Fluorinated Conjugated Microporous Polymers Based on Pillar[n]arenes for Removal of Water Pollutants and Their Cation Selective Adsorption
Organic dyes are widely used in many applications. However, the leakage of organic dyes into the natural environment has become a severe and worldwide problem owing to their high toxicity and nonbiodegradability. Therefore, the development of effective removal technologies for organic dyes is requir...
Gespeichert in:
| Veröffentlicht in: | ACS applied materials & interfaces 2024-12, Vol.16 (50), p.69963-69972 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 69972 |
|---|---|
| container_issue | 50 |
| container_start_page | 69963 |
| container_title | ACS applied materials & interfaces |
| container_volume | 16 |
| creator | Togari, Yuki Ohtani, Shunsuke Kanao, Eisuke Sato, Kohei Mizuno, Motohiro Kato, Kenichi Mizuta, Ryosuke Sasaki, Yoshihiro Ogoshi, Tomoki |
| description | Organic dyes are widely used in many applications. However, the leakage of organic dyes into the natural environment has become a severe and worldwide problem owing to their high toxicity and nonbiodegradability. Therefore, the development of effective removal technologies for organic dyes is required. In this article, we report the synthesis and adsorption properties of highly fluorinated conjugated microporous polymers based on pillar[n]arenes. The polymers exhibited large Brunauer–Emmett–Teller surface areas of up to 1063 m2 g–1 and selective adsorptive removal of cationic organic dyes from aqueous solutions. Comparison with the nonfluorinated polymers indicated that the adsorption mechanism mainly relies on the fluorine–cation electrostatic interaction. The maximum adsorption capacity reached 313 mg g–1 for crystal violet, which is higher than those of conventional adsorbents. Additionally, the fluorinated polymers could function as proton channels when they were embedded into lipid membranes. |
| doi_str_mv | 10.1021/acsami.4c17877 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_pubmed_primary_39651559</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3154260367</sourcerecordid><originalsourceid>FETCH-LOGICAL-a215t-157313a1467025a226d2bbb50635ccc489807bf46ec55b19b11d1a833c730cbc3</originalsourceid><addsrcrecordid>eNp1kEtLAzEUhYMotla3LiVLEVrznMeyDlaFikUrLkSGTCajKTNJTWYK_Qv-alNb3bm6l3vPOXA-AE4xGmFE8KWQXjR6xCSOkzjeA32cMjZMCCf7fztjPXDk_QKhiBLED0GPphHHnKd98DWpO-u0Ea0qYWbNonv_We-1dHZpne08nNl63Sjn4ZXw4WUNnOm6Fu7VvAmnjPKwsg4-qsauRA1tBV9ChNvY6q4VpvVQmBLOP5R2MBOtDgFPqlay1SsFx6W3brk5HoODStRenezmADxPrufZ7XD6cHOXjadDQTBvh5jHFFOBWRQjwgUhUUmKouChHJdSsiRNUFxULFKS8wKnBcYlFgmlMqZIFpIOwPk2d-nsZ6d8mzfaSxUaGRXq5hRzRiJEozhIR1tpgOG9U1W-dLoRbp1jlG_451v--Y5_MJztsruiUeWf_Bd4EFxsBcGYL2znTKj6X9o3djqSJg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3154260367</pqid></control><display><type>article</type><title>Fluorinated Conjugated Microporous Polymers Based on Pillar[n]arenes for Removal of Water Pollutants and Their Cation Selective Adsorption</title><source>ACS Publications</source><creator>Togari, Yuki ; Ohtani, Shunsuke ; Kanao, Eisuke ; Sato, Kohei ; Mizuno, Motohiro ; Kato, Kenichi ; Mizuta, Ryosuke ; Sasaki, Yoshihiro ; Ogoshi, Tomoki</creator><creatorcontrib>Togari, Yuki ; Ohtani, Shunsuke ; Kanao, Eisuke ; Sato, Kohei ; Mizuno, Motohiro ; Kato, Kenichi ; Mizuta, Ryosuke ; Sasaki, Yoshihiro ; Ogoshi, Tomoki</creatorcontrib><description>Organic dyes are widely used in many applications. However, the leakage of organic dyes into the natural environment has become a severe and worldwide problem owing to their high toxicity and nonbiodegradability. Therefore, the development of effective removal technologies for organic dyes is required. In this article, we report the synthesis and adsorption properties of highly fluorinated conjugated microporous polymers based on pillar[n]arenes. The polymers exhibited large Brunauer–Emmett–Teller surface areas of up to 1063 m2 g–1 and selective adsorptive removal of cationic organic dyes from aqueous solutions. Comparison with the nonfluorinated polymers indicated that the adsorption mechanism mainly relies on the fluorine–cation electrostatic interaction. The maximum adsorption capacity reached 313 mg g–1 for crystal violet, which is higher than those of conventional adsorbents. Additionally, the fluorinated polymers could function as proton channels when they were embedded into lipid membranes.</description><identifier>ISSN: 1944-8244</identifier><identifier>ISSN: 1944-8252</identifier><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/acsami.4c17877</identifier><identifier>PMID: 39651559</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>adsorbents ; adsorption ; Applications of Polymer, Composite, and Coating Materials ; aromatic hydrocarbons ; cations ; electrostatic interactions ; gentian violet ; lipids ; porous media ; toxicity</subject><ispartof>ACS applied materials & interfaces, 2024-12, Vol.16 (50), p.69963-69972</ispartof><rights>2024 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-a215t-157313a1467025a226d2bbb50635ccc489807bf46ec55b19b11d1a833c730cbc3</cites><orcidid>0000-0002-4464-0347 ; 0000-0002-8948-8537 ; 0000-0002-1712-9308 ; 0000-0002-8669-1089 ; 0000-0001-5348-5521 ; 0000-0003-1333-5347 ; 0000-0001-7268-1501</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acsami.4c17877$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acsami.4c17877$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,778,782,2754,27063,27911,27912,56725,56775</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39651559$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Togari, Yuki</creatorcontrib><creatorcontrib>Ohtani, Shunsuke</creatorcontrib><creatorcontrib>Kanao, Eisuke</creatorcontrib><creatorcontrib>Sato, Kohei</creatorcontrib><creatorcontrib>Mizuno, Motohiro</creatorcontrib><creatorcontrib>Kato, Kenichi</creatorcontrib><creatorcontrib>Mizuta, Ryosuke</creatorcontrib><creatorcontrib>Sasaki, Yoshihiro</creatorcontrib><creatorcontrib>Ogoshi, Tomoki</creatorcontrib><title>Fluorinated Conjugated Microporous Polymers Based on Pillar[n]arenes for Removal of Water Pollutants and Their Cation Selective Adsorption</title><title>ACS applied materials & interfaces</title><addtitle>ACS Appl. Mater. Interfaces</addtitle><description>Organic dyes are widely used in many applications. However, the leakage of organic dyes into the natural environment has become a severe and worldwide problem owing to their high toxicity and nonbiodegradability. Therefore, the development of effective removal technologies for organic dyes is required. In this article, we report the synthesis and adsorption properties of highly fluorinated conjugated microporous polymers based on pillar[n]arenes. The polymers exhibited large Brunauer–Emmett–Teller surface areas of up to 1063 m2 g–1 and selective adsorptive removal of cationic organic dyes from aqueous solutions. Comparison with the nonfluorinated polymers indicated that the adsorption mechanism mainly relies on the fluorine–cation electrostatic interaction. The maximum adsorption capacity reached 313 mg g–1 for crystal violet, which is higher than those of conventional adsorbents. Additionally, the fluorinated polymers could function as proton channels when they were embedded into lipid membranes.</description><subject>adsorbents</subject><subject>adsorption</subject><subject>Applications of Polymer, Composite, and Coating Materials</subject><subject>aromatic hydrocarbons</subject><subject>cations</subject><subject>electrostatic interactions</subject><subject>gentian violet</subject><subject>lipids</subject><subject>porous media</subject><subject>toxicity</subject><issn>1944-8244</issn><issn>1944-8252</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLAzEUhYMotla3LiVLEVrznMeyDlaFikUrLkSGTCajKTNJTWYK_Qv-alNb3bm6l3vPOXA-AE4xGmFE8KWQXjR6xCSOkzjeA32cMjZMCCf7fztjPXDk_QKhiBLED0GPphHHnKd98DWpO-u0Ea0qYWbNonv_We-1dHZpne08nNl63Sjn4ZXw4WUNnOm6Fu7VvAmnjPKwsg4-qsauRA1tBV9ChNvY6q4VpvVQmBLOP5R2MBOtDgFPqlay1SsFx6W3brk5HoODStRenezmADxPrufZ7XD6cHOXjadDQTBvh5jHFFOBWRQjwgUhUUmKouChHJdSsiRNUFxULFKS8wKnBcYlFgmlMqZIFpIOwPk2d-nsZ6d8mzfaSxUaGRXq5hRzRiJEozhIR1tpgOG9U1W-dLoRbp1jlG_451v--Y5_MJztsruiUeWf_Bd4EFxsBcGYL2znTKj6X9o3djqSJg</recordid><startdate>20241218</startdate><enddate>20241218</enddate><creator>Togari, Yuki</creator><creator>Ohtani, Shunsuke</creator><creator>Kanao, Eisuke</creator><creator>Sato, Kohei</creator><creator>Mizuno, Motohiro</creator><creator>Kato, Kenichi</creator><creator>Mizuta, Ryosuke</creator><creator>Sasaki, Yoshihiro</creator><creator>Ogoshi, Tomoki</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0000-0002-4464-0347</orcidid><orcidid>https://orcid.org/0000-0002-8948-8537</orcidid><orcidid>https://orcid.org/0000-0002-1712-9308</orcidid><orcidid>https://orcid.org/0000-0002-8669-1089</orcidid><orcidid>https://orcid.org/0000-0001-5348-5521</orcidid><orcidid>https://orcid.org/0000-0003-1333-5347</orcidid><orcidid>https://orcid.org/0000-0001-7268-1501</orcidid></search><sort><creationdate>20241218</creationdate><title>Fluorinated Conjugated Microporous Polymers Based on Pillar[n]arenes for Removal of Water Pollutants and Their Cation Selective Adsorption</title><author>Togari, Yuki ; Ohtani, Shunsuke ; Kanao, Eisuke ; Sato, Kohei ; Mizuno, Motohiro ; Kato, Kenichi ; Mizuta, Ryosuke ; Sasaki, Yoshihiro ; Ogoshi, Tomoki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a215t-157313a1467025a226d2bbb50635ccc489807bf46ec55b19b11d1a833c730cbc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>adsorbents</topic><topic>adsorption</topic><topic>Applications of Polymer, Composite, and Coating Materials</topic><topic>aromatic hydrocarbons</topic><topic>cations</topic><topic>electrostatic interactions</topic><topic>gentian violet</topic><topic>lipids</topic><topic>porous media</topic><topic>toxicity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Togari, Yuki</creatorcontrib><creatorcontrib>Ohtani, Shunsuke</creatorcontrib><creatorcontrib>Kanao, Eisuke</creatorcontrib><creatorcontrib>Sato, Kohei</creatorcontrib><creatorcontrib>Mizuno, Motohiro</creatorcontrib><creatorcontrib>Kato, Kenichi</creatorcontrib><creatorcontrib>Mizuta, Ryosuke</creatorcontrib><creatorcontrib>Sasaki, Yoshihiro</creatorcontrib><creatorcontrib>Ogoshi, Tomoki</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>ACS applied materials & interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Togari, Yuki</au><au>Ohtani, Shunsuke</au><au>Kanao, Eisuke</au><au>Sato, Kohei</au><au>Mizuno, Motohiro</au><au>Kato, Kenichi</au><au>Mizuta, Ryosuke</au><au>Sasaki, Yoshihiro</au><au>Ogoshi, Tomoki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fluorinated Conjugated Microporous Polymers Based on Pillar[n]arenes for Removal of Water Pollutants and Their Cation Selective Adsorption</atitle><jtitle>ACS applied materials & interfaces</jtitle><addtitle>ACS Appl. Mater. Interfaces</addtitle><date>2024-12-18</date><risdate>2024</risdate><volume>16</volume><issue>50</issue><spage>69963</spage><epage>69972</epage><pages>69963-69972</pages><issn>1944-8244</issn><issn>1944-8252</issn><eissn>1944-8252</eissn><abstract>Organic dyes are widely used in many applications. However, the leakage of organic dyes into the natural environment has become a severe and worldwide problem owing to their high toxicity and nonbiodegradability. Therefore, the development of effective removal technologies for organic dyes is required. In this article, we report the synthesis and adsorption properties of highly fluorinated conjugated microporous polymers based on pillar[n]arenes. The polymers exhibited large Brunauer–Emmett–Teller surface areas of up to 1063 m2 g–1 and selective adsorptive removal of cationic organic dyes from aqueous solutions. Comparison with the nonfluorinated polymers indicated that the adsorption mechanism mainly relies on the fluorine–cation electrostatic interaction. The maximum adsorption capacity reached 313 mg g–1 for crystal violet, which is higher than those of conventional adsorbents. Additionally, the fluorinated polymers could function as proton channels when they were embedded into lipid membranes.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>39651559</pmid><doi>10.1021/acsami.4c17877</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-4464-0347</orcidid><orcidid>https://orcid.org/0000-0002-8948-8537</orcidid><orcidid>https://orcid.org/0000-0002-1712-9308</orcidid><orcidid>https://orcid.org/0000-0002-8669-1089</orcidid><orcidid>https://orcid.org/0000-0001-5348-5521</orcidid><orcidid>https://orcid.org/0000-0003-1333-5347</orcidid><orcidid>https://orcid.org/0000-0001-7268-1501</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1944-8244 |
| ispartof | ACS applied materials & interfaces, 2024-12, Vol.16 (50), p.69963-69972 |
| issn | 1944-8244 1944-8252 1944-8252 |
| language | eng |
| recordid | cdi_pubmed_primary_39651559 |
| source | ACS Publications |
| subjects | adsorbents adsorption Applications of Polymer, Composite, and Coating Materials aromatic hydrocarbons cations electrostatic interactions gentian violet lipids porous media toxicity |
| title | Fluorinated Conjugated Microporous Polymers Based on Pillar[n]arenes for Removal of Water Pollutants and Their Cation Selective Adsorption |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T18%3A38%3A23IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fluorinated%20Conjugated%20Microporous%20Polymers%20Based%20on%20Pillar%5Bn%5Darenes%20for%20Removal%20of%20Water%20Pollutants%20and%20Their%20Cation%20Selective%20Adsorption&rft.jtitle=ACS%20applied%20materials%20&%20interfaces&rft.au=Togari,%20Yuki&rft.date=2024-12-18&rft.volume=16&rft.issue=50&rft.spage=69963&rft.epage=69972&rft.pages=69963-69972&rft.issn=1944-8244&rft.eissn=1944-8252&rft_id=info:doi/10.1021/acsami.4c17877&rft_dat=%3Cproquest_cross%3E3154260367%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3154260367&rft_id=info:pmid/39651559&rfr_iscdi=true |