Application of mixed phosphorus/sulfur ligands based on terpenoids in Pd-catalyzed asymmetric allylic substitution and Rh-catalyzed hydrogenation

A small library of easily prepared diamidophosphite-sulfides based on 1,3-thioether alcohols, primarily of terpenoid nature, was developed. Upon complexation with Pd( ii ) ions, these hemilabile ligands showed the ability to form both P , S -chelates and complexes with two ligands P -monodentately b...

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Veröffentlicht in:	Organic & biomolecular chemistry 2024-08, Vol.22 (31), p.6362-6369
Hauptverfasser:	Gavrilov, Konstantin N, Chuchelkin, Ilya V, Gavrilov, Vladislav K, Firsin, Ilya D, Trunina, Valeria M, Shiryaev, Alexey A, Shkirdova, Alena O, Bermesheva, Evgeniya V, Tafeenko, Victor A, Chernyshev, Vladimir V, Zimarev, Vladislav S, Goulioukina, Nataliya S
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetic acid Alcohols Alkylation Asymmetry Catalytic converters Chelates Chemical reactions Esters Hydrogenation Ketoesters Ligands Magnetic resonance spectroscopy NMR spectroscopy Nucleophiles Palladium Rhodium Substitution reactions Sulfur Terpenes X-ray diffraction
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