Anaerobic Hydroxylation of C(sp3)–H Bonds Enabled by the Synergistic Nature of Photoexcited Nitroarenes

A photoexcited-nitroarene-mediated anaerobic C–H hydroxylation of aliphatic systems is reported. The success of this reaction is due to the bifunctional nature of the photoexcited nitroarene, which serves as the C–H bond activator and the oxygen atom source. Compared to previous methods, this approa...

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Veröffentlicht in:	Journal of the American Chemical Society 2023-02, Vol.145 (5), p.2794-2799
Hauptverfasser:	Paolillo, Joshua M., Duke, Alana D., Gogarnoiu, Emma S., Wise, Dan E., Parasram, Marvin
Format:	Artikel
Sprache:	eng
Schlagworte:	Communication
Online-Zugang:	Volltext
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