Efficient Photosynthesis of Value-Added Chemicals by Electrocarboxylation of Bromobenzene with CO 2 Using a Solar Energy Conversion Device
Solar-driven CO conversion into high-value-added chemicals, powered by photovoltaics, is a promising technology for alleviating the global energy crisis and achieving carbon neutrality. However, most of these endeavors focus on CO electroreduction to small-molecule fuels such as CO and ethanol. In t...
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| Veröffentlicht in: | International journal of molecular sciences 2024-10, Vol.25 (19) |
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| container_issue | 19 |
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| container_title | International journal of molecular sciences |
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| creator | Zhang, Yingtian Gao, Cui Ren, Huaiyan Luo, Peipei Wan, Qi Zhou, Huawei Chen, Baoli Zhang, Xianxi |
| description | Solar-driven CO
conversion into high-value-added chemicals, powered by photovoltaics, is a promising technology for alleviating the global energy crisis and achieving carbon neutrality. However, most of these endeavors focus on CO
electroreduction to small-molecule fuels such as CO and ethanol. In this paper, inspired by the photosynthesis of green plants and artificial photosynthesis for the electroreduction of CO
into value-added fuel, CO
artificial photosynthesis for the electrocarboxylation of bromobenzene (BB) with CO
to generate the value-added carboxylation product methyl benzoate (MB) is demonstrated. Using two series-connected dye-sensitized photovoltaics and high-performance catalyst Ag electrodes, our artificial photosynthesis system achieves a 61.1% Faraday efficiency (FE) for carboxylation product MB and stability of the whole artificial photosynthesis for up to 4 h. In addition, this work provides a promising approach for the artificial photosynthesis of CO
electrocarboxylation into high-value chemicals using renewable energy sources. |
| doi_str_mv | 10.3390/ijms251910608 |
| format | Article |
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conversion into high-value-added chemicals, powered by photovoltaics, is a promising technology for alleviating the global energy crisis and achieving carbon neutrality. However, most of these endeavors focus on CO
electroreduction to small-molecule fuels such as CO and ethanol. In this paper, inspired by the photosynthesis of green plants and artificial photosynthesis for the electroreduction of CO
into value-added fuel, CO
artificial photosynthesis for the electrocarboxylation of bromobenzene (BB) with CO
to generate the value-added carboxylation product methyl benzoate (MB) is demonstrated. Using two series-connected dye-sensitized photovoltaics and high-performance catalyst Ag electrodes, our artificial photosynthesis system achieves a 61.1% Faraday efficiency (FE) for carboxylation product MB and stability of the whole artificial photosynthesis for up to 4 h. In addition, this work provides a promising approach for the artificial photosynthesis of CO
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electroreduction to small-molecule fuels such as CO and ethanol. In this paper, inspired by the photosynthesis of green plants and artificial photosynthesis for the electroreduction of CO
into value-added fuel, CO
artificial photosynthesis for the electrocarboxylation of bromobenzene (BB) with CO
to generate the value-added carboxylation product methyl benzoate (MB) is demonstrated. Using two series-connected dye-sensitized photovoltaics and high-performance catalyst Ag electrodes, our artificial photosynthesis system achieves a 61.1% Faraday efficiency (FE) for carboxylation product MB and stability of the whole artificial photosynthesis for up to 4 h. In addition, this work provides a promising approach for the artificial photosynthesis of CO
electrocarboxylation into high-value chemicals using renewable energy sources.</description><subject>Bromobenzenes - chemistry</subject><subject>Carbon Dioxide - chemistry</subject><subject>Carbon Dioxide - metabolism</subject><subject>Catalysis</subject><subject>Electrodes</subject><subject>Photosynthesis</subject><subject>Solar Energy</subject><issn>1422-0067</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFjr1OwzAURi0kRMvPyIruCwQcuw3NCCGIDSR-1spxbhpXtm9luwXzCDw1VIKZ6Szf-XQYOy_5pZQ1vzJrF8W8rEte8cUBm5YzIQrOq-sJO45xzbmQYl4fsYmsZ3xRy2rKvtphMNqgT_A0UqKYfRoxmgg0wJuyWyxu-h57aEZ0RisbocvQWtQpkFaho49sVTLk98JtIEcd-k_0CO8mjdA8goDXaPwKFDyTVQFaj2GVoSG_wxD35h3ujMZTdjj8_OPZL0_YxX370jwUm23nsF9ugnEq5OVfvPx38A2-6Vae</recordid><startdate>20241001</startdate><enddate>20241001</enddate><creator>Zhang, Yingtian</creator><creator>Gao, Cui</creator><creator>Ren, Huaiyan</creator><creator>Luo, Peipei</creator><creator>Wan, Qi</creator><creator>Zhou, Huawei</creator><creator>Chen, Baoli</creator><creator>Zhang, Xianxi</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope></search><sort><creationdate>20241001</creationdate><title>Efficient Photosynthesis of Value-Added Chemicals by Electrocarboxylation of Bromobenzene with CO 2 Using a Solar Energy Conversion Device</title><author>Zhang, Yingtian ; Gao, Cui ; Ren, Huaiyan ; Luo, Peipei ; Wan, Qi ; Zhou, Huawei ; Chen, Baoli ; Zhang, Xianxi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmed_primary_394089363</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Bromobenzenes - chemistry</topic><topic>Carbon Dioxide - chemistry</topic><topic>Carbon Dioxide - metabolism</topic><topic>Catalysis</topic><topic>Electrodes</topic><topic>Photosynthesis</topic><topic>Solar Energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yingtian</creatorcontrib><creatorcontrib>Gao, Cui</creatorcontrib><creatorcontrib>Ren, Huaiyan</creatorcontrib><creatorcontrib>Luo, Peipei</creatorcontrib><creatorcontrib>Wan, Qi</creatorcontrib><creatorcontrib>Zhou, Huawei</creatorcontrib><creatorcontrib>Chen, Baoli</creatorcontrib><creatorcontrib>Zhang, Xianxi</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><jtitle>International journal of molecular sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Yingtian</au><au>Gao, Cui</au><au>Ren, Huaiyan</au><au>Luo, Peipei</au><au>Wan, Qi</au><au>Zhou, Huawei</au><au>Chen, Baoli</au><au>Zhang, Xianxi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient Photosynthesis of Value-Added Chemicals by Electrocarboxylation of Bromobenzene with CO 2 Using a Solar Energy Conversion Device</atitle><jtitle>International journal of molecular sciences</jtitle><addtitle>Int J Mol Sci</addtitle><date>2024-10-01</date><risdate>2024</risdate><volume>25</volume><issue>19</issue><eissn>1422-0067</eissn><abstract>Solar-driven CO
conversion into high-value-added chemicals, powered by photovoltaics, is a promising technology for alleviating the global energy crisis and achieving carbon neutrality. However, most of these endeavors focus on CO
electroreduction to small-molecule fuels such as CO and ethanol. In this paper, inspired by the photosynthesis of green plants and artificial photosynthesis for the electroreduction of CO
into value-added fuel, CO
artificial photosynthesis for the electrocarboxylation of bromobenzene (BB) with CO
to generate the value-added carboxylation product methyl benzoate (MB) is demonstrated. Using two series-connected dye-sensitized photovoltaics and high-performance catalyst Ag electrodes, our artificial photosynthesis system achieves a 61.1% Faraday efficiency (FE) for carboxylation product MB and stability of the whole artificial photosynthesis for up to 4 h. In addition, this work provides a promising approach for the artificial photosynthesis of CO
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| source | MEDLINE; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; MDPI - Multidisciplinary Digital Publishing Institute; PubMed Central |
| subjects | Bromobenzenes - chemistry Carbon Dioxide - chemistry Carbon Dioxide - metabolism Catalysis Electrodes Photosynthesis Solar Energy |
| title | Efficient Photosynthesis of Value-Added Chemicals by Electrocarboxylation of Bromobenzene with CO 2 Using a Solar Energy Conversion Device |
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