A family of edge-sharing bi-octahedral diruthenium(,) compounds containing Ru-Ru single bonds

From paddlewheel starting reactants Ru 2 (R′CO 2 ) 4 + , a family of edge-sharing bi-octahedral (ESBO) diruthenium( iii , iii ) compounds has been prepared, formulated as Ru 2 (μ-O 2 CR′) 2 (μ-OR) 2 (η-L) 2 ( 1-10 ) [R′ = CH 3 , R = CH 3 , L = acac ( 1 ), tfac ( 2 ); R′ = CH 3 , R = CH 2 CH 3 , L =...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2023-07, Vol.52 (29), p.199-118
Hauptverfasser:	Guo, Li-Xiang, Gao, Yao, Zhang, Pei, Yang, Jian-Hui, Liu, Bin
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylacetone Band theory Bimetals Chemical bonds Density functional theory Electronic spectra Electrons Ligands Wavelengths
Online-Zugang:	Volltext
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