Fabrication of highly conductive, flexible, and hydrophobic Kevlar®@Ni-P-B@Cu@CS fabric with excellent self-cleaning performance for electromagnetic interference shielding
In this work, a simple and cost-effective method was proposed and developed to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate (Kevlar®@Ni-P-B@Cu@CS) composite fabric with high conductivity, high flexibility, high hydrophobicity, and high durability to ef...
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Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2024-03, Vol.53 (1), p.4432-4443 |
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container_title | Dalton transactions : an international journal of inorganic chemistry |
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creator | Shao, Qinsi Wang, Hao Zhang, Leilei Wang, Xihai Zhang, Hengxin Bai, Ruicheng Fu, Hongshan |
description | In this work, a simple and cost-effective method was proposed and developed to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate (Kevlar®@Ni-P-B@Cu@CS) composite fabric with high conductivity, high flexibility, high hydrophobicity, and high durability to effectively shield electromagnetic interference (EMI). In this method, an amorphous Ni-P-B alloy nanolayer was initially deposited onto a Kevlar® fabric
via
electroless plating. Afterward, a crystalline Cu nanolayer was deposited as the second layer
via
electroplating. Finally, a monolayer of copper stearate was innovatively self-assembled as the outermost protective layer. The Cu deposition was effectively adjusted and designed by controlling the plating current and plating time. The electrical resistance and contact angle of the optimized Kevlar®@Ni-P-B@Cu@CS composite fabric were as low as 3.2 mΩ sq
−1
and as high as 115.39°, respectively, indicating that the fabric could withstand bending, tape-off, corrosion, and accelerated environmental tests. The average EMI-shielding efficiency of the durable composite fabric was 93.9 dB in the frequency range of 8.2-12.4 GHz, which was mainly attributed to the absorption loss. Thus, the proposed material configuration has promise for applications in aviation, aerospace, telecommunication, wearable devices, and military industries.
A simple and cost-effective method to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate composite fabric with outstanding properties is successfully developed. |
doi_str_mv | 10.1039/d3dt04291j |
format | Article |
fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmed_primary_38349221</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2937236324</sourcerecordid><originalsourceid>FETCH-LOGICAL-c296t-afb9527e65f357daf8aa6b72b7d595b5ce3b37c13dcd79ff7e1a08f07fd7bb873</originalsourceid><addsrcrecordid>eNpd0stu1DAUBuAIgWgpbNiDLLFBiIBjJ_FkN-2UlksFSJR15MvxxCPHHmyndN4J8RA8WT2dMkis_Mv-zpGt46J4WuE3FabdW0VVwjXpqtW94rCqGSs7Quv7-0zag-JRjCuMCcENeVgc0Bmt8351WPw64yIYyZPxDnmNBrMc7AZJ79Qkk7mC10hbuDbC5sSdQsNGBb8evDASfYIry8Of3_PPpvxanswX03zxDenbjuinSQOCawnWgksogtWltMCdcUu0hqB9GLmTgHJAYEGm4Ee-dJBysXEpCwiwBXEwYFUue1w80NxGeHK3HhXfz95dLt6XF1_OPyyOL0pJujaVXIuuIQzaRtOGKa5nnLeCEcFU0zWikUAFZbKiSirWac2g4nimMdOKCTFj9Kh4ueu7Dv7HBDH1o4nbh3AHfoo96UiLGatxl-mL_-jKT8Hl22VFGaEtJXVWr3ZKBh9jAN2vgxl52PQV7rcz7E_p6eXtDD9m_Pyu5SRGUHv6d2gZPNuBEOX-9N8noDfXo6Vt</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2937236324</pqid></control><display><type>article</type><title>Fabrication of highly conductive, flexible, and hydrophobic Kevlar®@Ni-P-B@Cu@CS fabric with excellent self-cleaning performance for electromagnetic interference shielding</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Shao, Qinsi ; Wang, Hao ; Zhang, Leilei ; Wang, Xihai ; Zhang, Hengxin ; Bai, Ruicheng ; Fu, Hongshan</creator><creatorcontrib>Shao, Qinsi ; Wang, Hao ; Zhang, Leilei ; Wang, Xihai ; Zhang, Hengxin ; Bai, Ruicheng ; Fu, Hongshan</creatorcontrib><description>In this work, a simple and cost-effective method was proposed and developed to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate (Kevlar®@Ni-P-B@Cu@CS) composite fabric with high conductivity, high flexibility, high hydrophobicity, and high durability to effectively shield electromagnetic interference (EMI). In this method, an amorphous Ni-P-B alloy nanolayer was initially deposited onto a Kevlar® fabric
via
electroless plating. Afterward, a crystalline Cu nanolayer was deposited as the second layer
via
electroplating. Finally, a monolayer of copper stearate was innovatively self-assembled as the outermost protective layer. The Cu deposition was effectively adjusted and designed by controlling the plating current and plating time. The electrical resistance and contact angle of the optimized Kevlar®@Ni-P-B@Cu@CS composite fabric were as low as 3.2 mΩ sq
−1
and as high as 115.39°, respectively, indicating that the fabric could withstand bending, tape-off, corrosion, and accelerated environmental tests. The average EMI-shielding efficiency of the durable composite fabric was 93.9 dB in the frequency range of 8.2-12.4 GHz, which was mainly attributed to the absorption loss. Thus, the proposed material configuration has promise for applications in aviation, aerospace, telecommunication, wearable devices, and military industries.
A simple and cost-effective method to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate composite fabric with outstanding properties is successfully developed.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d3dt04291j</identifier><identifier>PMID: 38349221</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Accelerated tests ; Aramid fiber reinforced plastics ; Contact angle ; Copper ; Copper stearate ; Corrosion tests ; Durability ; Electric contacts ; Electroless plating ; Electromagnetic interference ; Electromagnetic shielding ; Electroplating ; Environmental testing ; Frequency ranges ; Hydrophobicity ; Kevlar (trademark) ; Multilayers ; Nickel ; Self-assembly ; Wearable technology</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2024-03, Vol.53 (1), p.4432-4443</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c296t-afb9527e65f357daf8aa6b72b7d595b5ce3b37c13dcd79ff7e1a08f07fd7bb873</cites><orcidid>0000-0002-2762-5196</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38349221$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shao, Qinsi</creatorcontrib><creatorcontrib>Wang, Hao</creatorcontrib><creatorcontrib>Zhang, Leilei</creatorcontrib><creatorcontrib>Wang, Xihai</creatorcontrib><creatorcontrib>Zhang, Hengxin</creatorcontrib><creatorcontrib>Bai, Ruicheng</creatorcontrib><creatorcontrib>Fu, Hongshan</creatorcontrib><title>Fabrication of highly conductive, flexible, and hydrophobic Kevlar®@Ni-P-B@Cu@CS fabric with excellent self-cleaning performance for electromagnetic interference shielding</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>In this work, a simple and cost-effective method was proposed and developed to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate (Kevlar®@Ni-P-B@Cu@CS) composite fabric with high conductivity, high flexibility, high hydrophobicity, and high durability to effectively shield electromagnetic interference (EMI). In this method, an amorphous Ni-P-B alloy nanolayer was initially deposited onto a Kevlar® fabric
via
electroless plating. Afterward, a crystalline Cu nanolayer was deposited as the second layer
via
electroplating. Finally, a monolayer of copper stearate was innovatively self-assembled as the outermost protective layer. The Cu deposition was effectively adjusted and designed by controlling the plating current and plating time. The electrical resistance and contact angle of the optimized Kevlar®@Ni-P-B@Cu@CS composite fabric were as low as 3.2 mΩ sq
−1
and as high as 115.39°, respectively, indicating that the fabric could withstand bending, tape-off, corrosion, and accelerated environmental tests. The average EMI-shielding efficiency of the durable composite fabric was 93.9 dB in the frequency range of 8.2-12.4 GHz, which was mainly attributed to the absorption loss. Thus, the proposed material configuration has promise for applications in aviation, aerospace, telecommunication, wearable devices, and military industries.
A simple and cost-effective method to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate composite fabric with outstanding properties is successfully developed.</description><subject>Accelerated tests</subject><subject>Aramid fiber reinforced plastics</subject><subject>Contact angle</subject><subject>Copper</subject><subject>Copper stearate</subject><subject>Corrosion tests</subject><subject>Durability</subject><subject>Electric contacts</subject><subject>Electroless plating</subject><subject>Electromagnetic interference</subject><subject>Electromagnetic shielding</subject><subject>Electroplating</subject><subject>Environmental testing</subject><subject>Frequency ranges</subject><subject>Hydrophobicity</subject><subject>Kevlar (trademark)</subject><subject>Multilayers</subject><subject>Nickel</subject><subject>Self-assembly</subject><subject>Wearable technology</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0stu1DAUBuAIgWgpbNiDLLFBiIBjJ_FkN-2UlksFSJR15MvxxCPHHmyndN4J8RA8WT2dMkis_Mv-zpGt46J4WuE3FabdW0VVwjXpqtW94rCqGSs7Quv7-0zag-JRjCuMCcENeVgc0Bmt8351WPw64yIYyZPxDnmNBrMc7AZJ79Qkk7mC10hbuDbC5sSdQsNGBb8evDASfYIry8Of3_PPpvxanswX03zxDenbjuinSQOCawnWgksogtWltMCdcUu0hqB9GLmTgHJAYEGm4Ee-dJBysXEpCwiwBXEwYFUue1w80NxGeHK3HhXfz95dLt6XF1_OPyyOL0pJujaVXIuuIQzaRtOGKa5nnLeCEcFU0zWikUAFZbKiSirWac2g4nimMdOKCTFj9Kh4ueu7Dv7HBDH1o4nbh3AHfoo96UiLGatxl-mL_-jKT8Hl22VFGaEtJXVWr3ZKBh9jAN2vgxl52PQV7rcz7E_p6eXtDD9m_Pyu5SRGUHv6d2gZPNuBEOX-9N8noDfXo6Vt</recordid><startdate>20240305</startdate><enddate>20240305</enddate><creator>Shao, Qinsi</creator><creator>Wang, Hao</creator><creator>Zhang, Leilei</creator><creator>Wang, Xihai</creator><creator>Zhang, Hengxin</creator><creator>Bai, Ruicheng</creator><creator>Fu, Hongshan</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-2762-5196</orcidid></search><sort><creationdate>20240305</creationdate><title>Fabrication of highly conductive, flexible, and hydrophobic Kevlar®@Ni-P-B@Cu@CS fabric with excellent self-cleaning performance for electromagnetic interference shielding</title><author>Shao, Qinsi ; Wang, Hao ; Zhang, Leilei ; Wang, Xihai ; Zhang, Hengxin ; Bai, Ruicheng ; Fu, Hongshan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c296t-afb9527e65f357daf8aa6b72b7d595b5ce3b37c13dcd79ff7e1a08f07fd7bb873</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Accelerated tests</topic><topic>Aramid fiber reinforced plastics</topic><topic>Contact angle</topic><topic>Copper</topic><topic>Copper stearate</topic><topic>Corrosion tests</topic><topic>Durability</topic><topic>Electric contacts</topic><topic>Electroless plating</topic><topic>Electromagnetic interference</topic><topic>Electromagnetic shielding</topic><topic>Electroplating</topic><topic>Environmental testing</topic><topic>Frequency ranges</topic><topic>Hydrophobicity</topic><topic>Kevlar (trademark)</topic><topic>Multilayers</topic><topic>Nickel</topic><topic>Self-assembly</topic><topic>Wearable technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shao, Qinsi</creatorcontrib><creatorcontrib>Wang, Hao</creatorcontrib><creatorcontrib>Zhang, Leilei</creatorcontrib><creatorcontrib>Wang, Xihai</creatorcontrib><creatorcontrib>Zhang, Hengxin</creatorcontrib><creatorcontrib>Bai, Ruicheng</creatorcontrib><creatorcontrib>Fu, Hongshan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shao, Qinsi</au><au>Wang, Hao</au><au>Zhang, Leilei</au><au>Wang, Xihai</au><au>Zhang, Hengxin</au><au>Bai, Ruicheng</au><au>Fu, Hongshan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of highly conductive, flexible, and hydrophobic Kevlar®@Ni-P-B@Cu@CS fabric with excellent self-cleaning performance for electromagnetic interference shielding</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2024-03-05</date><risdate>2024</risdate><volume>53</volume><issue>1</issue><spage>4432</spage><epage>4443</epage><pages>4432-4443</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>In this work, a simple and cost-effective method was proposed and developed to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate (Kevlar®@Ni-P-B@Cu@CS) composite fabric with high conductivity, high flexibility, high hydrophobicity, and high durability to effectively shield electromagnetic interference (EMI). In this method, an amorphous Ni-P-B alloy nanolayer was initially deposited onto a Kevlar® fabric
via
electroless plating. Afterward, a crystalline Cu nanolayer was deposited as the second layer
via
electroplating. Finally, a monolayer of copper stearate was innovatively self-assembled as the outermost protective layer. The Cu deposition was effectively adjusted and designed by controlling the plating current and plating time. The electrical resistance and contact angle of the optimized Kevlar®@Ni-P-B@Cu@CS composite fabric were as low as 3.2 mΩ sq
−1
and as high as 115.39°, respectively, indicating that the fabric could withstand bending, tape-off, corrosion, and accelerated environmental tests. The average EMI-shielding efficiency of the durable composite fabric was 93.9 dB in the frequency range of 8.2-12.4 GHz, which was mainly attributed to the absorption loss. Thus, the proposed material configuration has promise for applications in aviation, aerospace, telecommunication, wearable devices, and military industries.
A simple and cost-effective method to prepare a novel multilayer-structured Kevlar®@nickel-phosphorus-boron@copper@copper stearate composite fabric with outstanding properties is successfully developed.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38349221</pmid><doi>10.1039/d3dt04291j</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-2762-5196</orcidid></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Accelerated tests Aramid fiber reinforced plastics Contact angle Copper Copper stearate Corrosion tests Durability Electric contacts Electroless plating Electromagnetic interference Electromagnetic shielding Electroplating Environmental testing Frequency ranges Hydrophobicity Kevlar (trademark) Multilayers Nickel Self-assembly Wearable technology |
title | Fabrication of highly conductive, flexible, and hydrophobic Kevlar®@Ni-P-B@Cu@CS fabric with excellent self-cleaning performance for electromagnetic interference shielding |
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