Solvent modulation of the morphology of homochiral gadolinium coordination polymers and its impact on circularly polarized luminescence
Studying the effect of morphology on the circularly polarized luminescence (CPL) of chiral molecular materials is important for the development of CPL-active materials for applications. Herein, we report that the morphology of Gd(NO 3 ) 3 / R -, S -AnempH 2 [AnempH 2 = (1-anthrylethylamino)methylpho...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2024-02, Vol.53 (9), p.4291-4298 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Hou, Ting Zhao, Chen-Chen Bao, Song-Song Zhai, Zhi-Min Zheng, Li-Min |
| description | Studying the effect of morphology on the circularly polarized luminescence (CPL) of chiral molecular materials is important for the development of CPL-active materials for applications. Herein, we report that the morphology of Gd(NO
3
)
3
/
R
-,
S
-AnempH
2
[AnempH
2
= (1-anthrylethylamino)methylphosphonic acid] assemblies can be controlled by solvent modulation to form spiral bundles Gd(
R
-,
S
-AnempH)
3
·2H
2
O (
R
-,
S
-1
), crystals Gd(
R
-,
S
-AnempH)
3
·2H
2
O (
R
-,
S
-2
) and spindle-shaped particles Gd(
R
-,
S
-AnempH)
3
·3H
2
O·0.5DMF (
R
-,
S
-3
) with similar chain structures. Interestingly,
R
-,
S
-1
are CPL active and show the highest value of dissymmetric factor among the three pairs of enantiomers (|
g
lum
| = 2.1 × 10
-3
), which is 2.8 times larger than that of
R
-,
S
-2
, while
R
-,
S
-3
are CPL inactive with |
g
lum
| 0. This work provides a new route to control the morphology of chiral coordination polymers and improve their CPL performance.
The morphology of Gd(NO
3
)
3
/
R
-,
S
-AnempH
2
assemblies is controlled by solvent. The spiral bundles (
R
-,
S
-1
) are CPL active with asymmetric factor 2.8 times larger than that of crystals (
R
-,
S
-2
), while spindle-shaped particles (
R
-,
S
-3
) are CPL inactive. |
| doi_str_mv | 10.1039/d3dt03735e |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmed_primary_38345325</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2926077002</sourcerecordid><originalsourceid>FETCH-LOGICAL-c332t-15be174aa6d3c99742f95cc39eba22911865e2deb354969d510ef4a3d18864a23</originalsourceid><addsrcrecordid>eNpd0U2LFDEQBuAgLu6HXrwrgb2IMJqkku7OUfZDFxY8uJ6bTFK9kyWdtEm3MP6B_dtmnHUETwlVT4oiLyGvOfvAGeiPDtzMoAWFz8gJl2270gLk88NdNMfktJQHxoRgSrwgx9CBVCDUCXn8lsJPjDMdk1uCmX2KNA103mCt5GmTQrrf7iqbNCa78dkEem9cCj76ZaQ2pex83L-bUtiOmAs10VE_F-rHydiZ1pb12dbxOWx3ymT_Cx0Ny-gjFovR4ktyNJhQ8NXTeUa-X1_dXXxZ3X79fHPx6XZlAcS84mqNvJXGNA6s1q0Ug1bWgsa1EUJz3jUKhcM1KKkb7RRnOEgDjnddI42AM_JuP3fK6ceCZe5HXzcIwURMS-mFFg1r2_pVlZ7_Rx_SkmPdrirgndZa8qre75XNqZSMQz9lP5q87Tnrd_H0l3B59yeeq4rfPo1c1iO6A_2bRwVv9iAXe-j-yxd-A_iRlxg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2931899941</pqid></control><display><type>article</type><title>Solvent modulation of the morphology of homochiral gadolinium coordination polymers and its impact on circularly polarized luminescence</title><source>Alma/SFX Local Collection</source><source>Royal Society of Chemistry E-Journals</source><creator>Hou, Ting ; Zhao, Chen-Chen ; Bao, Song-Song ; Zhai, Zhi-Min ; Zheng, Li-Min</creator><creatorcontrib>Hou, Ting ; Zhao, Chen-Chen ; Bao, Song-Song ; Zhai, Zhi-Min ; Zheng, Li-Min</creatorcontrib><description>Studying the effect of morphology on the circularly polarized luminescence (CPL) of chiral molecular materials is important for the development of CPL-active materials for applications. Herein, we report that the morphology of Gd(NO
3
)
3
/
R
-,
S
-AnempH
2
[AnempH
2
= (1-anthrylethylamino)methylphosphonic acid] assemblies can be controlled by solvent modulation to form spiral bundles Gd(
R
-,
S
-AnempH)
3
·2H
2
O (
R
-,
S
-1
), crystals Gd(
R
-,
S
-AnempH)
3
·2H
2
O (
R
-,
S
-2
) and spindle-shaped particles Gd(
R
-,
S
-AnempH)
3
·3H
2
O·0.5DMF (
R
-,
S
-3
) with similar chain structures. Interestingly,
R
-,
S
-1
are CPL active and show the highest value of dissymmetric factor among the three pairs of enantiomers (|
g
lum
| = 2.1 × 10
-3
), which is 2.8 times larger than that of
R
-,
S
-2
, while
R
-,
S
-3
are CPL inactive with |
g
lum
| 0. This work provides a new route to control the morphology of chiral coordination polymers and improve their CPL performance.
The morphology of Gd(NO
3
)
3
/
R
-,
S
-AnempH
2
assemblies is controlled by solvent. The spiral bundles (
R
-,
S
-1
) are CPL active with asymmetric factor 2.8 times larger than that of crystals (
R
-,
S
-2
), while spindle-shaped particles (
R
-,
S
-3
) are CPL inactive.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d3dt03735e</identifier><identifier>PMID: 38345325</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Circular polarization ; Coordination polymers ; Enantiomers ; Gadolinium ; Luminescence ; Modulation ; Morphology ; Solvents</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2024-02, Vol.53 (9), p.4291-4298</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c332t-15be174aa6d3c99742f95cc39eba22911865e2deb354969d510ef4a3d18864a23</cites><orcidid>0000-0003-4437-1105 ; 0000-0001-6770-8802</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38345325$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hou, Ting</creatorcontrib><creatorcontrib>Zhao, Chen-Chen</creatorcontrib><creatorcontrib>Bao, Song-Song</creatorcontrib><creatorcontrib>Zhai, Zhi-Min</creatorcontrib><creatorcontrib>Zheng, Li-Min</creatorcontrib><title>Solvent modulation of the morphology of homochiral gadolinium coordination polymers and its impact on circularly polarized luminescence</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Studying the effect of morphology on the circularly polarized luminescence (CPL) of chiral molecular materials is important for the development of CPL-active materials for applications. Herein, we report that the morphology of Gd(NO
3
)
3
/
R
-,
S
-AnempH
2
[AnempH
2
= (1-anthrylethylamino)methylphosphonic acid] assemblies can be controlled by solvent modulation to form spiral bundles Gd(
R
-,
S
-AnempH)
3
·2H
2
O (
R
-,
S
-1
), crystals Gd(
R
-,
S
-AnempH)
3
·2H
2
O (
R
-,
S
-2
) and spindle-shaped particles Gd(
R
-,
S
-AnempH)
3
·3H
2
O·0.5DMF (
R
-,
S
-3
) with similar chain structures. Interestingly,
R
-,
S
-1
are CPL active and show the highest value of dissymmetric factor among the three pairs of enantiomers (|
g
lum
| = 2.1 × 10
-3
), which is 2.8 times larger than that of
R
-,
S
-2
, while
R
-,
S
-3
are CPL inactive with |
g
lum
| 0. This work provides a new route to control the morphology of chiral coordination polymers and improve their CPL performance.
The morphology of Gd(NO
3
)
3
/
R
-,
S
-AnempH
2
assemblies is controlled by solvent. The spiral bundles (
R
-,
S
-1
) are CPL active with asymmetric factor 2.8 times larger than that of crystals (
R
-,
S
-2
), while spindle-shaped particles (
R
-,
S
-3
) are CPL inactive.</description><subject>Circular polarization</subject><subject>Coordination polymers</subject><subject>Enantiomers</subject><subject>Gadolinium</subject><subject>Luminescence</subject><subject>Modulation</subject><subject>Morphology</subject><subject>Solvents</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0U2LFDEQBuAgLu6HXrwrgb2IMJqkku7OUfZDFxY8uJ6bTFK9kyWdtEm3MP6B_dtmnHUETwlVT4oiLyGvOfvAGeiPDtzMoAWFz8gJl2270gLk88NdNMfktJQHxoRgSrwgx9CBVCDUCXn8lsJPjDMdk1uCmX2KNA103mCt5GmTQrrf7iqbNCa78dkEem9cCj76ZaQ2pex83L-bUtiOmAs10VE_F-rHydiZ1pb12dbxOWx3ymT_Cx0Ny-gjFovR4ktyNJhQ8NXTeUa-X1_dXXxZ3X79fHPx6XZlAcS84mqNvJXGNA6s1q0Ug1bWgsa1EUJz3jUKhcM1KKkb7RRnOEgDjnddI42AM_JuP3fK6ceCZe5HXzcIwURMS-mFFg1r2_pVlZ7_Rx_SkmPdrirgndZa8qre75XNqZSMQz9lP5q87Tnrd_H0l3B59yeeq4rfPo1c1iO6A_2bRwVv9iAXe-j-yxd-A_iRlxg</recordid><startdate>20240227</startdate><enddate>20240227</enddate><creator>Hou, Ting</creator><creator>Zhao, Chen-Chen</creator><creator>Bao, Song-Song</creator><creator>Zhai, Zhi-Min</creator><creator>Zheng, Li-Min</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-4437-1105</orcidid><orcidid>https://orcid.org/0000-0001-6770-8802</orcidid></search><sort><creationdate>20240227</creationdate><title>Solvent modulation of the morphology of homochiral gadolinium coordination polymers and its impact on circularly polarized luminescence</title><author>Hou, Ting ; Zhao, Chen-Chen ; Bao, Song-Song ; Zhai, Zhi-Min ; Zheng, Li-Min</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c332t-15be174aa6d3c99742f95cc39eba22911865e2deb354969d510ef4a3d18864a23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Circular polarization</topic><topic>Coordination polymers</topic><topic>Enantiomers</topic><topic>Gadolinium</topic><topic>Luminescence</topic><topic>Modulation</topic><topic>Morphology</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hou, Ting</creatorcontrib><creatorcontrib>Zhao, Chen-Chen</creatorcontrib><creatorcontrib>Bao, Song-Song</creatorcontrib><creatorcontrib>Zhai, Zhi-Min</creatorcontrib><creatorcontrib>Zheng, Li-Min</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hou, Ting</au><au>Zhao, Chen-Chen</au><au>Bao, Song-Song</au><au>Zhai, Zhi-Min</au><au>Zheng, Li-Min</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvent modulation of the morphology of homochiral gadolinium coordination polymers and its impact on circularly polarized luminescence</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2024-02-27</date><risdate>2024</risdate><volume>53</volume><issue>9</issue><spage>4291</spage><epage>4298</epage><pages>4291-4298</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Studying the effect of morphology on the circularly polarized luminescence (CPL) of chiral molecular materials is important for the development of CPL-active materials for applications. Herein, we report that the morphology of Gd(NO
3
)
3
/
R
-,
S
-AnempH
2
[AnempH
2
= (1-anthrylethylamino)methylphosphonic acid] assemblies can be controlled by solvent modulation to form spiral bundles Gd(
R
-,
S
-AnempH)
3
·2H
2
O (
R
-,
S
-1
), crystals Gd(
R
-,
S
-AnempH)
3
·2H
2
O (
R
-,
S
-2
) and spindle-shaped particles Gd(
R
-,
S
-AnempH)
3
·3H
2
O·0.5DMF (
R
-,
S
-3
) with similar chain structures. Interestingly,
R
-,
S
-1
are CPL active and show the highest value of dissymmetric factor among the three pairs of enantiomers (|
g
lum
| = 2.1 × 10
-3
), which is 2.8 times larger than that of
R
-,
S
-2
, while
R
-,
S
-3
are CPL inactive with |
g
lum
| 0. This work provides a new route to control the morphology of chiral coordination polymers and improve their CPL performance.
The morphology of Gd(NO
3
)
3
/
R
-,
S
-AnempH
2
assemblies is controlled by solvent. The spiral bundles (
R
-,
S
-1
) are CPL active with asymmetric factor 2.8 times larger than that of crystals (
R
-,
S
-2
), while spindle-shaped particles (
R
-,
S
-3
) are CPL inactive.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38345325</pmid><doi>10.1039/d3dt03735e</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-4437-1105</orcidid><orcidid>https://orcid.org/0000-0001-6770-8802</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2024-02, Vol.53 (9), p.4291-4298 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_pubmed_primary_38345325 |
| source | Alma/SFX Local Collection; Royal Society of Chemistry E-Journals |
| subjects | Circular polarization Coordination polymers Enantiomers Gadolinium Luminescence Modulation Morphology Solvents |
| title | Solvent modulation of the morphology of homochiral gadolinium coordination polymers and its impact on circularly polarized luminescence |
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