>García-Martínez, Jesús-María ; P Collar, Emilia</creator><creatorcontrib>García-Martínez, Jesús-María ; P Collar, Emilia</creatorcontrib><description>This work has a two-fold objective. First, it attempts to present the excellent efficiency of a maleated interfacial agent (obtained by the authors by using atactic polypropylene industrial waste) when used as interfacial additive in polypropylene/short carbon fiber composites (iPP/SCF). Second, in this paper, we pay attention to the role played by processing in the final properties of the composite. This work has been performed by considering the emerging crystalline morphologies generated by the different shear forces that the molten material suffers depending on the molding method employed. The interfacial agent analyzed here consists of an atactic polypropylene containing succinic anhydride grafts obtained through a chemical modification process performed in solution. It incorporates different types of succinic grafts, such as succinic bridges between aPP chains and backbone and terminal grafts (aPP-SASA) in its structure, and contains 5.6% (5.6 × 10
g/mol) of grafted polar groups in total. The adhesion of the polyamide SCF sizing and the succinic units is followed by Field Emission Scanning Electronic Microscopy (FESEM) and Synchrotron Infrared Microscopy (SIRM). However, the main objective of this work is the study of the thermal and the dynamic mechanical behavior of the materials of a series of both compression- and injection-molded samples to ascertain the enhanced interfacial interactions in the material and further comparison between the results obtained by both processing operations. Therefore, we detect improvements of 200% in stiffness and 400% in the viscous response of the same SCF content composites caused by aPP-SASA, depending on the processing method used.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym15061527</identifier><identifier>PMID: 36987307</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Atacticity ; Carbon fiber reinforced plastics ; Carbon fibers ; Dynamic mechanical properties ; Fiber composites ; Field emission microscopy ; Grafting ; Industrial wastes ; Injection molding ; Mechanical properties ; Polyamide resins ; Polyamides ; Polymers ; Polypropylene ; Shear forces ; Stiffness ; Synchrotrons</subject><ispartof>Polymers, 2023-03, Vol.15 (6), p.1527</ispartof><rights>COPYRIGHT 2023 MDPI AG</rights><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2023 by the authors. 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c411t-d42ead7281648ab633b1b42d2da721958441a968069cab3e99445b73ff7dd9d53</cites><orcidid>0000-0002-9365-8674 ; 0000-0002-6541-4816</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10053728/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10053728/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36987307$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>García-Martínez, Jesús-María</creatorcontrib><creatorcontrib>P Collar, Emilia</creatorcontrib><title>Polymer Waste-Based Highly Efficient Maleated Interfacial Modifier in iPP/SCF Composites-Some Notes on the Role of Processing in Their Thermal and Dynamic Mechanical Properties</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>This work has a two-fold objective. First, it attempts to present the excellent efficiency of a maleated interfacial agent (obtained by the authors by using atactic polypropylene industrial waste) when used as interfacial additive in polypropylene/short carbon fiber composites (iPP/SCF). Second, in this paper, we pay attention to the role played by processing in the final properties of the composite. This work has been performed by considering the emerging crystalline morphologies generated by the different shear forces that the molten material suffers depending on the molding method employed. The interfacial agent analyzed here consists of an atactic polypropylene containing succinic anhydride grafts obtained through a chemical modification process performed in solution. It incorporates different types of succinic grafts, such as succinic bridges between aPP chains and backbone and terminal grafts (aPP-SASA) in its structure, and contains 5.6% (5.6 × 10
g/mol) of grafted polar groups in total. The adhesion of the polyamide SCF sizing and the succinic units is followed by Field Emission Scanning Electronic Microscopy (FESEM) and Synchrotron Infrared Microscopy (SIRM). However, the main objective of this work is the study of the thermal and the dynamic mechanical behavior of the materials of a series of both compression- and injection-molded samples to ascertain the enhanced interfacial interactions in the material and further comparison between the results obtained by both processing operations. Therefore, we detect improvements of 200% in stiffness and 400% in the viscous response of the same SCF content composites caused by aPP-SASA, depending on the processing method used.</description><subject>Atacticity</subject><subject>Carbon fiber reinforced plastics</subject><subject>Carbon fibers</subject><subject>Dynamic mechanical properties</subject><subject>Fiber composites</subject><subject>Field emission microscopy</subject><subject>Grafting</subject><subject>Industrial wastes</subject><subject>Injection molding</subject><subject>Mechanical properties</subject><subject>Polyamide resins</subject><subject>Polyamides</subject><subject>Polymers</subject><subject>Polypropylene</subject><subject>Shear forces</subject><subject>Stiffness</subject><subject>Synchrotrons</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdUsFu3CAQtapGTZTm2GuF1EsvTsBgs5yqdJs0kbLtqknVo4Vh2CWywQVvpf2rfmJntWmUBCQYzbz3hmGmKN4xesq5omdj7LcDq2nD6kq-Ko4qKnkpeENfP7EPi5Oc7ykuUTcNk2-KQ96omeRUHhV_lzsJSOSXzhOUn3UGS678at1vyYVz3ngIE1noHvSEkeswQXLaeN2TRbTeeaT6QPxyeXY7vyTzOIwx-wlyeRsHIN8imiQGMq2B_Ig9kOjIMkUDOfuw2lHv1uDT7kwDiupgyZdt0IM3ZAFmrYM36EbKCGnykN8WB073GU4e7uPi5-XF3fyqvPn-9Xp-flMawdhUWlGBtrKasUbMdNdw3rFOVLayWlZM1TMhmFbNjDbK6I6DUkLUneTOSWuVrflx8WmvO266AazBb0i6b8fkB522bdS-fR4Jft2u4p-WUVpzTIwKHx8UUvy9gTy1g88G-l4HiJvcVlJVQjVKMYR-eAG9j5sUsL4diklKsV2IOt2jVtiO1gcXMbHBbQG_KwZwHv3nUnDFcSYkEso9waSYcwL3-HxG290Atc8GCPHvn9b8iP4_LvwfW1_DUg</recordid><startdate>20230320</startdate><enddate>20230320</enddate><creator>García-Martínez, Jesús-María</creator><creator>P Collar, Emilia</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-9365-8674</orcidid><orcidid>https://orcid.org/0000-0002-6541-4816</orcidid></search><sort><creationdate>20230320</creationdate><title>Polymer Waste-Based Highly Efficient Maleated Interfacial Modifier in iPP/SCF Composites-Some Notes on the Role of Processing in Their Thermal and Dynamic Mechanical Properties</title><author>García-Martínez, Jesús-María ; P Collar, Emilia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c411t-d42ead7281648ab633b1b42d2da721958441a968069cab3e99445b73ff7dd9d53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Atacticity</topic><topic>Carbon fiber reinforced plastics</topic><topic>Carbon fibers</topic><topic>Dynamic mechanical properties</topic><topic>Fiber composites</topic><topic>Field emission microscopy</topic><topic>Grafting</topic><topic>Industrial wastes</topic><topic>Injection molding</topic><topic>Mechanical properties</topic><topic>Polyamide resins</topic><topic>Polyamides</topic><topic>Polymers</topic><topic>Polypropylene</topic><topic>Shear forces</topic><topic>Stiffness</topic><topic>Synchrotrons</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>García-Martínez, Jesús-María</creatorcontrib><creatorcontrib>P Collar, Emilia</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Access via ProQuest (Open Access)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>García-Martínez, Jesús-María</au><au>P Collar, Emilia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymer Waste-Based Highly Efficient Maleated Interfacial Modifier in iPP/SCF Composites-Some Notes on the Role of Processing in Their Thermal and Dynamic Mechanical Properties</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2023-03-20</date><risdate>2023</risdate><volume>15</volume><issue>6</issue><spage>1527</spage><pages>1527-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>This work has a two-fold objective. First, it attempts to present the excellent efficiency of a maleated interfacial agent (obtained by the authors by using atactic polypropylene industrial waste) when used as interfacial additive in polypropylene/short carbon fiber composites (iPP/SCF). Second, in this paper, we pay attention to the role played by processing in the final properties of the composite. This work has been performed by considering the emerging crystalline morphologies generated by the different shear forces that the molten material suffers depending on the molding method employed. The interfacial agent analyzed here consists of an atactic polypropylene containing succinic anhydride grafts obtained through a chemical modification process performed in solution. It incorporates different types of succinic grafts, such as succinic bridges between aPP chains and backbone and terminal grafts (aPP-SASA) in its structure, and contains 5.6% (5.6 × 10
g/mol) of grafted polar groups in total. The adhesion of the polyamide SCF sizing and the succinic units is followed by Field Emission Scanning Electronic Microscopy (FESEM) and Synchrotron Infrared Microscopy (SIRM). However, the main objective of this work is the study of the thermal and the dynamic mechanical behavior of the materials of a series of both compression- and injection-molded samples to ascertain the enhanced interfacial interactions in the material and further comparison between the results obtained by both processing operations. Therefore, we detect improvements of 200% in stiffness and 400% in the viscous response of the same SCF content composites caused by aPP-SASA, depending on the processing method used.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>36987307</pmid><doi>10.3390/polym15061527</doi><orcidid>https://orcid.org/0000-0002-9365-8674</orcidid><orcidid>https://orcid.org/0000-0002-6541-4816</orcidid><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 2073-4360 |
ispartof | Polymers, 2023-03, Vol.15 (6), p.1527 |
issn | 2073-4360 2073-4360 |
language | eng |
recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10053728 |
source | PubMed (Medline); MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central Open Access |
subjects | Atacticity Carbon fiber reinforced plastics Carbon fibers Dynamic mechanical properties Fiber composites Field emission microscopy Grafting Industrial wastes Injection molding Mechanical properties Polyamide resins Polyamides Polymers Polypropylene Shear forces Stiffness Synchrotrons |
title | Polymer Waste-Based Highly Efficient Maleated Interfacial Modifier in iPP/SCF Composites-Some Notes on the Role of Processing in Their Thermal and Dynamic Mechanical Properties |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T12%3A02%3A29IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Polymer%20Waste-Based%20Highly%20Efficient%20Maleated%20Interfacial%20Modifier%20in%20iPP/SCF%20Composites-Some%20Notes%20on%20the%20Role%20of%20Processing%20in%20Their%20Thermal%20and%20Dynamic%20Mechanical%20Properties&rft.jtitle=Polymers&rft.au=Garc%C3%ADa-Mart%C3%ADnez,%20Jes%C3%BAs-Mar%C3%ADa&rft.date=2023-03-20&rft.volume=15&rft.issue=6&rft.spage=1527&rft.pages=1527-&rft.issn=2073-4360&rft.eissn=2073-4360&rft_id=info:doi/10.3390/polym15061527&rft_dat=%3Cgale_pubme%3EA743935067%3C/gale_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2791700873&rft_id=info:pmid/36987307&rft_galeid=A743935067&rfr_iscdi=true |