Investigation of the structure and dielectric properties of doped barium titanates
This work examined the influence of zirconium concentration on barium titanate (BZT) BaZr x Ti 1− x O 3 , with ( x = 0, 0.15, 0.50, 0.75, and 1), produced by the tartrate precursor technique. The Fourier transform infrared (FTIR) spectra support the X-ray diffraction (XRD) results regarding formatio...
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| creator | Salem, Mohamed M Darwish, Moustafa A Altarawneh, Aseel M Alibwaini, Yamen A Ghazy, Ryad Hemeda, Osama M Zhou, Di Trukhanova, Ekaterina L Trukhanov, Alex V Trukhanov, Sergei V Mostafa, Maha |
| description | This work examined the influence of zirconium concentration on barium titanate (BZT) BaZr
x
Ti
1−
x
O
3
, with (
x
= 0, 0.15, 0.50, 0.75, and 1), produced by the tartrate precursor technique. The Fourier transform infrared (FTIR) spectra support the X-ray diffraction (XRD) results regarding formation of the perovskite structure. Grain size grows with Zr concentration, suggesting that the presence of Zr ions enlarges the grains. The transmission electron microscopy (TEM) images demonstrated that, due to their nano size, nanocrystallites are agglomerated in most images with irregular morphologies and average particle sizes from 20.75 nm to 63.75 nm. Increasing Zr content diminished the piezoelectric coefficient (
d
33
) and the grain size. The value of
d
33
decreases by increasing Zr content, and there is an inverse relationship between grain size and
d
33
. The remnant polarization of BZT increases with increasing Zr
4+
content, which may be suitable for permanent memory device applications.
This work examined the influence of zirconium concentration on barium titanate (BZT) BaZr
x
Ti
1−
x
O
3
, with (
x
= 0, 0.15, 0.50, 0.75, and 1), produced by the tartrate precursor technique. |
| doi_str_mv | 10.1039/d3ra05885a |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmed_primary_38259985</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2917476173</sourcerecordid><originalsourceid>FETCH-LOGICAL-c429t-242cc749558301a037c300aa02d15710307d851da2674f641e67c796112834be3</originalsourceid><addsrcrecordid>eNpd0UlLAzEUB_Agikrtxbsy4EWEapbJdpJSVygIRc8hTVKNTCc1yRT89kZb65JLEvLj8V7-ABwieI4gkReWRA2pEFRvgX0MazbAkMntX-c90E_pFZbFKMIM7YI9IjCVUtB9MLlvly5l_6yzD20VZlV-cVXKsTO5i67Sra2sd40zOXpTLWJYuJi9S5_Uloutpjr6bl5ln3Wrs0sHYGemm-T6670Hnm6uH0d3g_HD7f1oOB6YGss8wDU2hteSUkEg0pBwQyDUGmKLKC-zQW4FRVZjxusZq5Fj3HDJEMKC1FNHeuByVXfRTefOGtfmqBu1iH6u47sK2qu_L61_Uc9hqRAUEDEpS4XTdYUY3rryDWruk3FNo1sXuqSwRFwwxKEo9OQffQ1dbMt8X6rmhZGizlbKxJBSdLNNNwiqz7jUFZkMv-IaFnz8u_8N_Q6ngKMViMlsXn_yJh8o_ZkG</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2917476173</pqid></control><display><type>article</type><title>Investigation of the structure and dielectric properties of doped barium titanates</title><source>DOAJ Directory of Open Access Journals</source><source>PubMed Central Open Access</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><creator>Salem, Mohamed M ; Darwish, Moustafa A ; Altarawneh, Aseel M ; Alibwaini, Yamen A ; Ghazy, Ryad ; Hemeda, Osama M ; Zhou, Di ; Trukhanova, Ekaterina L ; Trukhanov, Alex V ; Trukhanov, Sergei V ; Mostafa, Maha</creator><creatorcontrib>Salem, Mohamed M ; Darwish, Moustafa A ; Altarawneh, Aseel M ; Alibwaini, Yamen A ; Ghazy, Ryad ; Hemeda, Osama M ; Zhou, Di ; Trukhanova, Ekaterina L ; Trukhanov, Alex V ; Trukhanov, Sergei V ; Mostafa, Maha</creatorcontrib><description>This work examined the influence of zirconium concentration on barium titanate (BZT) BaZr
x
Ti
1−
x
O
3
, with (
x
= 0, 0.15, 0.50, 0.75, and 1), produced by the tartrate precursor technique. The Fourier transform infrared (FTIR) spectra support the X-ray diffraction (XRD) results regarding formation of the perovskite structure. Grain size grows with Zr concentration, suggesting that the presence of Zr ions enlarges the grains. The transmission electron microscopy (TEM) images demonstrated that, due to their nano size, nanocrystallites are agglomerated in most images with irregular morphologies and average particle sizes from 20.75 nm to 63.75 nm. Increasing Zr content diminished the piezoelectric coefficient (
d
33
) and the grain size. The value of
d
33
decreases by increasing Zr content, and there is an inverse relationship between grain size and
d
33
. The remnant polarization of BZT increases with increasing Zr
4+
content, which may be suitable for permanent memory device applications.
This work examined the influence of zirconium concentration on barium titanate (BZT) BaZr
x
Ti
1−
x
O
3
, with (
x
= 0, 0.15, 0.50, 0.75, and 1), produced by the tartrate precursor technique.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d3ra05885a</identifier><identifier>PMID: 38259985</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Barium titanates ; Chemistry ; Dielectric properties ; Fourier transforms ; Grain size ; Infrared spectra ; Memory devices ; Perovskite structure ; Perovskites ; Piezoelectricity ; Zirconium</subject><ispartof>RSC advances, 2024-01, Vol.14 (5), p.3335-3345</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2024</rights><rights>This journal is © The Royal Society of Chemistry 2024 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c429t-242cc749558301a037c300aa02d15710307d851da2674f641e67c796112834be3</citedby><cites>FETCH-LOGICAL-c429t-242cc749558301a037c300aa02d15710307d851da2674f641e67c796112834be3</cites><orcidid>0000-0003-3430-9578 ; 0000-0003-2294-4371</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10801699/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10801699/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38259985$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Salem, Mohamed M</creatorcontrib><creatorcontrib>Darwish, Moustafa A</creatorcontrib><creatorcontrib>Altarawneh, Aseel M</creatorcontrib><creatorcontrib>Alibwaini, Yamen A</creatorcontrib><creatorcontrib>Ghazy, Ryad</creatorcontrib><creatorcontrib>Hemeda, Osama M</creatorcontrib><creatorcontrib>Zhou, Di</creatorcontrib><creatorcontrib>Trukhanova, Ekaterina L</creatorcontrib><creatorcontrib>Trukhanov, Alex V</creatorcontrib><creatorcontrib>Trukhanov, Sergei V</creatorcontrib><creatorcontrib>Mostafa, Maha</creatorcontrib><title>Investigation of the structure and dielectric properties of doped barium titanates</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>This work examined the influence of zirconium concentration on barium titanate (BZT) BaZr
x
Ti
1−
x
O
3
, with (
x
= 0, 0.15, 0.50, 0.75, and 1), produced by the tartrate precursor technique. The Fourier transform infrared (FTIR) spectra support the X-ray diffraction (XRD) results regarding formation of the perovskite structure. Grain size grows with Zr concentration, suggesting that the presence of Zr ions enlarges the grains. The transmission electron microscopy (TEM) images demonstrated that, due to their nano size, nanocrystallites are agglomerated in most images with irregular morphologies and average particle sizes from 20.75 nm to 63.75 nm. Increasing Zr content diminished the piezoelectric coefficient (
d
33
) and the grain size. The value of
d
33
decreases by increasing Zr content, and there is an inverse relationship between grain size and
d
33
. The remnant polarization of BZT increases with increasing Zr
4+
content, which may be suitable for permanent memory device applications.
This work examined the influence of zirconium concentration on barium titanate (BZT) BaZr
x
Ti
1−
x
O
3
, with (
x
= 0, 0.15, 0.50, 0.75, and 1), produced by the tartrate precursor technique.</description><subject>Barium titanates</subject><subject>Chemistry</subject><subject>Dielectric properties</subject><subject>Fourier transforms</subject><subject>Grain size</subject><subject>Infrared spectra</subject><subject>Memory devices</subject><subject>Perovskite structure</subject><subject>Perovskites</subject><subject>Piezoelectricity</subject><subject>Zirconium</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpd0UlLAzEUB_Agikrtxbsy4EWEapbJdpJSVygIRc8hTVKNTCc1yRT89kZb65JLEvLj8V7-ABwieI4gkReWRA2pEFRvgX0MazbAkMntX-c90E_pFZbFKMIM7YI9IjCVUtB9MLlvly5l_6yzD20VZlV-cVXKsTO5i67Sra2sd40zOXpTLWJYuJi9S5_Uloutpjr6bl5ln3Wrs0sHYGemm-T6670Hnm6uH0d3g_HD7f1oOB6YGss8wDU2hteSUkEg0pBwQyDUGmKLKC-zQW4FRVZjxusZq5Fj3HDJEMKC1FNHeuByVXfRTefOGtfmqBu1iH6u47sK2qu_L61_Uc9hqRAUEDEpS4XTdYUY3rryDWruk3FNo1sXuqSwRFwwxKEo9OQffQ1dbMt8X6rmhZGizlbKxJBSdLNNNwiqz7jUFZkMv-IaFnz8u_8N_Q6ngKMViMlsXn_yJh8o_ZkG</recordid><startdate>20240117</startdate><enddate>20240117</enddate><creator>Salem, Mohamed M</creator><creator>Darwish, Moustafa A</creator><creator>Altarawneh, Aseel M</creator><creator>Alibwaini, Yamen A</creator><creator>Ghazy, Ryad</creator><creator>Hemeda, Osama M</creator><creator>Zhou, Di</creator><creator>Trukhanova, Ekaterina L</creator><creator>Trukhanov, Alex V</creator><creator>Trukhanov, Sergei V</creator><creator>Mostafa, Maha</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-3430-9578</orcidid><orcidid>https://orcid.org/0000-0003-2294-4371</orcidid></search><sort><creationdate>20240117</creationdate><title>Investigation of the structure and dielectric properties of doped barium titanates</title><author>Salem, Mohamed M ; Darwish, Moustafa A ; Altarawneh, Aseel M ; Alibwaini, Yamen A ; Ghazy, Ryad ; Hemeda, Osama M ; Zhou, Di ; Trukhanova, Ekaterina L ; Trukhanov, Alex V ; Trukhanov, Sergei V ; Mostafa, Maha</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c429t-242cc749558301a037c300aa02d15710307d851da2674f641e67c796112834be3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Barium titanates</topic><topic>Chemistry</topic><topic>Dielectric properties</topic><topic>Fourier transforms</topic><topic>Grain size</topic><topic>Infrared spectra</topic><topic>Memory devices</topic><topic>Perovskite structure</topic><topic>Perovskites</topic><topic>Piezoelectricity</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Salem, Mohamed M</creatorcontrib><creatorcontrib>Darwish, Moustafa A</creatorcontrib><creatorcontrib>Altarawneh, Aseel M</creatorcontrib><creatorcontrib>Alibwaini, Yamen A</creatorcontrib><creatorcontrib>Ghazy, Ryad</creatorcontrib><creatorcontrib>Hemeda, Osama M</creatorcontrib><creatorcontrib>Zhou, Di</creatorcontrib><creatorcontrib>Trukhanova, Ekaterina L</creatorcontrib><creatorcontrib>Trukhanov, Alex V</creatorcontrib><creatorcontrib>Trukhanov, Sergei V</creatorcontrib><creatorcontrib>Mostafa, Maha</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Salem, Mohamed M</au><au>Darwish, Moustafa A</au><au>Altarawneh, Aseel M</au><au>Alibwaini, Yamen A</au><au>Ghazy, Ryad</au><au>Hemeda, Osama M</au><au>Zhou, Di</au><au>Trukhanova, Ekaterina L</au><au>Trukhanov, Alex V</au><au>Trukhanov, Sergei V</au><au>Mostafa, Maha</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation of the structure and dielectric properties of doped barium titanates</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2024-01-17</date><risdate>2024</risdate><volume>14</volume><issue>5</issue><spage>3335</spage><epage>3345</epage><pages>3335-3345</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>This work examined the influence of zirconium concentration on barium titanate (BZT) BaZr
x
Ti
1−
x
O
3
, with (
x
= 0, 0.15, 0.50, 0.75, and 1), produced by the tartrate precursor technique. The Fourier transform infrared (FTIR) spectra support the X-ray diffraction (XRD) results regarding formation of the perovskite structure. Grain size grows with Zr concentration, suggesting that the presence of Zr ions enlarges the grains. The transmission electron microscopy (TEM) images demonstrated that, due to their nano size, nanocrystallites are agglomerated in most images with irregular morphologies and average particle sizes from 20.75 nm to 63.75 nm. Increasing Zr content diminished the piezoelectric coefficient (
d
33
) and the grain size. The value of
d
33
decreases by increasing Zr content, and there is an inverse relationship between grain size and
d
33
. The remnant polarization of BZT increases with increasing Zr
4+
content, which may be suitable for permanent memory device applications.
This work examined the influence of zirconium concentration on barium titanate (BZT) BaZr
x
Ti
1−
x
O
3
, with (
x
= 0, 0.15, 0.50, 0.75, and 1), produced by the tartrate precursor technique.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>38259985</pmid><doi>10.1039/d3ra05885a</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0003-3430-9578</orcidid><orcidid>https://orcid.org/0000-0003-2294-4371</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
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| ispartof | RSC advances, 2024-01, Vol.14 (5), p.3335-3345 |
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| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Barium titanates Chemistry Dielectric properties Fourier transforms Grain size Infrared spectra Memory devices Perovskite structure Perovskites Piezoelectricity Zirconium |
| title | Investigation of the structure and dielectric properties of doped barium titanates |
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