A flexible pH sensor based on polyaniline@oily polyurethane/polypropylene spunbonded nonwoven fabric

To fabricate a two-electrode flexible pH sensor based on polypropylene spunbonded nonwoven fabric (PP SF), oily polyurethane (OPU) was first coated on the surface of PP SF to obtain OPU/PP SF. Then, silver/silver chloride (Ag/AgCl) paste, used as the reference electrode and conductive carbon (C) pas...

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Veröffentlicht in:RSC advances 2024-02, Vol.14 (8), p.5627-5637
Hauptverfasser: Zhu, Xiangxiang, Sun, Hui, Yu, Bin, Xu, Lei, Xiao, Hao, Fu, Zhuan, Gao, Tian, Yang, Xiaodong
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container_end_page 5637
container_issue 8
container_start_page 5627
container_title RSC advances
container_volume 14
creator Zhu, Xiangxiang
Sun, Hui
Yu, Bin
Xu, Lei
Xiao, Hao
Fu, Zhuan
Gao, Tian
Yang, Xiaodong
description To fabricate a two-electrode flexible pH sensor based on polypropylene spunbonded nonwoven fabric (PP SF), oily polyurethane (OPU) was first coated on the surface of PP SF to obtain OPU/PP SF. Then, silver/silver chloride (Ag/AgCl) paste, used as the reference electrode and conductive carbon (C) paste were transferred to the OPU/PP SF surface through screen printing. Polyaniline (PANI) was deposited on the surface of the C paste to form a sensing working electrode via the electro-chemical deposition method. The results showed that the surface of the obtained PANI@OPU/PP SF flexible pH sensor (3D PANI pH sensor) presented a three-dimensional (3D) porous network structure. The 3D PANI pH sensor had good mechanical properties, an excellent Nernst response (−67.67 mV pH −1 ) and linearity ( R 2 = 0.99) in the pH range from 2.00 to 8.00 in the normal state. In the bent state, the 3D PANI pH sensor retained similar sensitivity (−68.87 mV pH −1 ) and linearity ( R 2 = 0.99). Moreover, the 3D PANI pH sensor exhibited a short response time (8 s), excellent reversibility (1.20 mV), low temperature drift (−0.0872 mV pH −1 °C −1 ) and long-term stability (0.83 mV h −1 ) in the normal state. Furthermore, the 3D PANI pH sensor can be effectively applied for pH monitoring of liquids and fruits with irregular curved surfaces. The error margin is no more than 0.16 compared to a commercial pH meter. Structure, mechanism, and application of a 3D PANI pH sensor in liquid and fruit pH value detection.
doi_str_mv 10.1039/d3ra07878g
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Then, silver/silver chloride (Ag/AgCl) paste, used as the reference electrode and conductive carbon (C) paste were transferred to the OPU/PP SF surface through screen printing. Polyaniline (PANI) was deposited on the surface of the C paste to form a sensing working electrode via the electro-chemical deposition method. The results showed that the surface of the obtained PANI@OPU/PP SF flexible pH sensor (3D PANI pH sensor) presented a three-dimensional (3D) porous network structure. The 3D PANI pH sensor had good mechanical properties, an excellent Nernst response (−67.67 mV pH −1 ) and linearity ( R 2 = 0.99) in the pH range from 2.00 to 8.00 in the normal state. In the bent state, the 3D PANI pH sensor retained similar sensitivity (−68.87 mV pH −1 ) and linearity ( R 2 = 0.99). Moreover, the 3D PANI pH sensor exhibited a short response time (8 s), excellent reversibility (1.20 mV), low temperature drift (−0.0872 mV pH −1 °C −1 ) and long-term stability (0.83 mV h −1 ) in the normal state. Furthermore, the 3D PANI pH sensor can be effectively applied for pH monitoring of liquids and fruits with irregular curved surfaces. The error margin is no more than 0.16 compared to a commercial pH meter. 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subjects Chemistry
Electrodes
Linearity
Low temperature
Mechanical properties
Nonwoven fabrics
Polyanilines
Polypropylene
Polyurethane resins
Screen printing
Sensors
Silver chloride
title A flexible pH sensor based on polyaniline@oily polyurethane/polypropylene spunbonded nonwoven fabric
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