Boron difluoride modified zinc metal-organic framework-based "off-on" fluorescence sensor for tetracycline and Al 3+ detection

A novel fluorescence "off-on" probe was developed using a boron difluoride-modified zinc metal-organic framework (Zn-MOF3) for sensitive determination of tetracycline (TC) and Al . The Zn-MOF3 has excellent optical property and good applicability in aqueous phase. The fluorescence recorded...

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Veröffentlicht in:Mikrochimica acta (1966) 2024-02, Vol.191 (3), p.144
Hauptverfasser: Wang, Qihui, Du, Haochen, Tang, Rui, Wang, Xiaohui, Xie, Lei, Liu, Jun, Sun, Kang, Li, Zhonghui, Deng, Guowei
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container_issue 3
container_start_page 144
container_title Mikrochimica acta (1966)
container_volume 191
creator Wang, Qihui
Du, Haochen
Tang, Rui
Wang, Xiaohui
Xie, Lei
Liu, Jun
Sun, Kang
Li, Zhonghui
Deng, Guowei
description A novel fluorescence "off-on" probe was developed using a boron difluoride-modified zinc metal-organic framework (Zn-MOF3) for sensitive determination of tetracycline (TC) and Al . The Zn-MOF3 has excellent optical property and good applicability in aqueous phase. The fluorescence recorded at 436 nm was quenched at the excitation wavelength of 336 nm. Signal-off detection of tetracycline via fluorescence quenching of Zn-MOF3 is based on the inner filter effect. Fluorescence on-off-on detection of Al occurs via the specific binding between tetracycline and Al . The limits of detection for TC and Al were 28.4 nM and 106.7 nM, respectively. This probe exhibited high selectivity which was used for the determination of TC and Al with satisfied recoveries (89.8 to 105.6% for TC, 90.0 to 110.4% for Al ) and good precision (
doi_str_mv 10.1007/s00604-024-06211-9
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The Zn-MOF3 has excellent optical property and good applicability in aqueous phase. The fluorescence recorded at 436 nm was quenched at the excitation wavelength of 336 nm. Signal-off detection of tetracycline via fluorescence quenching of Zn-MOF3 is based on the inner filter effect. Fluorescence on-off-on detection of Al occurs via the specific binding between tetracycline and Al . The limits of detection for TC and Al were 28.4 nM and 106.7 nM, respectively. This probe exhibited high selectivity which was used for the determination of TC and Al with satisfied recoveries (89.8 to 105.6% for TC, 90.0 to 110.4% for Al ) and good precision (&lt; 5%) in milk. 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subjects Anti-Bacterial Agents
Boron Compounds
Fluorescence
Metal-Organic Frameworks
Tetracycline
Zinc
title Boron difluoride modified zinc metal-organic framework-based "off-on" fluorescence sensor for tetracycline and Al 3+ detection
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