Squaramide-catalyzed enantioselective Michael addition of nitromethane to 2-enoylazaarenes: synthesis of chiral azaarene-containing γ-nitroketones

Bifunctional chiral squaramide-catalyzed highly enantioselective Michael addition of nitromethane to diverse 2-enoylazaarenes was successfully performed. This protocol provided a set of chiral azaarene-containing γ-nitroketones with up to 98% yield and 98% ee in a solvent-free catalytic system under...

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Veröffentlicht in:	RSC advances 2024-06, Vol.14 (28), p.256-26
Hauptverfasser:	Huang, Hong-Ping, Xie, Yu-Hang, Gan, Xu-Mei, Wen, Xin-Yu, Wang, Cui-Xia, Deng, Yan-Qiu, Zhang, Zhen-Wei
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Enantiomers Nitromethane
Online-Zugang:	Volltext
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