Dicarbonyl-1κ 2 C -μ-chlorido-2:3κ 2 Cl : Cl -penta-chlorido-2κ 2 Cl ,3κ 3 Cl -[1(η 6 )-toluene]digallium(III)ruthenium(I)( Ru - Ga )

Dicarbonyl-1κ 2 C -μ-chlorido-2:3κ 2 Cl : Cl -penta-chlorido-2κ 2 Cl ,3κ 3 Cl -[1(η 6 )-toluene]digallium(III)ruthenium(I)( Ru - Ga )

The title compound, [RuGa Cl (C H )(CO) ] or [(CO) (GaCl )(η -toluene)Ru] [GaCl ] , was isolated from the reaction of Ga Cl with di-phenyl-silanediol in toluene, followed by the addition of Ru (CO) . The compound contains a ruthenium-gallium metal-metal bond with a length of 2.4575 (2) Å.

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Veröffentlicht in:IUCrData 2024-07, Vol.9 (Pt 7), p.x240657
Hauptverfasser: Smith, Danielle, Harakas, George N
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description The title compound, [RuGa Cl (C H )(CO) ] or [(CO) (GaCl )(η -toluene)Ru] [GaCl ] , was isolated from the reaction of Ga Cl with di-phenyl-silanediol in toluene, followed by the addition of Ru (CO) . The compound contains a ruthenium-gallium metal-metal bond with a length of 2.4575 (2) Å.
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title Dicarbonyl-1κ 2 C -μ-chlorido-2:3κ 2 Cl : Cl -penta-chlorido-2κ 2 Cl ,3κ 3 Cl -[1(η 6 )-toluene]digallium(III)ruthenium(I)( Ru - Ga )
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