A cobalt-tetraphenylporphyrin-based hypercrosslinked polymer for efficient CO 2 photoreduction to CO
One of the main impediments during the CO photocatalytic reduction process is controlling a particular product's selectivity while keeping a high conversion rate. The adsorption and affinity of the catalyst for CO are key factors for achieving highly efficient CO reduction. Herein, we report a...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-12, Vol.60 (99), p.14774-14777 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Ullah, Saif Hu, Xunliang Zhang, Yaqin Hussain, Irshad Wang, Xiaoyan Gao, Hui Tan, Bien |
| description | One of the main impediments during the CO
photocatalytic reduction process is controlling a particular product's selectivity while keeping a high conversion rate. The adsorption and affinity of the catalyst for CO
are key factors for achieving highly efficient CO
reduction. Herein, we report a novel photocatalytic material, cobalt anchored onto a tetraphenylporphyrin-based hypercrosslinked polymer (HCP-CoTPP), which was designed for the efficient photoreduction of CO
to CO with an impressive evolution rate of 1449.9 μmol g
h
and nearly 100% selectivity in the presence of [Ru(Bpy)
]Cl
as a photosensitizer and sacrificial agent under visible light irradiation. |
| doi_str_mv | 10.1039/d4cc05331a |
| format | Article |
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photocatalytic reduction process is controlling a particular product's selectivity while keeping a high conversion rate. The adsorption and affinity of the catalyst for CO
are key factors for achieving highly efficient CO
reduction. Herein, we report a novel photocatalytic material, cobalt anchored onto a tetraphenylporphyrin-based hypercrosslinked polymer (HCP-CoTPP), which was designed for the efficient photoreduction of CO
to CO with an impressive evolution rate of 1449.9 μmol g
h
and nearly 100% selectivity in the presence of [Ru(Bpy)
]Cl
as a photosensitizer and sacrificial agent under visible light irradiation.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d4cc05331a</identifier><identifier>PMID: 39601642</identifier><language>eng</language><publisher>England</publisher><ispartof>Chemical communications (Cambridge, England), 2024-12, Vol.60 (99), p.14774-14777</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c582-e0c2eb6fcf535b7c988af61c98d0e4594482a31e3908a6e5410221a6b9b6fd223</cites><orcidid>0000-0001-7181-347X ; 0000-0003-1876-532X ; 0000-0001-5498-1236</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39601642$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ullah, Saif</creatorcontrib><creatorcontrib>Hu, Xunliang</creatorcontrib><creatorcontrib>Zhang, Yaqin</creatorcontrib><creatorcontrib>Hussain, Irshad</creatorcontrib><creatorcontrib>Wang, Xiaoyan</creatorcontrib><creatorcontrib>Gao, Hui</creatorcontrib><creatorcontrib>Tan, Bien</creatorcontrib><title>A cobalt-tetraphenylporphyrin-based hypercrosslinked polymer for efficient CO 2 photoreduction to CO</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>One of the main impediments during the CO
photocatalytic reduction process is controlling a particular product's selectivity while keeping a high conversion rate. The adsorption and affinity of the catalyst for CO
are key factors for achieving highly efficient CO
reduction. Herein, we report a novel photocatalytic material, cobalt anchored onto a tetraphenylporphyrin-based hypercrosslinked polymer (HCP-CoTPP), which was designed for the efficient photoreduction of CO
to CO with an impressive evolution rate of 1449.9 μmol g
h
and nearly 100% selectivity in the presence of [Ru(Bpy)
]Cl
as a photosensitizer and sacrificial agent under visible light irradiation.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNo9kEtPwzAQhC0EoqVw4Qcgn5ECfqbxsQrlIVXqpQdukWOvlUAaW457yL8nbYG9zGr07Wo0CN1T8kQJV89WGEMk51RfoDnlucikKD4vj7tU2ZILOUM3w_BFpqGyuEYzrnJCc8HmyK6w8bXuUpYgRR0a6Mcu-BiaMbZ9VusBLG7GANFEPwxd239PRvDduIeInY8YnGtNC33C5RYzHBqffAR7MKn1PU5-sm_RldPdAHe_ukC71_WufM8227ePcrXJjCxYBsQwqHNnnOSyXhpVFNrldFJLQEglRME0p8AVKXQOUlDCGNV5raYjyxhfoMfz21PUCK4Ksd3rOFaUVMemqhdRlqemVhP8cIbDod6D_Uf_quE_9TRlIg</recordid><startdate>20241210</startdate><enddate>20241210</enddate><creator>Ullah, Saif</creator><creator>Hu, Xunliang</creator><creator>Zhang, Yaqin</creator><creator>Hussain, Irshad</creator><creator>Wang, Xiaoyan</creator><creator>Gao, Hui</creator><creator>Tan, Bien</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-7181-347X</orcidid><orcidid>https://orcid.org/0000-0003-1876-532X</orcidid><orcidid>https://orcid.org/0000-0001-5498-1236</orcidid></search><sort><creationdate>20241210</creationdate><title>A cobalt-tetraphenylporphyrin-based hypercrosslinked polymer for efficient CO 2 photoreduction to CO</title><author>Ullah, Saif ; Hu, Xunliang ; Zhang, Yaqin ; Hussain, Irshad ; Wang, Xiaoyan ; Gao, Hui ; Tan, Bien</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c582-e0c2eb6fcf535b7c988af61c98d0e4594482a31e3908a6e5410221a6b9b6fd223</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ullah, Saif</creatorcontrib><creatorcontrib>Hu, Xunliang</creatorcontrib><creatorcontrib>Zhang, Yaqin</creatorcontrib><creatorcontrib>Hussain, Irshad</creatorcontrib><creatorcontrib>Wang, Xiaoyan</creatorcontrib><creatorcontrib>Gao, Hui</creatorcontrib><creatorcontrib>Tan, Bien</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ullah, Saif</au><au>Hu, Xunliang</au><au>Zhang, Yaqin</au><au>Hussain, Irshad</au><au>Wang, Xiaoyan</au><au>Gao, Hui</au><au>Tan, Bien</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A cobalt-tetraphenylporphyrin-based hypercrosslinked polymer for efficient CO 2 photoreduction to CO</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2024-12-10</date><risdate>2024</risdate><volume>60</volume><issue>99</issue><spage>14774</spage><epage>14777</epage><pages>14774-14777</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>One of the main impediments during the CO
photocatalytic reduction process is controlling a particular product's selectivity while keeping a high conversion rate. The adsorption and affinity of the catalyst for CO
are key factors for achieving highly efficient CO
reduction. Herein, we report a novel photocatalytic material, cobalt anchored onto a tetraphenylporphyrin-based hypercrosslinked polymer (HCP-CoTPP), which was designed for the efficient photoreduction of CO
to CO with an impressive evolution rate of 1449.9 μmol g
h
and nearly 100% selectivity in the presence of [Ru(Bpy)
]Cl
as a photosensitizer and sacrificial agent under visible light irradiation.</abstract><cop>England</cop><pmid>39601642</pmid><doi>10.1039/d4cc05331a</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-7181-347X</orcidid><orcidid>https://orcid.org/0000-0003-1876-532X</orcidid><orcidid>https://orcid.org/0000-0001-5498-1236</orcidid></addata></record> |
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| ispartof | Chemical communications (Cambridge, England), 2024-12, Vol.60 (99), p.14774-14777 |
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| language | eng |
| recordid | cdi_pubmed_primary_39601642 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | A cobalt-tetraphenylporphyrin-based hypercrosslinked polymer for efficient CO 2 photoreduction to CO |
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