Fabrication of highly conductive, flexible, and hydrophobic Kevlar®@Ni-P-B@Cu@CS fabric with excellent self-cleaning performance for electromagnetic interference shielding

In this work, a simple and cost-effective method was proposed and developed to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate (Kevlar®@Ni-P-B@Cu@CS) composite fabric with high conductivity, high flexibility, high hydrophobicity, and high durability to ef...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2024-03, Vol.53 (1), p.4432-4443
Hauptverfasser: Shao, Qinsi, Wang, Hao, Zhang, Leilei, Wang, Xihai, Zhang, Hengxin, Bai, Ruicheng, Fu, Hongshan
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Shao, Qinsi
Wang, Hao
Zhang, Leilei
Wang, Xihai
Zhang, Hengxin
Bai, Ruicheng
Fu, Hongshan
description In this work, a simple and cost-effective method was proposed and developed to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate (Kevlar®@Ni-P-B@Cu@CS) composite fabric with high conductivity, high flexibility, high hydrophobicity, and high durability to effectively shield electromagnetic interference (EMI). In this method, an amorphous Ni-P-B alloy nanolayer was initially deposited onto a Kevlar® fabric via electroless plating. Afterward, a crystalline Cu nanolayer was deposited as the second layer via electroplating. Finally, a monolayer of copper stearate was innovatively self-assembled as the outermost protective layer. The Cu deposition was effectively adjusted and designed by controlling the plating current and plating time. The electrical resistance and contact angle of the optimized Kevlar®@Ni-P-B@Cu@CS composite fabric were as low as 3.2 mΩ sq −1 and as high as 115.39°, respectively, indicating that the fabric could withstand bending, tape-off, corrosion, and accelerated environmental tests. The average EMI-shielding efficiency of the durable composite fabric was 93.9 dB in the frequency range of 8.2-12.4 GHz, which was mainly attributed to the absorption loss. Thus, the proposed material configuration has promise for applications in aviation, aerospace, telecommunication, wearable devices, and military industries. A simple and cost-effective method to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate composite fabric with outstanding properties is successfully developed.
doi_str_mv 10.1039/d3dt04291j
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In this method, an amorphous Ni-P-B alloy nanolayer was initially deposited onto a Kevlar® fabric via electroless plating. Afterward, a crystalline Cu nanolayer was deposited as the second layer via electroplating. Finally, a monolayer of copper stearate was innovatively self-assembled as the outermost protective layer. The Cu deposition was effectively adjusted and designed by controlling the plating current and plating time. The electrical resistance and contact angle of the optimized Kevlar®@Ni-P-B@Cu@CS composite fabric were as low as 3.2 mΩ sq −1 and as high as 115.39°, respectively, indicating that the fabric could withstand bending, tape-off, corrosion, and accelerated environmental tests. The average EMI-shielding efficiency of the durable composite fabric was 93.9 dB in the frequency range of 8.2-12.4 GHz, which was mainly attributed to the absorption loss. Thus, the proposed material configuration has promise for applications in aviation, aerospace, telecommunication, wearable devices, and military industries. A simple and cost-effective method to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate composite fabric with outstanding properties is successfully developed.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d3dt04291j</identifier><identifier>PMID: 38349221</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Accelerated tests ; Aramid fiber reinforced plastics ; Contact angle ; Copper ; Copper stearate ; Corrosion tests ; Durability ; Electric contacts ; Electroless plating ; Electromagnetic interference ; Electromagnetic shielding ; Electroplating ; Environmental testing ; Frequency ranges ; Hydrophobicity ; Kevlar (trademark) ; Multilayers ; Nickel ; Self-assembly ; Wearable technology</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2024-03, Vol.53 (1), p.4432-4443</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c296t-afb9527e65f357daf8aa6b72b7d595b5ce3b37c13dcd79ff7e1a08f07fd7bb873</cites><orcidid>0000-0002-2762-5196</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38349221$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shao, Qinsi</creatorcontrib><creatorcontrib>Wang, Hao</creatorcontrib><creatorcontrib>Zhang, Leilei</creatorcontrib><creatorcontrib>Wang, Xihai</creatorcontrib><creatorcontrib>Zhang, Hengxin</creatorcontrib><creatorcontrib>Bai, Ruicheng</creatorcontrib><creatorcontrib>Fu, Hongshan</creatorcontrib><title>Fabrication of highly conductive, flexible, and hydrophobic Kevlar®@Ni-P-B@Cu@CS fabric with excellent self-cleaning performance for electromagnetic interference shielding</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>In this work, a simple and cost-effective method was proposed and developed to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate (Kevlar®@Ni-P-B@Cu@CS) composite fabric with high conductivity, high flexibility, high hydrophobicity, and high durability to effectively shield electromagnetic interference (EMI). In this method, an amorphous Ni-P-B alloy nanolayer was initially deposited onto a Kevlar® fabric via electroless plating. Afterward, a crystalline Cu nanolayer was deposited as the second layer via electroplating. Finally, a monolayer of copper stearate was innovatively self-assembled as the outermost protective layer. The Cu deposition was effectively adjusted and designed by controlling the plating current and plating time. The electrical resistance and contact angle of the optimized Kevlar®@Ni-P-B@Cu@CS composite fabric were as low as 3.2 mΩ sq −1 and as high as 115.39°, respectively, indicating that the fabric could withstand bending, tape-off, corrosion, and accelerated environmental tests. The average EMI-shielding efficiency of the durable composite fabric was 93.9 dB in the frequency range of 8.2-12.4 GHz, which was mainly attributed to the absorption loss. Thus, the proposed material configuration has promise for applications in aviation, aerospace, telecommunication, wearable devices, and military industries. 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Thus, the proposed material configuration has promise for applications in aviation, aerospace, telecommunication, wearable devices, and military industries. A simple and cost-effective method to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate composite fabric with outstanding properties is successfully developed.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38349221</pmid><doi>10.1039/d3dt04291j</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-2762-5196</orcidid></addata></record>
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1477-9234
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Accelerated tests
Aramid fiber reinforced plastics
Contact angle
Copper
Copper stearate
Corrosion tests
Durability
Electric contacts
Electroless plating
Electromagnetic interference
Electromagnetic shielding
Electroplating
Environmental testing
Frequency ranges
Hydrophobicity
Kevlar (trademark)
Multilayers
Nickel
Self-assembly
Wearable technology
title Fabrication of highly conductive, flexible, and hydrophobic Kevlar®@Ni-P-B@Cu@CS fabric with excellent self-cleaning performance for electromagnetic interference shielding
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