Detection of Air Pollutants with Tunable Diode Lasers

Preliminary experiments indicate that tunable Pb(1-x)Sn(x)Te diode lasers will be useful in the identification and sensitive detection of most of the atmospheric pollutant gases. For point-sampling applications, concentrations in the parts-per-billion range should be measurable with very high specif...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 1971-02, Vol.171 (3972), p.635-639
Hauptverfasser: Hinkley, E. D., Kelley, P. L.
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description Preliminary experiments indicate that tunable Pb(1-x)Sn(x)Te diode lasers will be useful in the identification and sensitive detection of most of the atmospheric pollutant gases. For point-sampling applications, concentrations in the parts-per-billion range should be measurable with very high specificity. For long-range atmospheric transmission techniques, the improved resolution capability and tunability of these diode lasers make them attractive replacements for spectrometers and fixed-frequency laser sources where operation at cryogenic temperatures is not a serious impediment. By using these lasers as tunable local oscillators in the infrared heterodyne configuration, remote passive detection of gases present in smokestack effluent appears possible. Finally, pulsed operation at temperatures available with simple cryogenic coolers permits immediate application to the fast detection of gases present in automobile exhaust and in chemical processing plants.
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Finally, pulsed operation at temperatures available with simple cryogenic coolers permits immediate application to the fast detection of gases present in automobile exhaust and in chemical processing plants.</description><subject>500200 - Environment, Atmospheric- Chemicals Monitoring &amp; Transport- (-1989)</subject><subject>AIR POLLUTION</subject><subject>Air Pollution - analysis</subject><subject>AIR POLLUTION MONITORING</subject><subject>Ammonia</subject><subject>Atmospheric Pressure</subject><subject>AUTOMOBILES</subject><subject>Carbon dioxide emissions</subject><subject>CHEMICAL INDUSTRY</subject><subject>Cold Temperature</subject><subject>ENVIRONMENTAL SCIENCES</subject><subject>Ethylenes</subject><subject>EXHAUST GASES</subject><subject>FLUIDS</subject><subject>Fluorides</subject><subject>GASEOUS WASTES</subject><subject>GASES</subject><subject>Gases - analysis</subject><subject>INDUSTRY</subject><subject>Infrared Rays</subject><subject>LASERS</subject><subject>Lead</subject><subject>Methods</subject><subject>Micrometers</subject><subject>Pollutant emissions</subject><subject>Pollutants</subject><subject>POLLUTION</subject><subject>Pollution monitoring</subject><subject>REMOTE SENSING</subject><subject>SAMPLING</subject><subject>SEMICONDUCTOR DEVICES</subject><subject>Semiconductor diodes</subject><subject>SEMICONDUCTOR LASERS</subject><subject>Spectrum Analysis</subject><subject>Telluric lines</subject><subject>Tellurium</subject><subject>Tin</subject><subject>USES</subject><subject>VEHICLES</subject><subject>WASTES</subject><issn>0036-8075</issn><issn>1095-9203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1971</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNo9j8tqwzAUREVpSdO0f5CC6N6upKuHtQxJXxBoF-nayNINUXDsYCmU_n0NCV3N4gzDHELmnJWcC_2cfMTOY8kNL8EaUWpQV2TKmVWFFQyuyZQx0EXFjLoldyntGRuZhQmZKCUZMDElaoUZfY59R_stXcSBfvVte8quy4n-xLyjm1PnmhbpKvYB6dolHNI9udm6NuHDJWfk-_Vls3wv1p9vH8vFuvAAKhc-WJRMc9047nzjBQcWpABpNRPBCOVF8BadA9SIxlSuUsa5CllQGBzCjDydd_uUYz0Kj193vu-68XKthbXamrH0eC4dT80BQ30c4sENv_XFceTzM9-n3A__mBvgUkr4A1NOXec</recordid><startdate>19710219</startdate><enddate>19710219</enddate><creator>Hinkley, E. 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D.</creatorcontrib><creatorcontrib>Kelley, P. L.</creatorcontrib><creatorcontrib>Massachusetts Institute of Technology, Lexington</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>OSTI.GOV</collection><jtitle>Science (American Association for the Advancement of Science)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hinkley, E. D.</au><au>Kelley, P. 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For long-range atmospheric transmission techniques, the improved resolution capability and tunability of these diode lasers make them attractive replacements for spectrometers and fixed-frequency laser sources where operation at cryogenic temperatures is not a serious impediment. By using these lasers as tunable local oscillators in the infrared heterodyne configuration, remote passive detection of gases present in smokestack effluent appears possible. Finally, pulsed operation at temperatures available with simple cryogenic coolers permits immediate application to the fast detection of gases present in automobile exhaust and in chemical processing plants.</abstract><cop>United States</cop><pub>American Association for the Advancement of Science</pub><pmid>5540302</pmid><doi>10.1126/science.171.3972.635</doi><tpages>5</tpages></addata></record>
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source American Association for the Advancement of Science; Jstor Complete Legacy; MEDLINE
subjects 500200 - Environment, Atmospheric- Chemicals Monitoring & Transport- (-1989)
AIR POLLUTION
Air Pollution - analysis
AIR POLLUTION MONITORING
Ammonia
Atmospheric Pressure
AUTOMOBILES
Carbon dioxide emissions
CHEMICAL INDUSTRY
Cold Temperature
ENVIRONMENTAL SCIENCES
Ethylenes
EXHAUST GASES
FLUIDS
Fluorides
GASEOUS WASTES
GASES
Gases - analysis
INDUSTRY
Infrared Rays
LASERS
Lead
Methods
Micrometers
Pollutant emissions
Pollutants
POLLUTION
Pollution monitoring
REMOTE SENSING
SAMPLING
SEMICONDUCTOR DEVICES
Semiconductor diodes
SEMICONDUCTOR LASERS
Spectrum Analysis
Telluric lines
Tellurium
Tin
USES
VEHICLES
WASTES
title Detection of Air Pollutants with Tunable Diode Lasers
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