Photoinduced B-H Arylation of N-Heterocyclic Carbene Boranes with Sulfonyl(hetero)arenes

Arylborane complexes ligated by N-heterocyclic carbenes (NHCs) can be synthesized by photoirradiation of a mixture of NHC-boranes and sulfonyl(hetero)arenes. The reaction occurs under mild and convenient conditions without any photocatalyst, which are realized by a radical chain mechanism involving...

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Veröffentlicht in:Organic letters 2024-12
Hauptverfasser: Nishida, Tatsuya, Yonekura, Kyohei, Maeda, Katsuhiro, Shirakawa, Eiji, Taniguchi, Tsuyoshi
Format: Artikel
Sprache:eng
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