Proximity-induced FRET and charge-transfer between quantum dots and curcumin enable reversible thermochromic hybrid polymeric films

This study introduces a novel strategy for developing reversible thermochromic fluorescent films by precisely controlling the nanoscale proximity of boron nitride quantum dots and curcumin molecules within a poly(3-hydroxybutyrate) matrix. The synergistic interaction and Förster resonance energy tra...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2024-09, Vol.6 (78), p.1954-1957
Hauptverfasser: Thomas, Jefin Parukoor, Amal Raj, R. B, Virat, G, Dev, Amarjith V, Vijayakumar, Chakkooth, Gowd, E. Bhoje
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container_end_page 1957
container_issue 78
container_start_page 1954
container_title Chemical communications (Cambridge, England)
container_volume 6
creator Thomas, Jefin Parukoor
Amal Raj, R. B
Virat, G
Dev, Amarjith V
Vijayakumar, Chakkooth
Gowd, E. Bhoje
description This study introduces a novel strategy for developing reversible thermochromic fluorescent films by precisely controlling the nanoscale proximity of boron nitride quantum dots and curcumin molecules within a poly(3-hydroxybutyrate) matrix. The synergistic interaction and Förster resonance energy transfer between these fluorophores result in an energy transfer efficiency of ∼94%. This approach enables tunable color changes in response to temperature variations, governed by the segmental mobility of polymer chains. Practical applications of these films as temperature sensors for water bottles and electronic devices are demonstrated, highlighting their potential in temperature monitoring, smart packaging, and thermal management systems. This study introduces a novel strategy for developing reversible thermochromic fluorescent films by precisely controlling the nanoscale proximity of boron nitride quantum dots and curcumin molecules within a poly(3-hydroxybutyrate) matrix.
doi_str_mv 10.1039/d4cc03184a
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ispartof Chemical communications (Cambridge, England), 2024-09, Vol.6 (78), p.1954-1957
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1364-548X
1364-548X
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Boron nitride
Chemical compounds
Electronic packaging
Energy transfer
Fluorescence
Management systems
Polyhydroxybutyrate
Polymer films
Quantum dots
Smart sensors
Temperature sensors
Thermal management
title Proximity-induced FRET and charge-transfer between quantum dots and curcumin enable reversible thermochromic hybrid polymeric films
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