Reducing noble metal dependence: oxygen evolution reaction with a Ru-minimized Bi 2 Ru 2 O 7 @MOF-801 composite

Reducing noble metal dependence: oxygen evolution reaction with a Ru-minimized Bi 2 Ru 2 O 7 @MOF-801 composite

Developing efficient and noble metal-minimized electrocatalysts for the oxygen evolution reactions (OER) is critical for energy conversion reactions. Here we present Ru-minimized Bi Ru O @MOF-801 that synergistically combines the high catalytic activity of the bimetallic oxide with the unique struct...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Nanoscale 2025-01
Hauptverfasser: Sujita, P, Gupta, Keshav, Gopal, V, Sarmila, S, Vadivel, Sethumathavan
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue
container_start_page
container_title Nanoscale
container_volume
creator Sujita, P
Gupta, Keshav
Gopal, V
Sarmila, S
Vadivel, Sethumathavan
description Developing efficient and noble metal-minimized electrocatalysts for the oxygen evolution reactions (OER) is critical for energy conversion reactions. Here we present Ru-minimized Bi Ru O @MOF-801 that synergistically combines the high catalytic activity of the bimetallic oxide with the unique structural and hydrophilic properties of the Zr-MOF. The composite achieves superior OER performance with a low overpotential of 307 mV at 50 mA cm and a Tafel slope of 99.8 mV dec surpassing those of pure Bi Ru O and MOF-801. Comparative testing with cutting-edge catalysts shows that using less Ru and incorporating a MOF work well together, providing a promising way to make high-performance OER catalysts that are also cost-effective by integrating the MOF for energy applications.
doi_str_mv 10.1039/d4nr04140b
format Article
fullrecord <record><control><sourceid>pubmed</sourceid><recordid>TN_cdi_pubmed_primary_39791231</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>39791231</sourcerecordid><originalsourceid>FETCH-pubmed_primary_397912313</originalsourceid><addsrcrecordid>eNqFjs1qwkAUhYeCaFq78QHkvkDaO5lgGlelYnAjgriXSeZqr2RmQn5a49M3lHbt5pyPw7c4QswkvkhU6auJXY2xjDF_EEGEMYZKJdFEPDbNBXGRqoUai4lKk1RGSgbC78l0BbszOJ-XBJZaXYKhipwhV9AS_LU_kwP68mXXsndQky5-4ZvbT9Cw70LLji3fyMAHQzQsQ-wggfftLgvfUELhbeUbbmkqRiddNvT8109inq0Pq01Ydbklc6xqtrruj_8P1V3hB7hKSZM</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Reducing noble metal dependence: oxygen evolution reaction with a Ru-minimized Bi 2 Ru 2 O 7 @MOF-801 composite</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Sujita, P ; Gupta, Keshav ; Gopal, V ; Sarmila, S ; Vadivel, Sethumathavan</creator><creatorcontrib>Sujita, P ; Gupta, Keshav ; Gopal, V ; Sarmila, S ; Vadivel, Sethumathavan</creatorcontrib><description>Developing efficient and noble metal-minimized electrocatalysts for the oxygen evolution reactions (OER) is critical for energy conversion reactions. Here we present Ru-minimized Bi Ru O @MOF-801 that synergistically combines the high catalytic activity of the bimetallic oxide with the unique structural and hydrophilic properties of the Zr-MOF. The composite achieves superior OER performance with a low overpotential of 307 mV at 50 mA cm and a Tafel slope of 99.8 mV dec surpassing those of pure Bi Ru O and MOF-801. Comparative testing with cutting-edge catalysts shows that using less Ru and incorporating a MOF work well together, providing a promising way to make high-performance OER catalysts that are also cost-effective by integrating the MOF for energy applications.</description><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/d4nr04140b</identifier><identifier>PMID: 39791231</identifier><language>eng</language><publisher>England</publisher><ispartof>Nanoscale, 2025-01</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0009-0003-7798-2209 ; 0000-0003-0318-192X ; 0009-0002-7433-2617</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27911,27912</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39791231$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Sujita, P</creatorcontrib><creatorcontrib>Gupta, Keshav</creatorcontrib><creatorcontrib>Gopal, V</creatorcontrib><creatorcontrib>Sarmila, S</creatorcontrib><creatorcontrib>Vadivel, Sethumathavan</creatorcontrib><title>Reducing noble metal dependence: oxygen evolution reaction with a Ru-minimized Bi 2 Ru 2 O 7 @MOF-801 composite</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>Developing efficient and noble metal-minimized electrocatalysts for the oxygen evolution reactions (OER) is critical for energy conversion reactions. Here we present Ru-minimized Bi Ru O @MOF-801 that synergistically combines the high catalytic activity of the bimetallic oxide with the unique structural and hydrophilic properties of the Zr-MOF. The composite achieves superior OER performance with a low overpotential of 307 mV at 50 mA cm and a Tafel slope of 99.8 mV dec surpassing those of pure Bi Ru O and MOF-801. Comparative testing with cutting-edge catalysts shows that using less Ru and incorporating a MOF work well together, providing a promising way to make high-performance OER catalysts that are also cost-effective by integrating the MOF for energy applications.</description><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2025</creationdate><recordtype>article</recordtype><recordid>eNqFjs1qwkAUhYeCaFq78QHkvkDaO5lgGlelYnAjgriXSeZqr2RmQn5a49M3lHbt5pyPw7c4QswkvkhU6auJXY2xjDF_EEGEMYZKJdFEPDbNBXGRqoUai4lKk1RGSgbC78l0BbszOJ-XBJZaXYKhipwhV9AS_LU_kwP68mXXsndQky5-4ZvbT9Cw70LLji3fyMAHQzQsQ-wggfftLgvfUELhbeUbbmkqRiddNvT8109inq0Pq01Ydbklc6xqtrruj_8P1V3hB7hKSZM</recordid><startdate>20250110</startdate><enddate>20250110</enddate><creator>Sujita, P</creator><creator>Gupta, Keshav</creator><creator>Gopal, V</creator><creator>Sarmila, S</creator><creator>Vadivel, Sethumathavan</creator><scope>NPM</scope><orcidid>https://orcid.org/0009-0003-7798-2209</orcidid><orcidid>https://orcid.org/0000-0003-0318-192X</orcidid><orcidid>https://orcid.org/0009-0002-7433-2617</orcidid></search><sort><creationdate>20250110</creationdate><title>Reducing noble metal dependence: oxygen evolution reaction with a Ru-minimized Bi 2 Ru 2 O 7 @MOF-801 composite</title><author>Sujita, P ; Gupta, Keshav ; Gopal, V ; Sarmila, S ; Vadivel, Sethumathavan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmed_primary_397912313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2025</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sujita, P</creatorcontrib><creatorcontrib>Gupta, Keshav</creatorcontrib><creatorcontrib>Gopal, V</creatorcontrib><creatorcontrib>Sarmila, S</creatorcontrib><creatorcontrib>Vadivel, Sethumathavan</creatorcontrib><collection>PubMed</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sujita, P</au><au>Gupta, Keshav</au><au>Gopal, V</au><au>Sarmila, S</au><au>Vadivel, Sethumathavan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reducing noble metal dependence: oxygen evolution reaction with a Ru-minimized Bi 2 Ru 2 O 7 @MOF-801 composite</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2025-01-10</date><risdate>2025</risdate><eissn>2040-3372</eissn><abstract>Developing efficient and noble metal-minimized electrocatalysts for the oxygen evolution reactions (OER) is critical for energy conversion reactions. Here we present Ru-minimized Bi Ru O @MOF-801 that synergistically combines the high catalytic activity of the bimetallic oxide with the unique structural and hydrophilic properties of the Zr-MOF. The composite achieves superior OER performance with a low overpotential of 307 mV at 50 mA cm and a Tafel slope of 99.8 mV dec surpassing those of pure Bi Ru O and MOF-801. Comparative testing with cutting-edge catalysts shows that using less Ru and incorporating a MOF work well together, providing a promising way to make high-performance OER catalysts that are also cost-effective by integrating the MOF for energy applications.</abstract><cop>England</cop><pmid>39791231</pmid><doi>10.1039/d4nr04140b</doi><orcidid>https://orcid.org/0009-0003-7798-2209</orcidid><orcidid>https://orcid.org/0000-0003-0318-192X</orcidid><orcidid>https://orcid.org/0009-0002-7433-2617</orcidid></addata></record>
fulltext fulltext
identifier EISSN: 2040-3372
ispartof Nanoscale, 2025-01
issn 2040-3372
language eng
recordid cdi_pubmed_primary_39791231
source Royal Society Of Chemistry Journals 2008-
title Reducing noble metal dependence: oxygen evolution reaction with a Ru-minimized Bi 2 Ru 2 O 7 @MOF-801 composite
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T12%3A59%3A23IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Reducing%20noble%20metal%20dependence:%20oxygen%20evolution%20reaction%20with%20a%20Ru-minimized%20Bi%202%20Ru%202%20O%207%20@MOF-801%20composite&rft.jtitle=Nanoscale&rft.au=Sujita,%20P&rft.date=2025-01-10&rft.eissn=2040-3372&rft_id=info:doi/10.1039/d4nr04140b&rft_dat=%3Cpubmed%3E39791231%3C/pubmed%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/39791231&rfr_iscdi=true